To improve the lithium-ion battery performance and stability, a conducting polymer, which can simultaneously serve as both a conductive additive and a binder, is introduced into the anode. Water-soluble polyaniline:polystyrene sulfonate (PANI:PSS) can be successfully prepared through chemical oxidative polymerization, and their chemical/mechanical properties are adjusted by varying the molecular weight of PSS. As a conductive additive, the PANI with a conjugated double bond structure is introduced between active materials or between the active material and the current collector to provide fast and short electrical pathways. As a binder, the PSS prevents short circuits through strong π‒π stacking interaction with active material, and it exhibits superior adhesion to the current collector, thereby ensuring the maintenance of stable mechanical properties, even under high-speed charging/discharging conditions. Based on the synergistic effect of the intrinsic properties of PANI and PSS, it is confirmed that the anode with PANI:PSS introduced as a binder has about 1.8 times higher bonding strength (0.4 kgf/20 mm) compared to conventional binders. Moreover, since active materials can be additionally added in place of the generally added conductive additives, the total cell capacity increased by about 12.0%, and improved stability is shown with a capacity retention rate of 99.3% even after 200 cycles at a current rate of 0.2 C.
2022년 10월부터 2023년 5월까지 친환경 딸기재배 농가에서 점박이응애는 칠레이리애응애와 사막이리응애, 진딧물은 콜레마니진디벌을 대상으로 하는 천적처리구와 유기농자재를 사용하는 관행방제구에서 천적의 해 충 밀도억제 효과를 조사하였다. 천적처리구에서 점박이응애 성충 밀도는 잎당 1.5마리 이하, 알은 4개 이하로 관리되었고, 사막이리응애는 잎당 최대 0.4마리까지 증가하여 점박이응애 밀도억제에 많은 영향을 미친것으로 보인다. 반면, 관행방제구에서 점박이응애 밀도는 천적 방사구에 비하여 오히려 많은 발생량을 보였지만, 3월 9일부터는 사막이리응애의 증가와 유기농자재의 효과로 점박이응애 밀도는 급격하게 감소하였다. 진딧물 천적 처리구에서 진딧물 밀도는 1월부터 발생하였으며 3월 상순에 잎당 0.3마리까지 증가하였으나 이후 감소하였고, 콜레마니진디벌은 진딧물 발생이 많지 않아 3.9마리/㎡(2회) 방사하는 데 그쳤다. 한편, 관행방제구 포장의 진딧 물은 유기농자재의 영향으로 거의 발생하지 않았다.
We investigated the behavioral attractive responses of a lepidopteran larva parasite, Exorista japonica to 10 synthetic herbivore-induced plant volatiles (HIPVs). These synthetic HIPVs have been revealed the attractive effect on several parasites. For each of the HIPVs, we asked the following two questions : (1) Which volatiles show the attractiveness to this parasitoid, (2) Whether the attractant directly or indirectly affects the host settlement and parasitism of the parasitoid. To experimentally address these questions, we performed 2 and 4 choice indoor cage tests. E. japonica adults were significantly attracted to benzaldehyde and (Z)-3-hexen-1-ol showing higher settlement and parasitic rates on Spodoptera litura of treatments. Compared to the untreated plots, the average parasitism of E. japonica on S. litura larvae in the benzaldehyde treatments increased by approximately 20%.