Photocatalytically splitting water into hydrogen upon semiconductors has tremendous potential for alleviating environmental and energy crisis issues. There is increasing attention on improving solar light utilization and engineering photogenerated charge transfer of TiO2 photocatalyst because it has advantages of low cost, non-toxicity, and high chemical stability. Herein, oxygen vacancies and cocatalysts (Cu and MoS2) were simultaneously introduced into TiO2 nanoparticles from protonic titanate by a one-pot solvothermal method. The composition and structure characterization confirmed that the pristine TiO2 nanoparticle was rich in oxygen vacancies. The photocatalytic performances of the composites were evaluated by solar-tohydrogen evolution test. The results revealed that both Cu-TiO2 and MoS2- TiO2 could improve the photocatalytic hydrogen evolution ability. Among them, 0.8% Cu-TiO2 showed the best hydrogen evolution rate of 7245.01 μmol·g−1·h−1, which was 3.57 and 1.34 times of 1.25% MoS2- TiO2 (2726.22 μmol·g−1·h−1) and pristine TiO2 material (2028.46 μmol·g−1·h−1), respectively. These two kinds of composites also had good stability for hydrogen evolution. Combined with the results of photocurrent density and electrochemical impedance spectra, the incorporation of oxygen vacancies and cocatalysts (Cu and MoS2) could not only enhance the light-harvesting of TiO2 but also improve the separation and transfer capabilities of light-induced charge carriers, thus promoting water splitting to hydrogen.
Purpose – This research aims to examine the effects of 3D online products presentation by comparing it with general presentation. Research design, data, and methodology – To rigorously investigate the differences of effects between 3D presentation and general presentation, this study examines the differences of the two presentations in vividness, informedness, entertainment, product trust, and purchase intention. This research designed two different forms of online product presentations, 3D and general presentation for an experiment. Results – The research findings indicate that 1) the vividness of online product presentation has a positive impact on the informedness and entertainment. While both vividness and informedness product presentation have a positive impact on product trust, the entertainment of online product presentation has no significant impact. 2) Vividness, informedness, entertainment, product trust, and purchasing intention showed significant differences between 3D and general product presentations. 3) Overall, 3D product presentation showed a stronger impact on purchasing intention than the general product presentation. Conclusions – This research expands the area of business presentation by comparing the differences of 3D and general presentation methods. This study made a great contribution to theory development, and also to guidelines for practice. These insights could be used by organizations in developing realistic environments for business presentations.