아연(zinc) 분말은 철의 부식을 막아주는 희생양극의 기능으로 자동차, 선박 및 철구조물의 부식을 방지하 는데 널리 사용되고 있다. 그러나 아연 분말은 높은 비중 때문에 수지나 용매 내에서 분산성이 저하되고 빠르게 침전이 일어나는 단점을 가진다. 본 연구에서는 실리카(SiOx)를 미세 아연분말의 표면에 코팅함으로써 아연분말의 물성 및 기능을 개선하고자 하였다. 아연분말의 실리카 표면코팅은 졸-겔법을 사용하였고 SEM/EDS의 표면 및 성분분석과 TEM 단면분석을 통하여 불순물이 잔존하지 않는 실리카 코팅이 성공적으로 형성됨과 그 코팅의 두께를 확인 할 수 있었다. 한편 코팅공정의 반복회수와 평균입도 변화와의 관계를 측정하여 2회까지의 반복코팅이 분산안정성을 유지하는데 효과적임을 확인하였다. 이 밖에 실리카 코팅 아연분말의 진비중(true density) 측정을 통해 코팅 공정에 의해 비중이 20% 이상 감소함을 확인하였고 제타포텐셜 측정으로 실리카 코팅에 의해 아연분말의 분산안정성이 4배까지 증가함을 확인하였다. 마지막으로 질산수용액 담지를 통해 실리카 코팅 아연분말의 내산성 향상 또한 확인하였다. 따라서 본 연구에서 제조된 실리카 코팅 아연분말은 방청 안료의 원료로 적합할 것으로 기대된다.

Graphene is an interesting material because it has remarkable properties, such as high intrinsic carrier mobility, good thermal conductivity, large specific surface area, high transparency, and high Young’s modulus values. It is produced by mechanical and chemical exfoliation, chemical vapor deposition (CVD), and epitaxial growth. In particular, large-area and uniform single- and few-layer growth of graphene is possible using transition metals via a thermal CVD process. In this study, we utilize polystyrene and boron oxide, which are a carbon precursor and a doping source, respectively, for synthesis of pristine graphene and boron doped graphene. We confirm the graphene grown by the polystyrene and the boron oxide by the optical microscope and the Raman spectra. Raman spectra of boron doped graphene is shifted to the right compared with pristine graphene and the crystal quality of boron doped graphene is recovered when the synthesis time is 15 min. Sheet resistance decreases from approximately 2000 Ω/sq to 300Ω/sq with an increasing synthesis time for the boron doped graphene.

In the area around Jeju Island, the squid jigging fishery and the hair-tail angling are popular. Therefore, the study on the characteristics of the formation and shift of fishing grounds is very important. We have received and analyzed AIS data of all vessels around Jeju Island from October 16, 2016 to October 16, 2017, and extracted the positions of the fishing vessels with the same operational characteristics as the fishing vessels of their fisheries. The distribution chart of the frequency of fishing vessels appearing in each predefined fishing grid (1 NM × 1 NM) was analyzed. So we took a analogy with the monthly shift of fishing grounds. Many fishing vessels appeared in the seas around Jeju Island from November 2016 to January 2017, and the frequency of their appearance was maintained. In November, however, fishing vessels were mostly concentrated in coastal waters. Yet, the density gradually weakened as they moved into January. From February, the frequency itself began to decline, making it the worst in April. The high concentration of fishing vessels in the waters leading from Jeju Island's northwest coast to south coast in November is believed to be related to the yellowtail fishery that are formed annually in the coastal waters off the island of Marado. In May 2017, the appearance frequency of fishing vessels increased and began to show a concentration in coastal waters around Jeju Island. Fishing vessels began to flock in waters northwest of Jeju Island beginning in July and peaked in August, and by September, fishing vessels were moving south along the coast of Jeju Island, weakening the density and spreading out. Between July and August, fishing vessels were concentrated in waters surrounding Jeju Island, which is believed to be related to the operations of fishing vessels for the squid jigging fishery and the hair-tail angling.

In this study, we tested Japanese trolling lines in the Jeju fishery. This fishery simulates the natural marine environment with many seabed rocks, and has been redesigned and manufactured it to be suitable for the Jeju fishery. In order to ensure that the trolling lines were deployed at the inhabitation depth of hairtails, the conditions required for the fishing gear to reach the target depth were determined for use during the experiment. The experimental test fishing was conducted at the depth of 120 m water in front of Jeju Seongsanpo and in the offshore area of Jeju Hanlim. The fishing gear used in the test fishing is currently used in a variety of field operations in Japan. However, several problems were identified, such as twisting of the line during its deployment and excessive sinking of the main line. The fishing gear was, therefore, redesigned and manufactured to be more suitable for the Jeju fishery environment. For the fishing gear to accurately reach the target depth, depth loggers were installed at the starting point of the main line and at the 250 m and 340 m points of the line. Depth and time were recorded every 10 seconds. According to the daytime positioning of hairtails in the lower water column, the target depth of the fishing gear was set at 100-110 m, which was 10-20 m above the sea floor. At a speed of 1.9 knots and with a 9 kg sinker attached, the main fishing line was deployed and catch yields at depths of 100 m, 150 m and 180 m were recorded and analyzed. When the 180 m main line was fully deployed, the time for the hairtail trolling lines to arrive at the appropriate configuration had to be 5 minutes. At this time, the depth of the fishing gear was 16-23 m above the sea floor, in accordance with the depths at which the hairtails were during the day. In addition, in order to accurately place the fishing gear at the inhabitation water depth of hairtails, the experimental test fishing utilized the results of the depth testing that identified the conditions required for the fishing gear to reach the target depth, and the result was a catch of up to 97 kg a day.

