To synthesize a high-performance photocatalyst, N doped TiO2 nanotubes deposited with Ag nanoparticles were synthesized, and surface characteristics, electrochemical behaviors, and photocatalytic activity were investigated. The TiO2 nanotubular photocatalyst was fabricated by anodization; the Ag nanoparticles on the TiO2 nanotubes were synthesized by a reduction reaction in AgNO3 solution under UV irradiation. The XPS results of the N doped TiO2 nanotubes showed that the incorporated nitrogen ions were located in interstitial sites of the TiO2 crystal structure. The N doped titania nanotubes exhibited a high dye degradation rate, which is effectively attributable to the increase of visible light absorption due to interstitial nitrogen ions in the crystalline TiO2 structure. Moreover, the precipitated Ag particles on the titania nanotubes led to a decrease in the rate of electron-hole recombination; the photocurrent of this electrode was higher than that of the pure titania electrode. From electrochemical and dye degradation results, the photocurrent and photocatalytic efficiency were found to have been significantly affected by N doping and the deposition of Ag particles.