The need for the development of sustainable, efficient, and green radioactive waste disposal methods is emerging with the saturation of spent nuclear waste storage facilities in the Republic of Korea. Conventional radioactive waste management methods like using cement or glass have drawbacks such as high porosity, less chemical stability, high energy consumption, carbon dioxide production, and the generation of secondary wastes, etc. To address this gigantic issue of the planet, we have designed a study to explore the potential of alternative materials having easy processability, low carbon emissions and more chemical stability such as ceramic (hydroxyapatite, HAP) and alkali-activated materials (geopolymers, GP) to capture the simulated radioactive cobalt ions from the contaminated water and directly solidify them at low temperatures. Physical and mechanical properties of HAP alone and 15wt% GP incorporated HAP (HAP-GP- 15) composite were studied and compared. The surface of both materials was fully sorbed with an excess amount of Co(II) ions in the aqueous system. Co(II) sorbed powders were separated from aqueous media using a centrifuge machine operating at 5,000 RPM for 10 minutes and dried at 100°C for 8 hours. The dried powders were then placed in stainless steel molds, and shaped into cylindrical pellets using a uniaxial press at a pressure of 1 metric ton for 1 minute. The pellets were sintered at 1,100°C for 2 hours at a heating rate of 10°C/min. Following this, the water absorption, density, porosity, and compressive strength of the polished pellets were measured using standard methods. Results showed that HAP has a greater potential for decontamination and solidification of Co(II) due to its higher density (2.65 g/cm3 > 1.90 g/cm3), less open porosity (16.2±2.9% < 42.4 ±0.9%) and high compressive strength (82.1±10.2 MPa > 6.9±0.8 MPa) values at 1,100°C compared to that of HAP-GP-15. Nevertheless, further study with different constituent ratio of HAP and GP at various temperatures is required to fully optimize the HAP-GP matrix for waste solidifications.

A comprehensive understanding of actinide coordination chemistry and its structure is essential in many aspects of the nuclear fuel cycle, such as fuel reprocessing, waste management, reactor safety, and non-proliferation efforts. Managing radioactive waste generated during the nuclear fuel cycle has recently become more important, accordingly increasing the importance of designing appropriate waste forms and storage solutions for long-term waste disposal. Compared to the increase in the need for understanding the chemistry of major radioactive elements, the information on the local structure of the radioactive elements, especially actinides, remains unknown. To probe this issue, X-ray absorption fine structure (XAFS) can be applied. By analyzing the EXAFS (extended X-ray absorption fine structure) and XANES (X-ray absorption near edge structure), the local structure around atoms can be determined. However, the radioactive properties of the nuclides hindered the measurement of EXAFS and XANES, due to the difficulties of preparation, containment, and transfer of the sample. To measure the EXAFS of various compounds regarding the back-end nuclear fuel cycle, laboratory-based EXAFS (hiXAS, HP spectroscopy) has been introduced which can measure the EXAFS and XANES at the energy range of 5-18 keV. Compounds of Copper (Cu foil, CuO samples), Zirconium (Zr foil), and Europium (Eu2O3) were used for the verification of the laboratory -based EXAFS at a given energy range. The measured EXAFS spectrum of various compounds exhibit good agreement with the theoretical data, showing an R-factor of less than 0.02. It was found that each graph has a first peak corresponding to 2.55Å for Cu foil (Cu-Cu), 1.93Å for CuO samples (Cu-O), 3.23Å for Zr foil (Zr-Zr), and from 2.32Å to 2.34Å for Eu2O3 (Eu-O), which agree well with other values from the literature. From the result, it can be implied that this equipment can be used especially in the back-end nuclear fuel cycle field to enhance the understanding of local structure in radiochemistry.

