Polycyclic aromatic hydrocarbons (PAHs) are considered to be carriers of the unidentified infrared bands, which are ubiquitously observed in the Universe. PAHs are mainly formed around evolved carbon-rich stars and injected into interstellar space. Planetary nebulae (PNe), a late stage of low- and intermediate stellar mass evolution, are suitable objects to investigate the formation and evolution of PAHs. The shortest PAH feature is located in 3.3 μm, which is important to examine the excitation and size distribution of PAHs. While the number of samples had been limited before, the high sensitivity of AKARI/IRC has drastically increased the number of samples. We obtained the 2-5 μm spectra of Galactic PNe with AKARI/IRC and compiled a near-infrared spectral catalog, containing 73 PNe. We investigate the detection rate and the evolution of the PAH features. The characteristics of the catalog are illustrated and the origin of the evolution of the PAH features is discussed.

We present the results of the near-infrared (NIR) to mid-infrared (MIR) slit spectroscopic observations of the diffuse emission toward nine positions in the nearby irregular galaxy Large Magellanic Cloud (LMC) with the Infrared Camera (IRC) on board AKARI. The unique characteristic of AKARI/IRC provides a great opportunity to analyze variations in the unidentified infrared (UIR) bands based on continuous spectra from 2.5 to 13.4 μm of the same slit area. The observed variation of I3.3 / I11.3 suggests destruction of small-sized UIR band carriers, polycyclic aromatic hydrocarbons (PAHs) in harsh environments. This result demonstrates that the UIR 3.3 μm band provides us powerful information on the excitation conditions and/or the size distribution of PAHs, which is of importance for understanding the evolutionary process of hydrocarbon grains in the Universe. It also suggests a new diagnostic diagram of two band ratios, such as I3.3 / I11.3 versus I7.7 / I11.3 , for the interstellar radiation conditions. We discuss on the applicability of the diagnostic diagram to other astronomical objects, comparing the LMC results with those observed in other galaxies such as NGC 6946, NGC 1313, and M51.