To evaluate the remediation performance of recycled oyster shell powders to control nutrients release from polluted sediments. Different types of recycled oyster shell powder were applied on separated bottom sediments. The first type of oyster shell powder is Calcined Oyster Shell Powder (COSP) and another consist of ultrasonicated oyster shell powder (SOSP) which were composed of calcium peroxide. The recycled oyster shell powders were improving the water quality as slow oxygen releasing compound. The experimental results indicated that the Dissolved Oxygen (DO) in the treated columns were higher than the control column. pH was increased in the both experimental columns due to the hydrolysis of CaO2. Meanwhile, recycled oyster shell powders could prevent the nutrients (nitrogen and phosphorus) release from sediments into the overlying water. In addition, the total nitrogen and total phosphorus concentrations of the COSP applied column were decreased 27% and 20% compared to the control column respectively and the SOSP applied column were decreased 33% and 27% compared to control in the overlying water. It was proved that, COSP and SOSP can effectively adsorb phosphorus from sediments and prevent phosphorus release into overlying water from bottom sediments. In conclusion, COSP and SOSP applications was increased DO in the overlying water and nutrient released controlled effectively from the sediment.
This study was performed to investigate the possible uses of waste sludge for the removal of heavy metal ions. The adsorption experiments were conducted with wastes such as sewage treatment sludge, water treatment sludge and oyster shell to evaluate their sorption characteristics. Heavy metals selected were cadmium, copper and lead. In the sorption experiments on the sewage treatment sludge, water treatment sludge, oyster shell and soil, sorption occurred in the beginning and it reached equilibrium after 40 minutes on the oyster shell and 4 hour on the sewage treatment sludge and water treatment sludge. Results of Freundlich isotherms indicated that sewage treatment sludge could be properly used as an adsorbent for heavy metals and sorption strength of heavy metals was in the order of Pb > Cu > Cd. In the influence of pH on the adsorbents, sorption rate was more than 80% in pH 4 and most of heavy metals were adsorbed in pH 9. Adsorption rate of Cd decreased with decreasing pH and then adsorption rate of Cu was lower in soil.