Molten chloride salts have received considerable research attention as potential nuclear fuel and coolant candidates for molten salt reactors. However, there are several challenges, especially for structural materials due to the selective dissolution of chromium (Cr) in the molten chloride salts environment. Understanding the compatibility of uranium (U), which is used as nuclear fuel in molten salt reactors, with Cr in molten chloride salts is critical for designing the molten salt reactor structure. Therefore, in this study, the cyclic voltammetry (CV) was used to investigate the electrochemical behaviors of U and Cr. The diffusion coefficients and formal potentials were obtained. The electrochemical properties of uranium and chromium were investigated by CV in molten NaCl-MgCl2 salt at 600°C. Tungsten rods for working and counter electrode, and Ag/AgCl for reference electrode were utilized in this experiment. UCl3 made from the chemical dissolution of U rods and CrCl2 (Sigma-Aldrich, 99.99%) were used. Diffusion coefficients (D) of U and Cr were calculated by measuring reduction peak current of U3+/U and Cr2+/Cr from CV curves and using the Berzins-Delahay equation; D (U3+/U) = 3.0×10-5 cm2s-1 and D (Cr2+/Cr) = 3.3×10-5 cm2s-1. The formal potentials were also calculated by using the reduction peak potential obtained from CV results; E0’ (U3+/U) = -1.173 V and E0’ (Cr2+/Cr) = -0.321 V. The ionization tendency was investigated by comparing each reduction peak potential. The reduction peak potential Ep,c was increasing order of Ep,c (U3+/U) < Ep,c (Cr2+/Cr) < Ep,c (U4+/U3+). It can be seen that in the presence of U4+ and Cr metals, the Cr in the alloy can dissolve into Cr2+, but in the presence of U3+ and Cr metals, the Cr in the alloy does not dissolve into Cr2+. By analyzing the CV curve, diffusion coefficients and formal standard potentials were obtained. The result of comparing reduction peak potentials suggests that the nuclear fuel using U4+ should be inhibited to prevent the selective dissolution of Cr.

The ultimate objective of deep geological repositories is to achieve complete segregation of hazardous radioactive waste from the biosphere. Thus, given the possibility of leaks in the distant future, it is crucial to evaluate the capability of clay minerals to fulfill their promising role as both engineered and natural barriers. Selenium-79, a long-lived fission product originating from uranium- 235, holds significant importance due to its high mobility resulting from the predominant anionic form of selenium. To investigate the retardation behaviors of Se(IV) in clay media by sorption, a series of batch sorption experiments were conducted. The batch samples consisted of Se(IV) ions dissolved in 0.1 M NaCl solutions, along with clay minerals including kaolinite, montmorillonite, and illite-smectite mixed layers. The pH of the samples was also varied, reflecting the shift in the predominant selenium species from selenious acid to selenite ion as the environment can shift from slightly acidic to alkaline conditions. This alteration in pH concurrently promotes the competition of hydroxide ions for Se(IV) sorption on the mineral surface as the pH increases and impedes the selective attachment of selenium. The acquired experimental data were fitted through Langmuir and Freundlich sorption isotherms. From the Freundlich fit data, the distribution coefficient values of Se(IV) for kaolinite, montmorillonite, and illite-smectite mixed layer were derived, which exhibited a clear decrease from 91, 110, 62 L/kg at a pH of 3.2 to 16, 6.3, 12 L/kg at a pH of 7.5, respectively. These values derived over the pH range provide quantitative guidance essential for the safety assessment of clay mineral barriers, contributing to a more informed site selection process for deep geological repositories.

