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열전지 양극용 FeS2 분말의 성형성에 미치는 Li2O 첨가 및 열처리의 효과 KCI 등재

Effects of Li2O Addition and Heat-Treatment on Formability of FeS2 Powder for Cathode of Thermal Battery

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한국분말야금학회지 (Journal of Korean Powder Metallurgy Institute)
한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

FeS2 has been widely used for cathode materials in thermal battery because of its high stability and currentcapability at high operation temperature. Salts such as a LiCl-KCl were added as a binder for improving electrical per-formance and formability of FeS2 cathode powder. In this study, the effects of the addition of Li2O in LiCl-KCl binderon the formability of FeS2 powder compact were investigated. With the increasing amount of Li2O addition to LiCl-KClbinder salts, the strength of the pressed compacts increased considerably when the powder mixture were pre-heat-treatedabove 350oC. The heat-treatment resulted in promoting the coating coverage of FeS2 particles by the salts as Li2O wasadded. The observed coating as Li2O addition might be attributed to the enhanced wettability of the salt rather than itsreduced melting temperature. The high strength of compacts by the Li2O addition and pre-heat-treatment could improvethe formability of FeS2 raw materials.

저자
  • 이성민( 한국세라믹기술원 엔지니어링세라믹팀) | 이성민
  • 강승호( 국방과학연구소 국방신기술본부) | 강승호
  • 조성백( 국방과학연구소 국방신기술본부) | 조성백
  • 정해원( 국방과학연구소 국방신기술본부) | 정해원
  • 김성원( 한국세라믹기술원 엔지니어링세라믹팀) | 김성원
  • 이원진( 한국세라믹기술원 엔지니어링세라믹팀) | 이원진
  • 류성수(한국세라믹기술원 엔지니어링세라믹팀) | Ryu, Sung-Soo