Fe-base superalloy powders with Y2O3 dispersion were prepared by high energy ball milling, followed by sparkplasma sintering for consolidation. High-purity elemental powders with different Fe powder sizes of 24 and 50mm were usedfor the preparation of Fe-20Cr-4.5Al-0.5Ti-O.5Y2O3 powder mixtures (wt%). The milling process of the powders was carriedout in a horizontal rotary ball mill using a stainless steel vial and balls. The milling times of 1 to 5 h by constant operation(350 rpm, ball-to-powder ratio of 30:1 in weight) or cycle operation (1300 rpm for 4 min and 900 rpm for 1 min, 15:1) wereapplied. Microstructural observation revealed that the crystalline size of Fe decreased with an increase in milling time by cyclicoperation and was about 15nm after 3 h, forming a FeCr alloy phase. The cyclic operation had an advantage over constantmilling in that a smaller-agglomerated structure was obtained. The milled powders were sintered at 1100oC for 30 min invacuum. With an increase in milling time, the sintered specimen showed a more homogeneous microstructure. In addition, ahomogenous distribution of Y-compound particles in the grain boundary was confirmed by EDX analysis.

본 연구에서는 poly(vinyl chloride) (PVC)가지형 공중합체 전해질과 헤테로폴리산(HPA)을 이용하여 유무기 합성 전해질막을 제조하였다. poly(vinyl chloride)-g-poly(styrene sulfonic acid) (PVC-g-PSSA)는 PVC의 이차 염소의 직접적인 개시를 이용한 atom transfer radical polymerization (ATRP)로 합성하였다. 이때, HPA 나노입자는 수소 결합을 통해 PVC-g-PSSA 가지형 공중합체와 결합하는 것을 FT-IR spectroscopy를 통하여 확인하였다. 전해질막의 수소이온 전도도는 HPA의 질량 분율이 0.3이 될 때까지 상온에서 0.049에서 0.068 S/cm로 증가하였다. 이것은 HPA 나노입자 고유의 전도도와 가지형 공중합체가 가지고 있는 술폰산의 강화된 산도 때문이라고 추정된다. 합습률은 HPA의 질량 분율이 0.45까지 증가할수록 130에서 84%로 감소하였다. 이것은 HPA나노입자와 고분자 메트릭스 사이의 수소 결합의 상호작용 때문에 물을 흡수하는 site의 수가 감소한 결과라고 볼 수 있다. 열중량 분석결과 HPA의 농도가 증가할수록 전해질막의 열적 안정성이 강화된다는 것을 알 수 있었다.

The problem of supply and transport of sediment from a mountainous catchment is very important in explaining dynamic geomorphology and the hydrological cycle. The discharge of suspended sediment is determined by a morphological system. Human interference to environment is also an important, not negligible factor in sediment production. Moreover, growing concern in recent years for the problems of nonpoint pollution and for the transport of contaminants through terrestrial and aquatic ecosystem,; has highlighted the role of sediment-associated transport in fluvial systems. This study was conducted in forested and quarried catchments in order to clarify the different discharge process and the mechanism of suspended sediment dynamics for each catchment. As a forested catchment, the Yamaguchi River catchment which drains a 3.12 ㎢ area was chosen. On the other hand, the Futagami River basin, which is formed by three subbasins (1.07, 1.59 and 1.78 ㎢), as a quarried catchment was selected. These catchments are situated to the north and east of Mt. Tsukuba, Ibaraki, Japan. The discharge pattern of suspended sediment from the Futagami River basin is more unstable and irregular than that from forested catchment, the Yamaguchi River catchment. Under the similar rainstorm conditions, suspended sediment concentration from quarried catchment during a rainstorm event increases from 43 to 27,310㎎/l. However, in the case of the forested catchment it changes only from nearly zero to 274 ㎎/l. Generally, the supply source of suspended sediment is classified into two areas, the in-channel and non-channel source areas. As a result of field measurements, in the case of the forested catchment the in-channel (channel bed, channel bank and channel margin) is the main source area of suspended sediment. On the other hand, remarkable sediment source area on the quarried catchmen, is the non-channel that is unvegetated ground.