We have performed a systematic study of interstellar dust grains in various environments of galaxies. AKARI has revealed the detailed properties of dust grains not only in star-forming regions but also in regions not relevant to star formation, some of which are found not to follow our old empirical knowledge. Because of its unique capabilities, AKARI has provided new knowledge on the processing of large grains and polycyclic aromatic hydrocarbons (PAHs). For example, we detect PAHs from elliptical galaxies, which show unusual spectral features and spatial distributions, demonstrating importance of material processing in the interstellar space. We find that copious amounts of large grains and PAHs are flowing out of starburst galaxies by galactic superwinds, which are being shattered and destroyed in galactic haloes. We discover evidence for graphitization of carbonaceous grains near the center of our Galaxy, providing a clue to understanding the activity of the Galactic center. We review the results obtained from our AKARI program, focusing on the processing of carbonaceous grains in various environments of galaxies.

We present the results of far-infrared spectral mapping of the Galactic center region with FIS-FTS, which covered the two massive star-forming clusters, Arches and Quintuplet. We find that two dust components with temperatures of about 20 K and 50 K are required to fit the overall continuum spectra. The warm dust emission is spatially correlated with the [OIII] 88 μm emission and both are likely to be associated with the two clusters, while the cool dust emission is more widely distributed without any clear spatial correlation with the clusters. We find differences in the properties of the ISM around the two clusters, suggesting that the star-forming activity of the Arches cluster is at an earlier stage than that of the Quintuplet cluster.

We present the results of far-infrared spectroscopic observations of the Large Magellanic Cloud (LMC) with FIS-FTS. We covered a large area across the LMC, including 30 Doradus (30 Dor) and N44 star-forming regions, by 191 pointings in total. As a result, we detect the [OIII] and [CII] line emission as well as far-infrared dust continuum emission throughout the LMC. We find that the [OIII] emission is widely distributed around 30 Dor. The observed size of the distribution is too large to be explained by massive stars in 30 Dor, which are assumed to be enshrouded by clouds with the constant gas density estimated from the [OIII] line intensities. Therefore the surrounding structure is likely to be highly clumpy. We also find a global correlation between the [OIII] and the far-infrared continuum emission, suggesting that the gas and dust are well mixed in the highly-ionized region where the dust survives in clumpy dense clouds shielded from energetic photons. Furthermore we find that the ratios of [CII]/CO are as high as 110,000 in 30 Dor, and 45,000 even on average, while they are typically 6,000 for star-forming regions in our Galaxy. The unusually high [CII]/CO is also consistent with the picture of clumpy small dense clouds.

Among the AKARI all-sky survey data, the 9 μm diffuse map is crucial to study the polycyclic aromatic hydrocarbon (PAH) emission features on large spatial scales, while the 18 μm map is useful to trace hot dust emission. To utilize these advantages, we have improved the AKARI mid-infrared (MIR) all-sky survey diffuse maps. For example, we have established special methods to remove the effects of the ionizing radiation in the South Atlantic Anomaly (SAA) and of the scattered light from the moon. Using improved diffuse map data, we study the properties of PAHs and dust in the Galactic center region associated with high-energy phenomena.