In pyroprocessing, the residual salts (LiCl containing Li and Li2O) in the metallic fuel produced by the oxide reduction (OR) process are removed by salt distillation and fed into electrorefining. This study undertook an investigation into the potential viability of employing a separate LiCl salt rinsing process as an innovative alternative to conventional salt distillation techniques. The primary objective of this novel approach was to mitigate the presence of Li and Li2O within the residual OR salt of metallic fuel, subsequently facilitating its suitability for electrorefining processes. The process of rinsing the metallic fuel involved immersing it in a LiCl salt environment at a temperature of 650°C. During this immersion process, the residual OR salt contained within the fuel underwent dissolution, thereby reducing the concentrations of Li2O and Li generated during the OR process. Furthermore, the Li and Li2O dissolved within the LiCl salt were effectively consumed through chemical reactions with ZrO2 particles present within the salt. Importantly, even after the metallic fuel had been subjected to rinsing in a conventional LiCl salt solution, the concentration of Li and Li2O within the salt remained consistent with its initial levels, due to the utilization of ZrO2. Moreover, it was observed that the Li- Li2O content within the metallic fuel was significantly diluted as a result of the rinsing process.

The thermocatalytic decomposition of methane is a promising method for hydrogen production. To determine the cause of carbonaceous catalyst deactivation and to produce high-value carbon, methane decomposition behavior and deactivated catalysts were analyzed. The surface properties and crystallinity of a commercial activated carbon material, MSP20, used as a methane decomposition catalyst, varied with the reaction time at a reaction temperature of 900 °C. During the initial reaction, MSP20 provided a methane conversion of ≥ 50%; however, the catalyst exhibited rapid deactivation as crystalline carbon grew at surface defects; after 15 min of reaction, approximately 33% methane conversion was maintained. With increasing reaction time, the specific surface area of the catalyst decreased, whereas crystallinity increased. The R-square value of the conversion–crystallinity relationship was significantly higher than that of the conversion–specific surface area relationship; however, neither profile was linear. The activity of the activated carbon catalyst for methane decomposition is mainly determined by the complex actions of the specific surface area and defect sites. The activity was maintained after an initial sharp decline caused by the continuous growth of crystalline carbon product. This study presents the application of carbonaceous catalysts for the decomposition reaction of methane to form COx- free hydrogen, while simultaneously yielding porous carbon materials with an improved electrical conductivity.

This study presents the synthesis, characterization, and utilization of marine macroalgae-derived bio-carbon catalysts (BC and KOH-AC) for the efficient conversion of waste cooking oil (WCO) into biodiesel. The biochar (BC) was produced through slow pyrolysis of macroalgal biomass, which was subsequently activated with potassium hydroxide (KOH) to produce a KOH-modified activated carbon (KOH-AC) catalyst. Advanced characterization techniques, including SEM, EDX, XRD, FTIR, and TGA, were used to examine the physicochemical characteristics of the catalysts. The synthesized catalysts were utilized to produce biodiesel from WCO, and the results revealed that the highest biodiesel yields, 98.96%, and 47.54%, were obtained using KOH-AC and BC catalysts, respectively, under optimal reaction conditions of 66 °C temperature, 12.3 M/O molar ratio, 130 min time, and 3.08 wt.% catalyst loading via RSM optimization. The kinetic and thermodynamic parameters, such as k, Ea, ΔH, ΔS, and ΔG, were determined to be 0.0346 min− 1, 43.31 kJ mol− 1, 38.98 kJ mol− 1, − 158.38 J K− 1 mol− 1, and 92.58 kJ mol− 1, respectively. The KOH-AC catalyst was recycled up to five times, with a significant biodiesel yield of 80.37%. The fuel properties of the biodiesel met ASTM (D6751) specifications, ensuring that it has excellent fuel characteristics and can be used as an alternative fuel.

Owing to the great demand for portable and wearable chemical sensors, the development of all-solid-state potentiometric ion sensors is highly desirable considering their simplicity and stability. However, most ion sensors are challenged by the penetration of water and gas molecules into ion-selective membranes, causing unstable and undesirable sensing performances. In this study, a hydrophobic ionic liquid-modified graphene (Gr) sheet was prepared using a fluid dynamics-induced exfoliation and functionalization process. The high hydrophobicity and electrical double-layer capacitance of Gr make it a potential solid-state ion-to-electron transducer for the development of potentiometric sodium-ion ( Na+) sensors. The as-prepared Na+ sensors effectively prevented the formation of the water layer and penetration of gas species, resulting in stable and high sensing performances. The Na+ sensors showed a Nernstian sensitivity of 58.11 mV/[Na+] with a low relative standard deviation (0.46), fast response time (5.1 s), good selectivity (K < 10− 4), and good durability. Furthermore, the Na+ sensor demonstrated its feasibility in practical applications by measuring accurate and reliable ion concentrations of artificial human sweat and tear samples, comparable to a commercial ion meter.