본 연구에서는 중국 시장에 진출한 한국 기업을 대상으로 현지에서 CSR을 수행하는 기업의 특성을 파악하고자 하였다. 이를 위해, 내수 시장 진출 목적의 중국 투자 기업 153개 업체를 대상으로 설문조사를 수행하였다. 검증 결과, 모기업의 규모, 고용 규모, 매출 규모 그리고 브랜드 명성이 유의하게 나타났다. 구체적으로, CSR에 적극적인 기업은 모기업 규모가 크고, 고용 규모가 크고, 매출 규모가 크며, 브랜드 명성이 높은 기업인 것으로 나타났다. 이러한 특성은 대기업의 현지 법인의 특성으로, 한국 기업의 중국에서의 CSR은 결국 대기업에 의해 주도되고 있음을 본 연구 결과가 시사해주고 있다. 한편, 소유 형태, 투자 규모와 시장성과는 CSR 수행 정도는 CSR 수행 정도와 유의한 관계를 보이지 않았다. 이론적 관점에서, 한국 기업의 해외 CSR은 선제적 관점의 CSR이론 보다는 방어적 관점의 CSR이론이 설명력이 높은 것으로 나타났다.

With the recent development of manufacturing technology and the diversification of consumer needs, the process and quality control of production have become more complicated. In particular, due to the nature of domestic manufacturing companies that rely on foreign manufacturers for most of their manufacturing facilities, the need for their own data analysis and manufacturing support applications is increasing and research has been conducted in Korea. This study proposes integrated process and quality analysis platform supporting analysis template considering manufacturing big data DB interworking and data characteristics. In addition, the platform is implemented in two versions, web and CS, in consideration of user accessibility.

Three new compounds are synthesized as color filter dyes by substituting a pyridine group into 1,4-position, 1,5-position, and 1,8-position of anthraquinone core moiety. Changes in physical properties of the synthesized compounds according to the substitution position are systematically investigated in terms of optical properties and thermal properties. The extinction coefficient value (ε) of the synthesized materials is extremely high and is above 4.22 in a log scale, and Td is above 300°C with high thermal stability.

포토리소그래피는 웨이퍼 위에 선폭을 나노급으로 줄인 패턴을 제조하는 반도체 제조 공정의 핵심 기술이며 선폭을 줄이고 불량을 줄이기 위하여 photo-resist 용액 제조 및 정제 기술이 중요하다. 특히 photo-resist solution 내에 함유되어 있는 soft particle의 정제가 매우 중요하다. 현재 개발되어 있는 멤브레인 필터는 soft particle 정제 성능이 상당히 미흡한 수준이다. 나일론이나 폴리에틸렌 위에 아라미드 고분자를 함침하여 soft particle 정제 특성을 살펴보았다. 또한 팔라듐 나노입자를 합성하여 투과 특성에 사용하였다.

Well-defined methacrylate based amphiphilic block copolymers (BCs) used as additives to fabricate poly(vinylidene fluoride) (PVDF) UF membranes, where the amphiphilic BC additives hydrophilically altered PVDF with PPEGMA block segment by strong interaction with the other PMMA block segment, which reduced water resistance to the PVDF polymer solution during phase separation. FT-IR and XPS studies showed carbonyl groups of BCs in the PVDF membranes. Obtained membranes showed porous surface layer and finger-like pore structures on the sublayers, of which sizes were increased with the increase of BC contents. Obtained membranes showed MWCO with 100K PEO and the best water flux was achieved in the PVDF membrane with BC/LiCl additive and improved the anti-fouling property for BSA protein.

A new method for enhancing condensable gas-induced plasticization resistance of aromatic polyimides (PIs) as well as increasing the flux of gas penetrants with negligible selectivity loss was demonstrated via a so-called bromination/debromination-induced thermal crosslinking. Our newly developed crosslinking approach essentially loosened the polymeric chain packing of 6FDA-Durene PIs by forming ethylene crosslinking bonds, while retaining its rigid PI backbone. As the degree of crosslinking increased, the permeability increased with trivial selectivity loss. As a result, outstanding separation performances for CO2/N2, CO2/CH4 and C3H6/C3H8 gas pairs have been obtained, and most importantly, a high tolerance to CO2 or C3H6 induced plasticization was observed.

Sulfonated poly(arylene ether sulfone) (SPAES) random copolymers have been perceived as alternatives to perfluorinated sulfonic acid (PFSA) ionomers owing to their cheap production cost and low hydrogen permeability. In spite of their advantages, there are some issues to overcome such as membrane durability and relatively low proton conductivity in the low humidity range. An approach to solve these problems is to fill SPAES copolymers into porous support films (e.g., poly(tetra fluoro ethylene), PTFE). However, it is difficult to make defect-free pore-filling membranes. In this study, SPAES nanodispersion in a water-alcohol mixture is made under a modified supercritical condition and used to make highly proton conductive and chemical durable SPAES-PTFE pore-filling membranes.