This program aims to build a specialized and converged educational platform for the training of students in the back-end nuclear fuel cycle and cultivate integrated human resources encompassing majors, generations, and fields. To achieve this, we have established an infrastructure for integrated education and training in the radiochemistry and back-end nuclear fuel cycle and operated specialized educational courses linked with special lectures, experimental practices, and field trips. Firstly, to construct an integrated educational and training infrastructure for the back-end nuclear fuel cycle, we formed a committee of experts from both inside and outside the institution and built an advanced radiochemistry laboratory equipped with physical and chemical analysis instruments. Through a comprehensive educational program involving theory, experiments, and discussions, we have established an integrated curriculum across adjacent majors and interdisciplinary studies. We also operate short-term education and experimental training programs (e.g., summer and winter schools for the back-end nuclear fuel cycle). Secondly, the program has connected leading researchers domestically and internationally, as well as the next generation of scholars. The program offers long-term educational opportunities and internships targeting both undergraduate and graduate students. To support this, we continuously offer expert colloquiums and individual research internships. Through regular committee meetings and workshops, we focus on nurturing the integrated talents necessary for the back-end nuclear fuel cycle. Through this program, students from various fields are being trained as competent integrated human resources capable of addressing various issues in the back-end nuclear fuel cycle. It is expected that this will enable us to supply specialized technical personnel in the back-end nuclear field in line with mid-to-long-term demands.

To construct and operate nuclear power plants (NPPs), it is mandatory to submit a radiation environmental impact assessment report in accordance with Article 10 and Article 20 of the Nuclear Safety Act. Additionally, in compliance with Article 136 of the Enforcement Regulations of the same law, KHNP (Korea Hydro & Nuclear Power) annually assesses radiation environmental effects and publishes the results for operating NPPs. Furthermore, since the legalization of emission plans submission in 2015, KHNP has been submitting emission plans for individual NPPs, starting with the Shin-Hanul 1 and 2 units in 2018. These emission plans specify the emission quantities that meet the dose criteria specified by the Nuclear Safety and Security Commission. Before 2002, KHNP used programs developed in the United States, such as GASPAR and LADTAP, for nearby radiation environmental impact assessments. Since then, KHNP has been using K-DOSE60, developed internally. K-DOSE60 incorporates environmental transport analysis models in line with U.S. regulatory guidance Regulatory Guide 1.109 and dose assessment models reflecting ICRP-60 recommendations. K-DOSE60 is a stand-alone program installed on individual user PCs, making it difficult to manage comprehensively when program revisions are needed. Additionally, during the preparation of emission plans and the licensing phase, improvements to KDOSE60’ s dose assessment methodology were identified. Furthermore, in 2022, regulatory guidelines regarding resident dose assessments were revised, leading to additional improvement requirements. Currently, E-DOSE60, being developed by KHNP, is a network-based program allowing for integrated configuration management within the KHNP network. E-DOSE60 is expected to be developed while incorporating the identified improvements from K-DOSE60, in response to emission plan licensing and regulatory guideline revisions. Key improvements include revisions to dose assessment methodologies for H-13 and C-14 following IAEA TRS-472, expansion of dose assessment points, and changes in socio-environmental factors. Furthermore, data such as site meteorological information and releases of radioactive substances in liquid and gaseous forms can be linked through a network, reducing the potential for human errors caused by manual data entry. Ultimately, E-DOSE60 is expected to optimize resident exposure dose assessment and enhance public trust in NPP operation.

Strategic item export control aims to maintain international peace and safety and serves as a significant nuclear non-proliferation regime that directly impacts a nation’s security. Therefore, establishing an autonomous export control system at the state level is crucial, and one of the most efficient methods to achieve this is by enhancing an export company’s management system. Accordingly, many advanced countries, such as the United States, Europe, and Japan, have operated their own internal compliance programs (CP or ICP) to manage and screen the export of strategic items as a corporate social responsibility and risk mitigation measure. In Korea, which has a high dependence on trade, the need for CP was continuously confirmed, but the system was introduced in 2004, relatively late compared to other advanced countries. So far, the Korean government has made steady efforts to develop and establish the system and is actively encouraging businesses to obtain Compliance Program certification to autonomously manage strategic items. Major technologically advanced countries utilize technology transfer as a tool for economic sanctions, trade security, and strategic technology management, and they continue to strengthen their control regimes. In these countries, CP certification is considered a standard practice for export control among mid-sized and large enterprises. It serves as a vital risk management system that protects companies from unforeseen incidents. However, in Korea, the application of CP under the Foreign Trade Act is limited to dual-use items and does not extend to the nuclear export control system. Therefore, this paper analyzes international cases and CP requirements in countries like the United States, Japan, Europe, and Singapore. As a result of the review, the application of CP into Korea’s nuclear export control could be a coexistence means that can strengthen supply chain control as well as provide benefits not to impede technical research, international trade, and exchanges.