Bioreactors are devices used by sewage treatment plants to process sewage and which produce active sludge, and sediments separated by solid-liquid are treated in anaerobic digestion tanks. In anaerobic digestion tanks, the volume of active sludge deposits is reduced and biogas is produced. After dehydrating the digestive sludge generated after anaerobic digestion, anaerobic digested wastewater, which features a high concentration of organic matters, is generated. In this study, the decomposition of organic carbon and nitrogen was studied by advanced oxidation process. Ozone-microbubble flotation process was used for oxidation pretreatment. During ozonation, the TOC decreased by 11.6%. After ozone treatment, the TOC decreased and the removal rate reached 80.4% as a result of the Ultra Violet-Advanced Oxidation Process (UV-AOP). The results with regard to organic substances before and after treatment differed depending on the organic carbon index, such as CODMn, CODCr, and TOC. Those indexes did not change significantly in ozone treatment, but decreased significantly after the UV-AOP process as the linkage treatment, and were removed by up to 39.1%, 15.2%, and 80.4%, respectively. It was confirmed that biodegradability was improved according to the ratio of CODMn to TOC. As for the nitrogen component, the ammonia nitrogen component showed a level of 3.2×102 mg/L or more, and the content was maintained at 80% even after treatment. Since most of the contaminants are removed from the treated water and its transparency is high, this water can be utilized as a resource that contains high concentrations of nitrogen.

Recently, in the case of the root industry, although it is a basic industry that forms the basis of manufacturing competitiveness, there continues to be a shortage of manpower due to reasons such as dangerous working environments, industrial economic difficulties, and low wage systems. In addition, the demand for automation of production lines using robots is increasing due to a shrinking labor market due to a decrease in the working population due to aging, higher wages, shorter working hours, and limitations of foreign workers. In this study, a system was developed to automate the injection molding process for producing ball valves for automobiles by applying robot system. The applied process flow consists of alignment and insertion of insert parts, and removal, transfer, and loading of the product after injection molding, which is currently performed manually. Through the application of the developed robot automation system, the cycle time was improved by more than 30% and the defect rate was reduced by more than 70%.

이 연구는 일본 규슈 북쪽 서단(西端)에 위치한 작은 도시지만, 제1,2 차 세계대전에서 구(舊)일본 해군의 군사적 요충지 역할을 맡은 군항도시 사세보(佐世保)가 관광도시로 전환되는 그 과정의 설계와 실천 과정에 기반을 두고 있다. 1983년 개장한 나가사키(長崎) ‘오란다무라(Holland Village)’는 지역경제에 많은 파급효과를 가져왔고, 1992년 개장한 ‘하우 스텐보스(Huis Ten Bosch)’는 관광도시로의 전환에 있어 ‘결정체’와 같 은 역할을 했다. 오랜 기간 군항도시의 역할이 지속된 사세보는 전전기 (戦前期)와 전후기(戦後期)를 거치며 어두운 전쟁의 체험과 역사적 흔적 을 남겼다. 하지만 사세보 시민들이 염원하던 ‘평화산업항만도시’로의 전 환에 있어 결정체 역할을 한 ‘하우스텐보스’의 개장은 마치 어두운 전쟁 의 역사의 흔적을 지우듯 나가사키의 역사와 문화라는 옷을 입혀 그 부 지위에 자리 잡았다. 하우스텐보스가 조성된 부지는 전전기에는 해군병 교 하리오(針尾)분교가, 전후기에는 인양자들의 숙소이자 인양 원호국이 자리잡고 있었던 곳이었다. 이처럼 사세보의 어두운 역사의 땅 위에 하 우스텐보스가 지어지며 군항도시에서 관광도시로 전환된 과정을 흥미롭 게 살펴보고자 한다.

