본 연구에서는 상전이법을 이용하여 P(VDF-co-HFP) 분리막의 구조를 조절하였다. Macrovoid 없는 구조를 얻기 위하여 다양한 조건에서 비용매유도상전이(NIPS) 공법으로 분리막을 제막하였으나 고분자의 낮은 결정화 속도로 인해 macrovoid가 생성된다는 것을 관측하였다. 이를 극복하기 위해 증발유도상전이법(EIPS)과 증기유도상전이법(VIPS)을 도입하였으 며 NIPS공법과 함께 제막되었을 때 이상적인 구조를 얻을 수 있다는 것을 확인하였다.
In this study, TMD(Tuned Mass Damper) is installed in a retractable-roof spatial structure in order to investigate dynamic response characteristics according to mass ratio and installed position of TMD on large spatial structures. The example analytical model is generated based on the Singapore sports hub stadium. Twenty eight analytical models are used to investigate optimal installation position of TMD for the example retractable-roof spatial structure using 4 to 16 TMDs. The mass of one TMD is set up 1% of total mass at the example analytical model. Displacement response ratio of model with TMD is compared with that of base model without TMD. It has been found from numerical simulation that it is more effective to install TMD at the edge of the spatial structure rather than to concentrate the TMD at the center of the spatial structure.
수분을 포함한 압축공기는 공압 시스템에서 부식과 관석 등의 여러가지 문 제를 유발하기 때문에 기상 내의 수분을 효율적으로 제거하기 위한 다양한 기술이 개발되어오고 있다. 특히, 분리막을 이용한 제습 방법은 에너지 소비가 작 고, 장치를 소형화할 수 있다는 장점으로 주목받고 있다. 본 연구에서는 제습용 중공사막을 상전이 방적법으로 제조하고, 친수성 또는 소수성으로 표면 개질하였다. 선택도와 투과도 향상을 위하여 기공 구조를 제어하였으며, SEM, 기체 투 과도, 접촉각 측정 등으로 중공사막의 특성을 분석하였다. 또한, 분리막을 모듈 화하여 제습 실험을 수행하였으며, 여러 운전 조건에서의 특성을 확인하였다.
본 연구에서는 물/에탄올 분리 성능이 우수한 모데나이트 제올라이트 분리막을 제조하였다. 모데나이트 분리막은 다공성 알루미나 지지체 표면에 종결정이 분산된 종결정 수용액을 이용하여 침지코팅한 후 1SiO2:0.05Al2O3: 0.76NaOH:40H2O 의 몰비로 제조된 수열용액을 이용하여 170°C에서 24시간 동안 이차성장 시켰다. 이때 종결정 수용액의 농도가 모데나이트 분리막의 미세구조 및 투과증발성능에 미치는 영향에 대하여 분석하였다. 종결정 수용액의 농도를 0.025, 0.05, 0.1, 0.25, 0.5 wt%로 한 후 합성한 경우, b축으로 성장된 바늘 구조의 모데나이트 결정은 농도가 증가할수록 c축으로 성장하는 것을 확인하였다. c축으로 성장 된 분리막의 물/에탄올 분리성능은 > 10000의 선택도와 0.2 kg/m2h의 투과도 를 나타냈다.
Due to rapid development of infrared guided weapon, survivability of armored vehicle is severely threatened. Hence, reduction of susceptibility by lowering infrared signature level is essential to enhance survivability of the vehicle. For this purpose, numerical analysis is conducted to analyze time and spatial characteristics of infrared signature of the vehicle when surface emissivity changes in this study. The analysis shows that the emissivity which produces minimum contrast radiant intensity is significantly altered by time and detecting position. Based on the result, it is concluded that the controlled structures which have different emissivity should be adopted at different region of the vehicle to effectively decrease infrared signature level.
A retractable-roof spatial structure is frequently used for a stadium and sports hall. A retractable-roof spatial structure allows natural lighting, ventilation, optimal conditions for grass growth with opened roof. It can also protects users against various weather conditions and give optimal circumstances for different activities. Dynamic characteristics of a retractable-roof spatial structure is changed based on opened or closed roof condition. A tuned mass damper (TMD) is widely used to reduce seismic responses of a structure. When a TMD is properly tuned, its control performance is excellent. Opened or closed roof condition causes dynamic characteristics variation of a retractable-roof spatial structure resulting in off-tuning. This dynamic characteristics variation was investigated. Control performance of a passive TMD and a smart TMD were evaluated under off-tuning condition.
