간행물

한국환경과학회지 KCI 등재 Journal of Environmental Science International

권호리스트/논문검색
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권호

제23권 제5호 (2014년 5월) 23

ORIGINAL ARTICLE

21.
2014.05 서비스 종료(열람 제한)
In this study, ibuprofen(IBP) degradation by the photochemical (UV/S2O8 2-) and sonochemical (US/S2O8 2-) processes was examined under various parameters, such as UV (10~40±5 W/L) and US (50~90±5 W/L) power density, optimum dosage of persulfate ion (S2O8 2-), temperature (20~60℃) and anions effect (Cl-, HCO3 -, CO3 2-). The pseudo‐first‐order degradation rate constants were in the order of 10-1 to 10-5 min-1 depending on each processes. The synergistic effect of IBP degradation in UV/S2O8 2- and US/S2O8 2- processes could investigated, due to the generation of SO4 - radical. This result can confirm from the produced H2O2 and SO4 2- concentration in each processes. IBP degradation rate affected by the S2O8 2- dosage, temperature, power and anion existence parameters. In particular, IBP degradation rate increased with the increase of the temperature (60℃) and applied power density (UV:40±5 W/L, US:90±5 W/L). On the other hand, anions effect on the IBP degradation was negative, due to the anion play as a the scavenger of radical.
22.
2014.05 서비스 종료(열람 제한)
Seasonal and stational variation of SS and COD were investigated from February 2008 to December 2010 and the relationship between them was discussed. During three years monitoring, SS decreased significantly (46% decline) possibly due to the increase of precipitation and thereby resulting salinity drop. COD on average was the highest in 2009. SS was the highest in autumn and the lowest in winter, and over 72% of SS was FSS. While SS is high in the upper sampling stations of the bay with shallow water, COD values do not show any relationship to the geomorphological characteristics. CODins, which was defined as COD after filtration, ranged 56%(winter) ~ 44.6%(summer) and showed no correlation with SS. It indicates that high SS concentration is not necessarily related to the high CODins. The seasonal CODins/SS data, which can be interpreted as COD density in SS, shows that SS in winter contains the dense COD materials compared to the other seasons.

RESEARCH NOTE

23.
2014.05 서비스 종료(열람 제한)
For the field application of dielectric barrier discharge plasma reactor, a multi-plasma reactor was investigated for the inactivation of microorganisms in sewage. We also considered the possibility of degradation of non-biodegradable matter (UV254) and total organic carbon (TOC) in sewage. The multi-plasma reactor in this study was divided into high voltage neon transformers, gas supply unit and three plasma modules (consist of discharge, ground electrode and quartz dielectric tube). The experimental results showed that the inactivation of microorganisms with treated water type ranked in the following order: distilled water > synthetic sewage effluent >> real sewage effluent. The dissolved various components in the real sewage effluent highly influenced the performance of the inactivation of microorganisms. After continuous plasma treatment for 10 min at 180 V, residual microorganisms appeared below 2 log and UV254 absorbance (showing a non-biodegradable substance in water) and TOC removal rate were 27.5% and 8.5%, respectively. Therefore, when the sewage effluent is treated with plasma, it can be expected the inactivation of microorganisms and additional improvement of water quality. It was observed that the NH4 +-N and PO4 3--P concentrations of sewage was kept at the constant plasma discharging for 30 min. On the other hand, NO3 --N concentration was increased with proceeding of the plasma discharge.
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