본 연구에서는 Monopile 방식 풍력발전기 강구조물의 부식을 방지하기 위하여 S355 steel의 표면 거칠기에 따른 용사 코팅 상태에 관한 연구를 수행했다. 일차적으로는 시편별 서로 다른 표면거칠기를 부여하기 위해 밀링머신에 페이스 커터를 결합하여 시편별로 다른 조건의 Ra값 기준 표면거칠기를 부여했다. 실험 조건으로는 시편 가공 시 4가지의 회전속도(60, 400, 1200, 2000 rpm), feed rate 150(mm/min) 조건을 선정했다. 2차로는 와이어 용융 방식의 아크 용사 코팅을 실시했다. 코팅 조건으로는 분사 거리 200mm, 전압 24V, 전류 120A, 분사 압력 5bar, 와이어 삽입 속도 30g/mm, 와이어 직경 2mm이다. 용사 코팅 후 FE-SEM으로 표면을 관찰한 결과 모든 시편의 S355 면과 코팅층(아연-알루미늄) 사이에 유격이 발생하지 않고 성공적으로 안착이 되었음을 확인할 수 있었다.

It is essential to select materials with excellent mechanical properties to prevent chemical and mechanical damage to the surfaces of materials used in machines and structures and to extend their lifespan. Co-based stellite alloy, which has wear resistance, heat resistance, and corrosion resistance, is essential for products used in harsh environments. However, due to the problem of enormous costs, research on hard facing, which uses a stellite coating layer only on the contact surface, is urgently required. Currently, high-facing research on Stellite coating layers is focused on powder, and GMAW research using wire is relatively lacking. In this study, welding experiments were performed to form stable weld beads using stellite 6 welding wire, and the correlation between parameters and weld beads was analyzed. A CMT welder was used to minimize the heat effect on the base material.

이 연구의 목적은 예비 지구과학 교사들이 선다형 문항 제작 실습 프로그램에 참여하는 과정에서 드러나는 문 항 제작 역량의 발달 양상을 이해하는 것이다. 이를 위해 예비 지구과학 교사 15명이 선다형 문항 제작 과정 중 공동 검토 과정에서 나타나는 논의에 초점을 맞춰 그 특징을 분석하였다. 구성주의 근거 이론을 토대로 3단계의 코딩을 수 행한 결과, 36개의 초기 코드, 12개의 초점 코드, 5개의 이론적 코드가 도출되었다. 코딩 범주에 근거하여 논의의 특징 을 규정하는 검토 문화와 문항에 대한 관점을 두 축으로 설정하였으며, 이로부터 수험생의 문제풀이, 조심스레 한 걸음 떼기, 짙어지는 담화를 주제로 하는 세 가지 이야기를 구성하였다. 또한 프로그램 동안 일관되게 드러나는 문항 제작 역량의 한계를 다다르지 못한 노정에 대한 네 번째 이야기로 서술하였다. 문항 제작 과정에서 드러나는 평가 전문성은 예비교사의 정체성 발달과 관련되어 있으며, 본 연구에서 적용한 개발한 프로그램의 효과와 의의 및 프로그램의 개발과 개선을 위한 시사점을 논의하였다.

Molybdenum-tungsten (Mo-W) alloy sputtering targets are widely utilized in fields like electronics, nanotechnology, sensors, and as gate electrodes for TFT-LCDs, owing to their superior properties such as hightemperature stability, low thermal expansion coefficient, electrical conductivity, and corrosion resistance. To achieve optimal performance in application, these targets’ purity, relative density, and grain size of these targets must be carefully controlled. We utilized nanopowders, prepared via the Pechini method, to obtain uniform and fine powders, then carried out spark plasma sintering (SPS) to densify these powders. Our studies revealed that the sintered compacts made from these nanopowders exhibited outstanding features, such as a high relative density of more than 99%, consistent grain size of 3.43 μm, and shape, absence of preferred orientation.

아메리카동애등에(H. illucens)는 음식물 폐기물 등 유기성 폐자원을 효율적으로 처리할 수 있는 능력을 가지 고 있어 전세계적으로 주목받고 있는 환경정화 곤충이다. 하지만 유기성 폐자원을 처리 시 가장 큰 문제는 아메리 카동애등에가 먹이인 유기성 폐자원을 소화시킬 때 발생되는 악취이다. 국내에서 현재 아메리카동애등에를 사육하고 있는 농가는 223호로 조사되고 있지만 이중 악취발생 저감장치 등을 설치한 농가는 10%가 안되는 것으 로 생각된다. 따라서 국내에서 동애등에 먹이로 가장 많이 사용되는 습식사료를 먹이로 사용하였을 때 농가 사육 장 안에서 발생되는 복합악취와 지정악취 22종에 대하여 분석하였다. 그 결과, 복합악취는 249배였으며, 지정악 취는 22종 중 7종(암모니아, 메틸메르캅탄, 트라이메틸아민, 아세트알데하이드, 프로피온알데하이드, 뷰틸알 데하이드, i-발레르알데하이드)가 검출되었다. 이중 가장 높은 농도를 나타낸 악취물질은 암모니아로 98.4ppm 이 분석되었다. 또한, 아메리카동애등에를 사육 시 가장 많이 발생되는 암모니아의 발생시기는 사육초기인 1~4 령보다 5령 이후 전생육기 중의 대부분을 발생시키는 것으로 조사되었다. 이러한 결과는 암모니아 저감을 위한 적정시기를 설정하는데 도움이 될 것으로 생각된다.

