Free-standing hybridized electrode consisting of double-walled carbon nanotubes (DWNTs) and activated carbon have been fabricated for flexible supercapacitor applications. The xanthan-gum, used in our methodology, showed high ability in dispersing the strongly bundled DWNTs, and was then effectively converted to activated carbon with large surface area via chemical activation. The homogeneously dispersed DWNTs within xanthan-gum derived activated carbon acted as both electrical path and mechanical support of electrode material. The hybridized film from highly dispersed DWNTs and activated carbon was mechanically strong, has high electrical conductivity, and exhibited high specific capacitance of 141.5 F/g at the current density of 100 mV/s. Our hybridized film is highly promising as electrode material for flexible supercapacitors in wearable device.

The importance of nanopore structures of carbons is shown in terms of interaction potential for various molecules including supercritical gases such as H2 and CH4. The key factors for adsorption of supercritical H2 and CH4 are shown for single wall carbon nanohorn, single wall carbon nanotube, and double wall carbon nanotube. The cluster formation of molecules is a key process for water adsorption on hydrophobic carbon nanopores. The X-ray absorption spectroscopic examination elucidates an explicit dehydration structure of ions confined in carbon nanopores.