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        검색결과 2

        1.
        2022.08 KCI 등재 구독 인증기관 무료, 개인회원 유료
        With the aim to fabricate flexible, mobile, and low-energy powered electronics, laser treatment of paper-based materials from carbon, cellulose, and natural products may be viable as one of the strategies to achieve this objective as it potentially provides a sustainable and precise patterning of a graphene-based circuit for various emerging electronic applications, such as sensor, robot, energy, and memory devices. Irradiation of high-energy beam for induction of porous-rich graphene or reduction of graphene oxide is easily accomplished from a commercially available laser machine with various laser sources, power, and pulse number setting. Moreover, the process itself can easily be adapted in the various manufacturing sectors due to the technology’s maturity status and its ability to be computer programmed. In comparison to environmental-benign polymer, the selection of paper as a substrate for electronics may introduce a new idea into the design possibility of electronic devices since the paper is not only thin, lightweight, biodegradable, and mechanically stable, but is also able to be assembled into another form and shape simply by traditional origami and kirigami technique for many applications. Here, in this work, recent laser processing strategies for the preparation of graphene either from graphitization of cellulose or deoxygenation of graphene oxide for green electronics are reviewed with brief coverage of the deposition technique of graphene oxide paper prior to laser annealing and discussion on the emerging relevant electronics field that benefitted greatly from the laser-assisted fabrication. To conclude the literature study, a remaining challenge, and prospective outlooks of laser writing of graphene on paper are also highlighted.
        5,400원
        2.
        2020.08 KCI 등재 구독 인증기관 무료, 개인회원 유료
        A liquid-phase exfoliation of few-layer graphene in tea is considered as one of the alternative approaches for the preparation of environment-friendly graphene. However, the removal of chemically adsorbed tea-polyphenols from graphene is known to be difficult and the application of centrifugation or filtration alone for the purification of graphene against tea-polyphenols is regarded to be almost technically impossible. Notably, a strategy for facile deoxygenation of tea-graphene must be established for a green and economical production of graphene to be realized. In this work, a simple purification method of graphene through the application of merely a household bleach ( Clorox®) after the pre-exfoliation in black tea has been proposed. It has been found that the carbon–oxygen (C/O) value for graphene increases from 2.7 to 8.1 while the values of C–OH, C–O–C and C=O region in the C1s spectrum of graphene decrease significantly after being purified in bleach for 5 h. The stretching and shift of C–OH, C=O and C–O–C at 3468 cm−1, 1637 cm−1 and 1008 cm−1 from IR spectrum of purified graphene seems to be in agreement with the produced data from the XPS and Raman spectroscopy. Despite the enhanced ID/IG of Raman from the hybridization of sp2 by hydroxylation, the deoxygenation of tea-graphene does not negatively affect the electrical performance since the sheet resistance was impressively reduced to 193 Ω from 2.1 kΩ. It is believed that this photo-Fenton-inspired purification strategy would assist in the washing issue of polyphenol-stabilized graphene for various future electronic applications.
        4,000원