Small gas bubbles are used in many environmental and industrial processes for solid-liquid separations or to facilitate heat and mass transfer between phases. This study examines some of the factors that affect the bubble volume and size processed in the EF (electroflotation) process. The effect of electrode material, NaCl dosage, current and electrode distance were studied. The results showed that the generated bubble volume with electrode material lay in: Pt/Ti ≒ Ru/Ti ≒ Ir/Ti > Ti electrode. The more NaCl dosage was high, the smaller bubble was generated due to the low electric power. Bubble generation was increased with increase of current. With the increase of NaCl dosage, bubble generation was increased at same electric power (16.2 W). Generated bubble volume was not affected by electrode distance. However, no clear trends in bubble size as a function of these parameters were evident.