Process-based models are effective in addressing spatially explicit dispersal of invasive species based on life mechanisms including birth, death, movement and response to environmental factors. An invading alien species, the western conifer seed bug (Leptoglossus occidentalis), spreads rapidly in the Korean peninsula since 1988. Process-based models were developed to include the rules occurred in population dynamics of the western conifer seed bug population. Passive movements were additionally linked to the models to present local and global transportations due to sapling trades. Simulation results presented the rapid dispersal of the pest species, comparable to field data. Model parameters including the Alle effect threshold and contribution of global transportation were adjusted to reveal spatially-explicit advancement patters of the species. Utilization of process-based models is further discussed in monitoring and management of forest insect pests in field conditions.

In order to solve the rapidly increasing domestic delivery volume and various problems in the recent metropolitan area, domestic researchers are conducting research on the development of “Urban Logistics System Using Underground Space” using existing urban railway facilities in the city. Safety analysis and scenario analysis should be performed for the safe system design of the new concept logistics system, but the scenario analysis techniques performed in previous studies so far do not have standards and are defined differently depending on the domain, subject, or purpose. In addition, it is necessary to improve the difficulty of clearly defining the control structure and the omission of UCA in the existing STPA safety analysis. In this study, an improved scenario table is proposed for the AGV horizontal transport device, which is a key equipment of an urban logistics system using underground space, and a process model is proposed by linking systematic STPA safety analysis and scenario analysis, and UCA and Control Structure Guidelines are provided to create a safety analysis.

For the sustainable use of fishery resources as common resources and the mitigation of conflicts with commercial fishermen, it is essential to understand recreational anglers’ participation process of environmentally responsible behaviors (ERB). This study intends to show that the effects of recreation specialization on environmentally responsible behaviors can be weakened due to the characteristics of anglers, who prefer to possess caught fish. Two different research models were tested with two data sets independently collected. The data were analyzed with structural equation modeling. The results show that consumptive orientation, which measures a degree of catching and owning fish, and fishing-specific ERBs negatively affect the relationships between recreation specialization and general ERBs as mediation variables. Implications are further discussed that regulation policies and education programs are needed to change anglers’ consumptive orientation and catch-related fishing behaviors.

본 연구는 경로의존성과 정책선도자의 개념으로 최근의 주요 경비업 법 개정 관련 논란 및 사태 등을 살펴, 10.29 참사 이후 경비업법 개 정 관련 논의를 하고자 한다. 이를 위해 각종 논문 및 학술자료와 신문 기사 등 자료를 통한 문헌분석 방법을 통해 살펴본다. 경비업법은 경비 업 제한(지도와 감독, 규제와 처벌 논리)법으로서 기능을 하여 왔으며, 경비업의 권한 남용의 방지에 관한 광범위한 기술적인 규정을 두는 경 로의존성을 지니고 있으며, 경비업법에서 정책선도자인 행정안전부(경 찰청)의 역할과 기능은 매우 중요함을 알 수 있었다. 결국, 경비업법의 경로의존성은 개정 입법 논의의 한계로 작용하고 정책선도자인 행정안 전부(경찰청)의 의지에 달렸다. 최근 10.29 참사로 인해 경비업법의 개 정에 대한 정책의 창이 열렸다. 그간의 경비업법 개정 과정 분석을 통 해 경로의존성과 정책선도자의 특성을 고려해 본다면, 개정의 논의가 순탄치 않음을 탐색해 볼 수 있다.

In this study, we proposed a simulator for the development of a digital multi-process welding machine and a welding process monitoring system. The simulator, which mimics the data generation process of the welding machine, is composed of process control circuit, peripheral device circuit, and wireless communication circuit. Utilizing this simulator, we aimed to develop a welding process monitoring system that can monitor the welding situations of four multi-process welding machines and three processes each, with data transmission through wireless communication. Through the operation of the proposed simulator, sequential digital processing of multi-process welding data and wireless communication were achieved. The welding process monitoring system enabled real-time monitoring and accumulation of the process data. The selection of upper and lower limits for process variables was carried out using a deep neural network based on allowable changes in bead shape, enabling the management of welding quality by applying a process control technique based on the trend of received data.