A Stability to the Spreading solvents, Which is acetonitrile, dichloromethane, benzene, chloroform and acetonitrile-benzene(1:1, v/v) of (3-Alkyl benzimidazolium)-TCNQ(1:1) Complex was investigated by UV-visible Spectrometer and was confirmed stabilized on acetonitrile, acetonitrilbenzene(1:1, v/v) for five hours. Using Ultra pure water as subphase for Langmuir-Blodgett (LB) Films, it was achived successively to fabricate the Y-type LB films of (3-Alkyl benzimidazolium)-TCNQ(1:1) Complex. For the identification of deposition of (3-Alkyl benzimidazolium)-TCNQ(1:1) Complex, UV-visible spectra was recorded on HP 8452A spectrometer.

In this research, (3-alkyl benzimidazalium)-TCNQ complexes were synthesized to obtain the necessary components for Langmuir-Blodgett Technique. (3- Alkyl benzimidazolium)-TCNQ complexes were prepared by the reaction of LiTCNQ with 3-alkyl benzimidazolium bromides and the products were confirmed by elemental analysis. FT-IR, UV-Visible spectroscopies. FT-IR spectra of (3-alkyl benzimidazolium) TCNQ(1:2) complexes were characterized by a broad band with a maximum at about 2900cm-1 appears and were ascribed to electronic rather than vibrational absorption.

The transesterification of dimethylphthalate by 1,4-butanediol was kinetically investigated In the presence of various metal acetate catalysts at 180℃. The quantity of dimethylphthalate reacted in the reaction flask was measured by gas chromatography. The transesterification was assumed to obey first-order kinetics with respect to dimethylphthalate and 1,4-butanediol, and a rate equation was derived. The linear relationship was shown between apparent rate constant and reciprocal absolute temperature, the activation energy has been calculated as 7.4kcal with lead acetate. The maximum reaction rate was appeared at the range of 1.5~1.6 of electronegativity of metal ions.

A Stability to the dispersion solvent, which is acetonitrile, dichloromethane, benzene, chloroform and acetonitrile-benzene(1:1,v/v) of N-docosyl pyridinium)-TCNQ(1:2)complex was investigated by U.V Spectrophotometer and was confirmed stabilized on acetonitrile, the dichloromethane and acetonitrile-benzene (1:1,v/v) for seven hours. Using CdCl2buffer solution as subphase for LB films deposition, it was achived successively to fabricate the Y-type LB films of (N-docosyl pyridinium)-TCNQ(1:2)complex. For the sake of verifying the deposition of LB films, U.V is measured by variation of nominal layer number.

Using CdCl2 buffer solution as subphase for LB films deposition, it was achieved successively to fabricate the Y-type mixed LB films of (N-eicosyl pyridinium)-TCNQ(1:2) complex and arachidic acid. By measure of U.V spectra and capacitance, deposition status was confirmed. Electrical conductivity was measured on a perpendicular direction of the LB films and in consequence of calculated was average 2.5 × 10-13 - 2 × 10-14 S/cm.

Transesterification reactions (methyl methacrylate with monoethanolamine, methyl methacrylate with n-butyl alcohol, dimethylphthalate with ethylene glycol, dimethyl phthalate with monoethanolamine) were kinetically investigated in the presense of various metal acetate catalysts at 110℃. The amount of reactants was measured by gas and liquid chromatography, and the reaction rates also measured from the amount of reaction products and reactants upon each catalyst. The transesterification reactions were carried out under the first order conditions respect to the concentration of reactants, respectively. The overall reaction order was 2nd, Maximum reaction rates were appeared at the range of 1.4 to 1.6 in electronegativity of metal ions and maximum catalytic activities were obserbed at the range of 1.5 to 1,8 in instability constant of metal acetates.

(N-docosyl pyridinium)-TCNQ(1:1) complex was synthesized by reacting N-docosyl pyridinium bromide and LiTCNQ. This complex was investigated and confirmed by elemental analysis. U.V, I.R spectra. A stability to the dispersion solvent, which is acetonitrile, dichloromethane, benzene, chloroform and acetonitrile-benzene (1:1, V/V) of (N-docosyl pyridinium)-TCNQ(1:1) complex was investigated by U. V spectrophotometer and was confirmed stabilized on acetonitrile, benzene and acetonitrile-benzene(1:1'V/V) for 7 hours. Using ultra pure water as subphase for L-B film deposition, the Y-type L-B film of (N-docosyl pyridinium)-TCNQ(1:1) complex was farbricated. The electrical conductivities on a perpendicular direction of the L-B film were measured to be 5×10-5~5×10-14S/cm according to the number of layer.

The transesterification reaction between diethanolamine and methyl methacrylate was kinetically investigated in the presence of various metal acetate catalysts at 120℃. The amount of reacted methyl methacrylate was measured by gas chromatography and liquid chromatography, and the reaction rate also measured from the amount of reaction products and reactants under each catalyst. The transesterification reaction was carried out in the first order with respect to the concentration of diethanolamine and methyl methacrylate, respectively. The over-all order is 2nd. The apparent rate constant was found to obey first-order kinetics with respect to the concentration of catalyst. The maximum reaction rate was appeared at the range of 1.4 to 1.6 of electronegativity of metal ions and instability constant of metal acetates.

The transesterification reaction between diethanolamine and methyl-methacrylate was kinetically investigated in the presence of various metal acetate catalysts at 120℃. The quantity of methylmethacrylate reacted in the reaction flask was measured by gas chromatography and liquid chromatography, and the reaction rate was investigated by measuring of the quantity of products and reactnts under various catalysts. The transesterification reaction was carried out in the first order reaction kinetics with respect to the concentration of diethanolamine and methylmethacrylate, respectively. The apparent rate constant was found to obey first-order kinetics with respect to the concentration of catalyst. The linear relationship was shown between apparent rate constant and reciprocal absolute temperature, and by the Arrhenius plot, the activation energy has been calculated as 11.08 Kcal with zinc acetate catalyst, 17.99 Kcal without catalyst. The maximum reaction rate was appeared at the range of 1.4 to 1.6 of electronegativity of metal ions and instability constant of metal acetates.