We have mapped the W 3 giant molecular cloud in the C0 3P1-3 Po ([CI]) line with the Mount Fuji Submillimeter-wave Telescope. The [CI] emission is extended over the molecular cloud, having peaks at three star forming clouds; W 3(Main), W 3(OH), and AFGL 333. The [CI] emission is found to be strong in the AFGL 333 cloud. We have also observed the C18O, CCS, N2H+, and H13CO+ lines by using the Nobeyama Radio Observatory 45 m telescope. In the AFGL 333 cloud, we find two massive cores, which are highly gravitationally bound and have no sign of active star formation. The high [Co]/[CO] and [CCS]/[N2H+] abundance ratios suggest that the AFGL 333 cloud is younger than the W 3(Main) and W 3(OH) clouds.