Recently, membrane can be prepared by two methods, phase inversion and electrospinning techniques. Phase inversion technique is a conventional but commercially preparation membrane. The most versatile of preparation in this technique is immersion of the cast film into nonsolvent bath, causing dense top layer with a finger-like pattern in the sub layer membrane. The membrane pore size getting from phase inversion is in the range of micro or submicrometer. As a result, it can be used as microfiltration and ultrafiltration applications. A new technique, electrospinning, is introduced for membrane preparation. Nonwoven nanofibrous mat or nanofibrous membrane is obtained. In this technique, electrostatic charge is introduced to the solution jet, causing a thin fiber with high surface area; hence it can be used in the applications where high surface area-to-volume or length-to-diameter ratios are required. Moreover, the pore size can be controlled by controlling the time of electrospinning. Hence, it can be used as a filter for filtering microparticles as well as nanoparticles.