CaAl2O4:RE3+(RE = Tb or Dy) phosphor powders were synthesized with different contents of activator ions Tb3+ and Dy3+ by using the solid-state reaction method. The effects of the content of activator ions on the crystal structure, morphology, and emission and excitation properties of the resulting phosphor particles were investigated. XRD patterns showed that all the synthesized phosphors had a monoclinic system with a main (220) diffraction peak, irrespective of the content and type of Tb3+ and Dy3+ ions. For the Tb3+-doped CaAl2O4 phosphor powders, the excitation spectra consisted of one broad band centered at 271 nm in the range of 220-320 nm and several weak peaks; the main emission band showed a strong green band at 552 nm that originated from the 5D4→ 7F5 transition of Tb3+ ions. For the Dy3+-doped CaAl2O4 phosphor, the emission spectra under ultraviolet excitation at 298 nm exhibited one strong yellow band centered at 581 nm and two weak bands at 488 and 672 nm. Concentration-dependent quenching was observed at 0.05 mol of Tb3+ and Dy3+ contents in the CaAl2O4 host lattice.

콘크리트 내에서 염소이온을 고정 및 침투 억제할 수 있는 CA계 클링커의 상호간의 영향을 파악하기 위하여 CA(CaAl2O4)와 CA2(CaAl4O7)을 혼입하여 실험체를 제작하였다. 실험수준은 W/C 50%로 28일간 수중양생 진행되었고 클링커는 시멘트 중량대비 10%로 설정되었다. 평가결과 CA의 혼입율이 증가 할수록 초결이 빨랐지만 장기강도 발현이 감소했고, 시멘트 매트릭스 내부 공긍률이 증가했다. XRD분석결과 CA계 클링커를 혼입한 실험체에서 하이드로 칼루마이트 생성이 증가 한 것으로 보아 염소이온고정능력이 향상될 것 이라고 판단된다