This paper has applied a simple model to the mass transfer mechanism of Cr(VI) with crownether in a batch-type, supported liquid membrane module. Concentration at pH 3 are as follows : 0.012 kmol/m3≤18-crown-6≤0.036 kmol/m3 and 20 g/m3≤ Cr(VI)≤500 g/m3. The measured values of forward- and backward-reaction rate constants between Cr(VI) and 18-crown-6 were used to simulate the model with the mass conservation equation and associated boundary conditions. Comparison between the experimental and simulated facilitated factor of Cr(VI) transport led to classification of reaction regions.
The container terminals in Korea usually adopts both the bar code and the image recognition systems at the gate complex to capture necessary information on containers passing through the gate. With the rapid advancement of Information Technology(IT) these systems, however, seem to make the user not satisfied due to the inherent limitations such as the long process time taken, low rate of recognition etc., This paper, therefore, examines the adoption of Radio Frequency Identification (RFID) technology to container terminals, and tried to get some implication for the way to improve the productivity of the terminal. The results imply that some improvement in the gate and storage yard operation is feasible by the benefit of using the information of vehicles and containers collected in advance by RFID technology.