Kori Unit 1 was permanently shut down in 2017 and is preparing to be dismantled. Decommissioning nuclear power plants is expected to generate a lot of decommissioning waste. Therefore, a radioactive waste treatment complex will be built on the site to safely and effectively the process of decommissioning waste generated from the Kori Unit 1, and the details are specified in the decommissioning plan. Therefore, a safety assessment should be conducted according to the facility’s normal and abnormal operations to construct a radioactive waste treatment complex. Currently, a safety assessment for a radioactive waste treatment complex can be conducted by the Safety Assessment Framework (SAFRAN) Tool based on the Safety Assessment Driving Radioactive Waste Management Solutions (SADRWMS) methodology developed by the International Atomic Energy Agency (IAEA). The SAFRAN Tool can be calculated radiation dose and hazard quotient (HQ) for workers and the public under normal and abnormal conditions of the radioactive waste treatment complex. When evaluating the radiation dose for the public due to releasing radioactive materials into the air or discharging radioactive materials into liquids, the radiation dose is calculated using the amount discharged or released from the treatment complex, and the Pathway Dose Factors (PDFs) derived from the generic environmental model given in the IAEA Safety Reports Series No.19. PDFs, which reflect the specific site data rather than the generic environmental model data, should be calculated and evaluated when performing the safety evaluation of the radioactive waste treatment complex to be built on the Kori site. In addition, in the SAFRAN tool, there is an inconvenience in that it must be calculated separately by radionuclides to calculate the contribution of dose or HQ for each radionuclide. Therefore, in this study, a safety assessment tool for a radioactive waste treatment complex was developed using Visual Basic by supplementing the limitations of the SAFRAN tool. This tool was developed to allow users to choose whether to apply PDFs based on the IAEA SRS-19 based on the generic environmental model or PDFs calculated to reflect the specific site data. Furthermore, the tool considered all types of decommissioning wastes that may occur during the decommissioning of the Kori Unit 1 and the treatment process scheduled to be introduced. Therefore, this study is expected to be used as basic data when conducting the safety assessment of radioactive waste treatment complex scheduled to be introduced in Korea.