This study investigated the relationship between phonemic awareness ability and performance in English listening comprehension. For the purpose of this research, two tests―a specially designed phonemic awareness test and an English L/C test―were used and a total of 268 high school students (132 males and 136 females) participated in this experiment. The statistical result clearly demonstrated that the ability to identify English phonemes was highly correlated with the English listening ability. It was also shown that there was a significant correlation between the two factors in a group of students showing a high level of L/C ability, whereas no significant correlation for the students with a low level of L/C ability. In addition, no major difference in the correlation was found between the male and female students.