When a loss of coolant accident which causes a partial or a full drainage in the SFP would happen, Zircaloy-4 spent fuel cladding begin to react with high temperature air, and the heat generates by exothermic reaction between Zircaloy-4 cladding and surrounding air. Due to the heat, the ignition may occur in the surface of Zircaloy-4 cladding. If the Zr-fire phenomenon occurs during the accident in a SFP, the spent fuel cladding and pellets would be severely fragmented and powdered and it may bring about a massive release of radioactive source terms. Therefore, it is crucial to prevent the zirconium fire phenomenon for the spent fuel pool safety. However, a main cause to trigger the zirconium fire was not identified. In order to identify a possible mechanism of the Zr-fire phenomenon, OECD-NEA SFP Project I, II was initiated. In this paper, we reviewed the Zr-fire phenomenon which may occur in the spent fuel pool for complete loss of coolant accident scenario. The Spent Fuel Pool Project (hereinafter SFP project) is the experimental program to investigate the phenomena of spent fuel pool complete loss of coolant accident using a 17×17 PWR fuel assembly. In this section, the zirconium fire phenomenon which was observed from the SFP project is briefly investigated. This paper presented the fuel assembly temperature (i.e. zirconium alloy cladding temperature) and oxygen concentration profile of the SFP project phase-1 ignition test. At around 12.7 hour, the temperature abruptly increased and the oxygen concentration also dramatically decreased. This abrupt temperature escalation is the zirconium fire phenomenon. In order to investigate the mechanism of this zirconium fire phenomenon, behaviors of both temperature and oxygen concentration were fully compared. This paper reviewed the results of OECD-NEA SFP project experiment and then a mechanism of Zr-fire phenomenon was dscussed. It seems that the Zr-fire phenomenon might be a consequence of thermal mismatch between heat generation and dissipation. A large amount of heat might be generated by the air oxidation of Zircaloy-4 spent cladding immediately after the kinetic transition which is a breakaway phenomenon. This paper discussed the relationship between the breakaway phenomenon and the Zr-fire phenomenon in case of air oxidation of Zircaloy-4 spent cladding. This paper presents preliminary findings on the Zr-fire phenomenon from the open experiment data of the prototypic spent fuel severe accident scenario. These findings would enhance the understanding of Zircaloy-4 spent cladding air oxidation and severe accident scenario progression in a SFP.