The purpose of this study is to estimate wet deposition flux and to investigate wet deposition characteristics by using the ADOM model. Wet deposition flux of highly reactive SO2 is estimated by applying observed meteorological parameters and concentrations of chemical species to the ADOM model. Wet deposition is largely dependent on large scale precipitation and cloud thickness. Wet deposition flux of sulfate depends on SO2 oxidation in clouds. When large amount of SO2 is converted to sulfate, deposition flux of sulfate increases, but wet deposition flux of SO2 is small. On the whole, the pattern of sulfate wet deposition flux agrees with the typical pattern of sulfate wet deposition that is high in the summer(July) and low in the winter(January).
The concentrations and wet deposition flux into the sea of heavy metals of precipitation in Pusan area were measured and estimated. The samples were collected by polyethylene bottle(30ℓ) from January to November in 1996, and heavy metals were analyzed by atomic absorption spectrometer.
The concentration order of heavy metals was Al >Fe >Zn >Pb >Mn >Cu >Ni >Cd >Co, and they were high at inland sites and low at coastal sites. The enrichment factors for some metals(Zn, Cu, Pb, Cd), based on crustal Al, were significantly greater than unity, and the order was Cd > Pb > Zn > Cu. This evidence suggests Cd and Pb are derived predominantly from non-crustal sources. Al, Fe and Mn contents showed good correlation with each other. Therefore this enrichment factor indicates similar geochemical behavior of these elements. The annual wet depositional flux(㎎/㎡/yr) from P1 site was as follows: Al (121.1), Fe,(177.2), Zn(12.9), Mn(6.19), Pb(14.4), Cu(0.64), Ni(1.03), Cd(1.02) and Co(1.01).