적외선을 이용한 무기체계의 발달로 인해 항공기의 생존은 큰 위협에 직면해 있다. 따라서 항공기의 생존성 향상을 위해 서 적외선 스텔스 기술이 매우 중요하다. 본 논문에서는 수치해석을 통해 실제 비행환경에서의 항공기 표면온도 및 주위 배 경에 따른 적외선 신호를 분석하고 이를 바탕으로 적외선 스텔스를 위한 항공기 표면 구조체 방사율의 가이드라인을 제시하 고 그 성능을 검증하고자 한다. 수치해석 결과, 주위 배경에 따라서 항공기 표면 방사율을 최적화한다면 항공기와 배경간의 복사대비강도를 감소시킬 수 있음을 확인하였다.
In this study, Stockbridge damper was adopted to reduce the reponses of structures under earthquakes. A finite element analysis software, SAP2000, was used to simulate the structural response and the control device under dynamic loads. A 3 story frame model and the proposed control device, Stockbridge damper, were designed under laboratory conditions. In this research, a pendulum type tuned mass damper (PTMD) was also adopted in order to compare with the Stockbridge damper. Harmonic loads were applied to verity the control performance of both control devices in each mode. In results, it has been found that the Stockbirdge damper decreases significantly the responses of the structure more than the PTMD under the harmonic loadings. The El Centro and Northridge earthquakes were also applied in order to investigate the performance by both control devices. The responses of the building demonstrate that the Stockbridge damper reduces the response of the building structure during earthquakes more effectively than the PTMD.
We report on an all-solution-processed hydrothermal method to control the morphology of ZnO nanostructures on Si substrates from three-dimensional hemispherical structures to two-dimensional thin film layers, by controlling the seed layer and the molar contents of surfactants during their primary growth. The size and the density of the seed layer, which is composed of ZnO nanodots, change with variation in the solute concentration. The ZnO nanodots act as heterogeneous nucleation sites for the main ZnO nanostructures. When the seed layer concentration is increased, the ZnO nanostructures change from a hemispherical shape to a thin film structure, formed by densely packed ZnO hemispheres. In addition, the morphology of the ZnO layer is systematically controlled by using trisodium citrate, which acts as a surfactant to enhance the lateral growth of ZnO crystals rather than a preferential one-dimensional growth along the c-direction. X-ray diffraction and energy dispersive X-ray spectroscopy results reveal that the ZnO structure is wurtzite and did not incorporate any impurities from the surfactants used in this study.
In the case where a MR-damper is employed for vibration control, it is important to decide on how much control capacity should be assigned to it against structural capacities (strength and load, etc). This paper aims to present a MR-damper's control capacity suitable for the capacities of the structure which needs to be controlled. First, a two span bridge was built equipped with a MR-damper, which constitutes a two-span MR-damper control system. Then, inflicting an earthquake load on the system, a basic experiment was performed for vibration control, and a simulation was also carried out reflecting specific control conditions such as MR-damper and rubber bearing. The comparison of the results against each other proved their validity. Then, in order to calculate an optimal control capacity of the MR-damper, structural capacity was divided into eleven cases in total and simulated. For each case, an additional load of 30 KN was inflicted everytime, thereby increasingly strengthening structural capacity. As a result of the study, it was found that the control capacity of MR-damper of 30 KN was safely secured only with lumped mass of more than 150 KN(case 6). Therefore, it is concluded the MR-damper showed the best performance of control when it exerted its capacity at around 20% of structural capacity.
