체인 형태의 코발트(Co) 메조스피어를 템플레이트로 활용하여 금(Au) 및 팔라듐(Pd) 전구체와의 2단계 갈바닉 치환 반응을 통해 비백금 기반의 AuPd 복합 촉매를 합성하였다. NaAuCl4 전구체로부터 합성된 AuPd-Cl(50) 촉매는 높은 비표면적과 다공성 구조를 통해 산소환원반응(ORR)에서 우수한 촉매 활성을 나타냈으며, 상용화된 Pt-20/C 및 Pd-20/C 촉매 대비 낮은 개시(onset) 전위와 높은 한계 전류 밀도 및 향상된 n 값을 보였다. Koutecky-Levich plot 분 석 결과, ORR이 4-전자 전달 메커니즘에 근접함을 확인하였으며, 메탄올 내성과 안정성 실험에서도 우수한 성능을 보였다. AuPd-Cl(50) 촉매는 경제적이고 효율적인 백금 대체 촉매로서 알칼리 연료전지 및 메탄올 기반 연료전지 응 용 가능성을 제시한다.

Electrochemical oxidation and reduction reactions are fundamental in various conversion and energy storage devices. Functional materials derived from MOFs have been considered promising as electrical catalysts for ORR, HER, and OER, which can be used in Zinc-air batteries and water electrolysis. Herein, we designed a novel approach to fabricating the ultrafine Co9S8 embedded nitrogen-doped hollow carbon nanocages ( Co9S8@N-HC). The method involved a process of sulfidation of cobalt-based metal–organic frameworks (ZIF67) and then coating them with polypyrrole (PPy). PPy has notable properties such as high electrical conductivity and abundant nitrogen content, rendering it highly promising for catalytic applications. The Co9S8@ N-HC catalyst was successfully synthesized via the carbonization of CoSx@ PPy. Remarkably, the Co9S8@ N-HC catalyst demonstrated exceptional electrocatalytic activity, requiring only low overpotentials of 285 mV and 201 mV at 10 mA cm‒ 2 for OER and HER, respectively, and exhibited high activity for ORR, with an onset potential ( Eonset) of 0.923 V and half-wave potential ( E1/2) of 0.879 V in alkaline media. The electrocatalytic efficiency displayed by Co9S8@ N-HC opens a new line of research on the synergistic effect of MOF-PPy materials on energy storage and conversion.

Exploring highly efficient, and low-cost oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalysts is extremely vital for the commercial application of advanced energy storage and conversion devices. Herein, a series of graphene-like C2N supported TMx@C2N, (TM = Fe, Co, Ni, and Cu, x = 1, 2) single- and dual-atom catalysts are designed. Their catalytic performance is systematically evaluated by means of spin-polarized density functional theory (DFT) computations coupled with hydrogen electrode model. Regulating metal atom and pairs can widely tune the catalytic performance. The most promising ORR/OER bifunctional activity can be realized on Cu2@ C2N with lowest overpotential of 0.46 and 0.38 V for ORR and OER, respectively. Ni2@ C2N and Ni@C2N can also exhibit good bifunctional activity through effectively balancing the adsorption strength of intermediates. The correlation of reaction overpotential with adsorption free energy is well established to track the activity and reveal the activity origin, indicating that catalytic activity is intrinsically governed by the adsorption strength of reaction intermediates. The key to achieve high catalytic activity is to effectively balance the adsorption of multiple reactive intermediates by means of the synergetic effect of suitably screened bimetal atoms. Our results also demonstrate that lattice strain can effectively regulate the adsorption free energies of reaction intermediates, regarding it as an efficient strategy to tune ORR/OER activity. This study could provide a significant guidance for the discovery and design of highly active noble-metal-free carbon-based ORR/OER catalysts.