Single Chinese character nowadays is the smallest componentfor all Chinese computer systems, however, the system do not recognizethe internal structural, frame details within each characters, whichcreated a big gap on teaching, study, analysis the relationships amongChinese character’s inter-structural with its pronunciation and meanings.This article invited a new reading system by using each character’s internal frame relationship. By adding up hundreds of frame code and structural code into the Chinese characters structural coding system, created a combination and separation two operational system. This type of system given a huge possibilityon study, teach and analysis on characters’internal frame structural, as well as relatively thoroughly solve the Chinese system’s typo issue.