A novel vibration control method for vibration reduction of a spacial structure subjected to earthquake excitation was proposed in this study. Generally, spatial structures have various vibration modes involving high-order modes and their natural frequencies are closely spaced. Therefore, in order to control these modes, a spatially distributed MTMDs (Multiple TMDs) method is proposed previously. MR (Magnetorheological) damper were used to enhance the control performance of the MTMDs. Accordingly, MSTMDs (Multiple Smart TMDs) were proposed in this study. An arch structure was used as an example structure because it has primary characteristics of spatial structures and it is a comparatively simple structure. MSTMDs were applied to the example arch structure and the seismic control performance were evaluated based on the numerical simulation. Fuzzy logic control algorithm (FLC) was used to generate command voltages sent for MSTMSs and the FLC was optimized by genetic algorithm. Based on the analytical results, it has been shown that the MSTMDs effectively decreased the dynamic responses of the arch structure subjected to earthquake loads.
본 연구에서는 평균입경 0.2, 0.5, 1,7㎛ 크기의 α-알루미나 분말을 이용하여 다공성 α-알루미나 지지체의 기공구조를 조절하고자 하였다. 다공성 α-알루미나 지지체는 슬립캐스팅공법을 이용하여 제조한 후 소결하였으며, 이 때 소결 온도가 지지체의 기공특성에 미치는 영향에 대하여 고찰하였다. 제조된 다공성 α-알루미나 지지체는 수은기공분석기를 이용하여 기공크기 및 기공률 등을 분석하였으며, 단일기체투과장치를 이용하여 기체 투과도를 측정하였다. 그 결과 평균입경 0.2, 0.5, 1.7㎛ 크기의 α-알루미나 분말을 이용하여 제조된 지지체는 각각 80, 130, 200㎚의 기공경을 가졌으며, CO2 단일기체에 대해 각각 1300, 1700, 5000GPU를 나타냈다.
Advances made in membrane technology have to do with either enhancing separation efficiency or improving the permeation flux. Enhancing the separation efficiency, however, inevitably led to reducing the flux, and improving the permeation flux resulted in a loss in the separation efficiency. In this presentation, we suggest multiscale porous membranes with inverse-opal structures that allow for high permeation flux without sacrificing separation efficiency. In order to create the multiscale architectured membranes, primary structure of inverse opal having macropores is first prepared. Then, secondary nanostructures are incorporated to elaborately tune the pore size, tortuosity, and interfacial properties. Finally, the constructed multiscale architectures are utilized for water-treatment or removal or organic molecules.
본 연구에서는 평균입경 0.2, 0.5㎛ 크기의 α-알루미나 분말을 이용하여 다공성 α-알루미나 지지체의 기공구조를 조절하고자 하였다. 다공성 α-알루미나 지지체는 슬립캐스팅공법을 이용하여 제조한 후 소결하였으며, 이 때 소결 온도가 지지체의 수축률 및 소결거동 등에 미치는 영향에 대하여 고찰하였다. 제조된 다공성 α-알루미나 지지체는 수은기공분석기를 이용하여 기공크기 및 기공률 등을 분석하였으며, 단일기체투과장치를 이용하여 기체 투과도를 측정하였다. 그 결과 평균입경 0.5㎛ 크기의 α-알루미나 분말을 이용하여 제조된 지지체의 경우, 평균 입경 0.2㎛ 크기의 α-알루미나 분말을 이용하여 제조된 지지체에 비하여 기공크기가 크고 기공률이 높았으며, 기체투과도가 높을 것을 알 수 있었다.
본 논문에서는 헤테로 애피택시(heteroepitaxy) 박막의 표면확산계수를 국부적으로 제어하여 표면에서 형성되는 나노구조물이 정렬되는 과정을 수치해석적으로 연구하였다. 격자 불일치 물질계(lattice-mismatched materials system)의 탄성변형에너지와 표면자유에너지, 그리고 습윤에너지를 고려하여 박막의 변형거동에 대한 지배방정식을 도출하였으며, 확산계수의 활성화 조건이 성장에 미치는 영향을 살펴보았다. 해석결과는 주기함수 형식으로 표면확산계수를 제어하면 표면구조물이 배열형태로 정렬됨을 나타내며, 이는 노광 및 식각 과정을 거쳐야 하는 포토리소그래피(photolithography)로부터 탈피한 바텀업(bottom-up) 방식의 공정방법에 규칙성을 부여하여 차세대 나노기기의 개발에 일조할 것으로 기대된다.
