In this paper, fly ash was investigated as a basic Si-Al ingredient of geopolymer. Based on compressive and flexural strength, the replacement percentage of fly ash and 3 types of curing regimes were studied to obtain the optimum synthesis condition. The results showed that geopolymer containing 30% fly ash that was prepared at 80˚C for 8 hours, exhibited high mechanical strength. The compressive and flexural strength of the fly ash based geopolymer were 32.2 and 7.15MPa, respectively. In order to investigate the durability behavior of fly ash based geopolymer concrete, CI permeability, freeze-thaw tests were also carried out. The measured results indicated that fly ash based gopolymer concrete had 2.63 times lower coefficient of chloride-ion diffusion and could withdraw 2.2 times more freeze-thaw cycles as compared to Portland concrete with the same compressive strength.