The denuclearization of North Korea was unpredictable and resulted in radical changes. Despite the skepticism and disappointment surrounding denuclearization, it is important for certain verification technologies to establish what is technically possible or practically impossible, and how reliable these technical means are. This article presents the technical hurdles in nuclear verification by systematically categorizing them into issues of correctness and completeness. Moreover, it addresses the safety and security risks during the denuclearization process, including the radiological impact on humans, environmental effects, and the illegal transfer of material, information, and technologies.

The scope of the maintenance of international peace and security has been increasingly widened by the United Nations Security Council in response to actions taken not only by the Member States but also in some cases by the individuals. In fact, a range of actions and decisions were taken by the Security Council, approximately in the late 1990s and after the so-called 9/11 attacks in the context of combating terrorism, as well as in other contexts against the member States. In consequence, the affected States and individuals had to seek redress from international or national courts on different grounds such as violations of human rights. This has led the domestic courts to develop novel jurisprudence. Thus, it is necessary to pay due attention to the jurisprudence created by these courts. This paper is devoted to analysis an interpretation by the High Court of Singapore in relation to sanctions resolutions of the Security Council against Iran.

최근 미-북간 관계 개선 등으로 인하여 북핵 문제가 핵 검증단계로 진전될 것이라는 예상이 나오고 있다. 이제부터 우리 정부는 북핵 프로그램의 성공적 검증·폐기를 위해, 북한의 신고 후 전개될 상황에 대비하여 철저히 준비해야 한다. 본 논문에서는 구소련과 이라크의 대량살상무기 검증·폐기 사례로부터 두 나라의 대량살상무기 검증·폐기 과정에서 발생한 문제점을 조사·분석하여, 북핵 검증·폐기 과정 시 발생할 수 있는 문제점을 파악하고 이를 방지하기 위한 정책적 고려사항을 도출하는데 목적을 두었다.

전세계 주요 원자력선진국들의 사용후핵연료 처리에 대한 기술 및 정책현황을 알아보고 향후 우리나라의 연구방향을 제시해 보았다. 재처리 정책을 가진 소위 핵연료주기 국가들은 최근 선진핵 연료주기기술에 기초한 새로운 사용후핵 연료 관리정책을 발표하였다. 그 정책은 사용후핵연료 내에 함유된 우라늄 또는 초우란 원소들을 재순환하고 고독성의 방사성 물질 및 장반감기를 가진 물질들을 소멸하거나 단반감기 원소로 변환하는데 초점을 맞추고 있다. 이러한 정책은 원자력의 자원 활용성을 높일 뿐만 아니라, 영구 처분할 고준위폐기물의 양을 감소시켜 궁극적으로 원자력의 지속가능성을 높여 준다. PUREX 방법에 기초한 습식재처리를 우선순위로 선택한 대부분의 국가들은 이 습식방법이 건식방법에 비해 실용화에 앞서 있음을 그 선택 의 근거로 든다. 그러나 습식방법은 건식에 비해 핵확산저항성 측면에서 더욱 민감하다. 왜냐하면 이 습식방법은 약간의 공정수정에 의해 순수 플루토늄을 회수 할 수 있기 때문이다. 반면에 아직까지 실용화 단계까지는 도달해 있지 않지만 고온 용융염을 사용하는 Pyroprocess와 같은 건식처리 방법은 순수한 플루토늄을 회수 할 수 없어서 핵비확산성 측면에서 유리하며, 제4세대 원자로로 고려되는 고속로의 핵연료주기 등에도 여러 가지 이점을 가지고 있다. 따라서 우리나라의 경우 현재 이 Pyroprocess에 대한 연구가 활발히 진행되고 있다.