본 연구는 거대고리 금속 이온 착화합물과 유도체를 이용하여 미세 다공성 구조를 가지는 분리막의 제조에 관한 것이다. 고분자와 금속이온 리간드 착물 시스템을 이용함으로써 기존의 방법들에 비해 상 전이 과정을 보다 정교하게 제어할 수 있었다. 금속염, cyclohexanedione dioxime, hydroxyphenylboronic acid와의 축합 반응을 통하여 금속 clathrochelate 착물을 얻을 수 있었다. PES, PVP, BE와 금속 clathrochelate 착물을 DMF에 녹인 후 비용매 유도 상 전이법을 통하여 유무기 혼성 고분자막을 제조하였다. 제조된 분리막의 구조는 FE-SEM과 microflow permporometer로 조사하였다. p-Hydroxyphenyl group 을 가지는 Fe(II) clathrochelate 착물의 첨가는 분리막의 구조에 있어 기공 크기 분산도를 좁혀주고, 표면의 기공 밀도를 높여 주었으며 최대 기공 크기를 감소시킴을 볼 수 있었다.
Spatial structures as like dome structure have the different dynamic characteristics from general rahmen structures. Therefore, it is necessary to accurately analyze dynamic characteristics and effectively control of seismic response of spatial structure subjected to multi-supported excitation. In this study, star dome structure that is subjected to multi-supported excitation was used as an example spatial structure. The response of the star dome structure under multiple support excitation are analyzed by means of the pseudo excitation method. Pseudo excitation method shows that the structural response is divided into two parts, ground displacement and structural dynamic response due to ground motion excitation. And the application of passive tuned mass damper(TMD) to seismic response control of star dome structures has been investigated. From this numerical analysis, it is shown that the seismic response of spatial structure under multiple support seismic excitation are different from those of spatial structure under unique excitation. And it is reasonable to install TMD to the dominant points of each mode. And it is found that the passive TMD could effectively reduce the seismic responses of dome structure subjected to multi-supported excitation.
Pt nanopowder-dispersed SiO2 (SOP) films were prepared by RF co-sputtering method using Pt and SiO2 targets in Ar atmosphere. The growth rate and Pt content in the film were controlled by means of manipulating the RF power of Pt target while that of SiO2 was fixed. The roughness of the film was increased with increasing the power of Pt target, which was mainly due to the increment of the size and planar density of Pt nanopowder. It was revealed that SOP film formed at 10, 15, 20 W of Pt power contained 2.3, 2.7, and 3.0 nm of spherical Pt nanopowder, respectively. Electrical conductivity of SOP films was exponentially increased with increasing Pt power as one can expect. Interestingly, conductivity of SOP films from Hall effect measurement was greater than that from DC I-V measurement, which was explained by the significant increase of electron density.
The paper introduces Multi-Platform Analysis (MPA) for the seismic performance of a structure controlled by Magneto-Rheological (MR) dampers and presents analytical assessment of the effect of MR damper when taking into account nonlinear behavior of the structure. This paper introduces the MR Damper Plugin that can facilitate communication between MATLAB/Simulink and a finite element analysis tool in order to account for more complex inelastic behavior of the structure with MR dampers. The MPA method using the developed MR Damper Plugin is validated with experimental results from the real-time hybrid simulation. By utilizing the proposed MPA method, the three-story RC structure controlled by MR dampers is more realistically modeled and its performance under seismic loads is investigated. It is concluded that MR damper designed for a linear structure is not effective in a nonlinear structure and can overestimate the effect of MR damper. This work is expected to overcome difficulties in the analytical assessment of structural control strategies for complex and nonlinear structures by obtaining more reliable results.
본 연구에서는 원형실린더 후류 와류에 의한 진동을 제어를 위해 적용되는 나선형 뱃전판의 효율향상을 위해 다양한 회전각에 대해 모델실험을 실시하였다.실험은 회류수조에서 레이놀즈수 Re=4.0×103,Re=5.5×103 및 Re=7.0×103에서 균일유입유동에서 2-프레임 그레이레벨 상호상관 PIV기법을 이용하였다.실험결과 원형실린더와 뱃전판을 부착한 실린더와의 비교를 통해..