Exploring cheap and efficient oxygen evolution reaction (OER) catalysts is extremely vital for the commercial application of advanced energy storage and conversion systems. Herein, a self-supporting Co3S4/ S-doped reduced graphene oxide ( Co3S4/S-rGO) film catalyst is successfully prepared by a blade coating coupled with high-temperature annealing strategy, and its morphology, structure and composition are measured and analyzed. It is substantiated that the as-synthesized Co3S4/ S-rGO film possesses unique self-supporting structure, and is composed of uniformly dispersed Co3S4 nanoparticles and highly conductive S-rGO, which benefit the exposure of catalytic sites and electron transfer. By reason of the synergistic effect of the two individual components, the self-supporting Co3S4/ S-rGO film catalyst displays outstanding catalytic performance towards OER. As a consequence, the Co3S4/ S-rGO film catalyst delivers an overpotential of 341 mV at 10 mA cm-2, and the current attenuation rate is only 2.6% after continuous operation for 4 h, verifying excellent catalytic activity and durability. Clearly, our results offers a good example for the construction of high-performance self-supporting carbon-based composite film catalysts for critical electrocatalytic reactions.

Transition-metal phosphides (TMPs), a promising anode material for lithium-ion batteries (LIBs), are limited in application because of its serious volume effect in the cycle. In this work, a simple electrospinning strategy was proposed to restrict the grain size of CoP nanocrystals by nano-confined effect of carbon nanofibers with ligands. The addition of ligands not only could realize the uniform dispersion of CoP nanocrystals, but also strengthen the bond between the metals and carbon nanofibers. As a result, the CoP/CNF composite exhibits excellent lithium storage performance, and its reversible specific capacity could reach 1016.4 mAh g− 1 after 200 cycles at a current density of 200 mA g− 1. The research is anticipated to provide a new idea for the preparation of anode materials for lithium ion batteries.