This facility was developed to investigate the characteristics of metal oxide and to secure operational technology through hydrogen supply to 100 kW capacity transferred arc plasma torch and melting furnace under anoxic conditions. Besides, the emission of pollutants generated during operation was minimized by burning the exhaust gases in the next combustion chamber and by applying a SNCR, a scrubber, etc. The main target object was determined as a metal oxides generated as radioactive wastes when dismantling the nuclear power plant. The metal alloy was produced by supplying hydrogen during the melting process of the metal oxide. The reaction equation is as follows: Fe + M(Metal)On + H2(Gas) → FeM + Slag + H2O In this paper, operating conditions according to the melting temperature and hydrogen supply with iron and metal oxides were investigated, and the chemical characteristics of the alloyed metal and Slag were analyzed. The result of this study can be used as fundamental data for the treatment and disposal of metal wastes.