The aim of this study is to ensure the structural integrity of a canister to be used in a dry storage system currently being developed in Korea. Based on burnup and cooling periods, the canister is designed with 24 bundles of spent nuclear fuel stored inside it. It is a cylindrical structure with a height of 4,890 mm, an internal diameter of 1,708 mm, and an inner length of 4,590 mm. The canister lid is fixed with multiple seals and welds to maintain its confinement boundary to prevent the leakage of radioactive waste. The canister is evaluated under different loads that may be generated under normal, off-normal, and accident conditions, and combinations of these loads are compared against the allowable stress thresholds to assess its structural integrity in accordance with NUREG-2215. The evaluation result shows that the stress intensities applied on the canister under normal, off-normal, and accident conditions are below the allowable stress thresholds, thus confirming its structural integrity.

Even though a huge amount of spent nuclear fuels are accumulated at each nuclear power plant site in Korea, our government has not yet started to select a final disposal site, which might require more than several km2 surface area. According to the second national plan for the management of high-level radioactive waste, the reference geological disposal concept followed the Finnish concept based on KBS-3 type. However, the second national plan also mentioned that it was necessary to develop the technical alternatives. Considering the limited area of the Korean peninsula, the authors had developed an alternative disposal concepts for spent nuclear fuels in order to enhance the disposal density since 2021. Among ten disposal concepts shown in the literature published in 2000’s, we narrowed them to four concepts by international experiences and expert judgements. Assuming 10,000 t of CANDU spent nuclear fuels (SNF), we designed the engineered barriers for each alternative disposal concept. That is, using a KURT geological conditions, the engineered barrier systems (EBS) for the following four alternative concepts were proposed: ① mined deep borehole matrix, ② sub-seabed disposal, ③ deep borehole disposal, and ④ multi-level dispoal. The quantitative data of each design such as foot prints, safety factors, economical factors are produced from the conceptual designs of the engineered barriers. Five evaluation criteria (public acceptance, safety, cost, technology readiness level, environmental friendliness) were chosen for the comparison of alternatives, and supporting indicators that can be evaluated quantitatively were derived. The AHP with domestic experts was applied to the comparison of alternatives. The twolevel disposal was proposed as the most appropriate alternative for the enhancement of disposal efficiency by the experts. If perspectives changes, the other alternatives would be preferred. Three kinds of the two-level disposal of CANDU SNF were compared. It was decided to dispose of all the CANDU spent nuclear fuels into the disposal holes in the lower-level disposal tunnels because total footprint of the disposal system for CANDU SNF was much smaller than that for PWR SNF. Currently, we reviewed the performance criteria related to the disposal canister and the buffer and designed the EBS for CANDU SNF. With the design, safety assessment and cost estimates for the alternative disposal system will be carried out next year.

Spent nuclear fuel management is a high-priority issue in South Korea, and addressing it is crucial for the country’s long-term energy sustainability. The KORAD (Korea Radioactive Waste Agency) is leading a comprehensive, long-term project to develop a safe and effective deep geological repository for spent nuclear fuel disposal. Within this framework, we have three primary objectives in this work. First, we conducted statistical analysis to assess the inventory of spent nuclear fuel in South Korea as of 2021. We also projected future generation rates of spent nuclear fuels to identify what we refer to as reference spent nuclear fuels. These reference spent nuclear fuels will be used as the design basis spent fuels for evaluating the safety of the repository. Specifically, we identified four types of design basis reference spent nuclear fuels: high and low burnup from PLUS7 (with a 16×16 array) and ACE7 (with a 17×17 array) assemblies. Second, we analyzed radioactive nuclides’ inventory, activities, and decay heats, extending up to a million years after reactor discharge for these reference spent nuclear fuels. This analysis was performed using SCALE/TRITON to generate the burnup libraries and SCALE/ORIGEN for source term evaluation. Third, to assess the safety resulted from potential radioactive nuclides’ release from the disposal canister in future work, we selected safety-related radionuclides based on the ALI (Annual Limit of Intake) specified in Annex 3 of the 2019-10 notification by the NSSC (Nuclear Safety and Security Commission). Conservative assumptions were made regarding annual water intake by humans, canister design lifetime, and aquifer flow rates. A safety margin of 10-3 of the ALI was applied. We selected 56 radionuclides that exceed the intake limits and have half-lives longer than one year as the safety-related radionuclides. However, it is crucial to note that our selection criteria focused on ALI and half-lives. It did not include other essential factors such as solubility limits, distribution coefficients, and leakage processes. So, some of these nuclides can be removed in a specific analysis area depending on their properties.

While many countries consider direct disposal of the spent nuclear fuels, they need to consider long-term disposal scenarios with severe accidents such as the contact between underwater and the spent nuclear fuel due to large defect of the canister. Radionuclides releases rapidly with contacting water or slowly with dissolution of UO2 matrix. The former is known as the ‘Instant Release’, and the latter is ‘Congruential Release’. Even though the instant release fractions (IRF) are much smaller than the congruential ones, IRF has to be treated carefully due to the fact that the instant releases lead to much larger value of the exposure dose rates than the congruential ones which proceed very slowly. It is known that the exposure dose rates by the instant releases are ~25 times larger than the one by the congruent release. The radionuclides from UO2 matrix migrate to the grain boundary, make bubbles, and make tunnels, which leads to instant releases of some radionuclides. The radionuclides in the gap between UO2 pellet and cladding can be also instantly released. In addition, the radionuclides in the crud are instantly released. But in this paper, nuclides from the crud are not regarded, due to the lack of the leaching data. Meanwhile, there’re some nuclides that released from the construction materials like the cladding, the Rod Cluster Control Assembly (RCCA), or the other metal parts. In this work, IRF values for major IRF nuclides such as Cs, I, Cl, Se for the reference PWR spent fuels of South Korea were evaluated based on the rationale from literatures’ review. In particular, these evaluations were done as the function of fission gas release (FGR), average discharge burnup, and fuel dimensions. In addition, the values of IRF for the other nuclides were also suggested based on the other institutes.

Spent fuels (SFs) are stored in a storage pool after discharge from nuclear power plants. They can be transferred to for the further processes such as dry storage sites, processing plants, or disposal sites. One of important measures of SF is the burnup. Since the radioactivity of SF is strongly dependent on its burnup, the burnup of SF should be well estimated for the safe management, storage, and final disposal. Published papers about the methodology for the burnup estimation from the known activities of important radioactive sources are somewhat rare. In this study, we analyzed the dependency of the burnup on the important radiation source activities using ORIGEN-ARP, and suggested simple correlations that relate the burnup and the important source activities directly. A burnup estimation equation is suggested for PWR fuels relating burnup with total neutron source intensity (TNSI), initial enrichment, and cooling time. And three burnup estimation equations for major gamma sources, 137Cs, 134Cs, and 154Eu are also suggested.

In order to use nuclear energy stably, high level radioactive waste including spent nuclear fuel that is inevitably discharged from nuclear power plants after electricity generation must be managed safely and isolated from the human living area for a long period of time. In consideration of the accumulated amount of spent nuclear fuel anticipated according to the national policy for HLW management, the area required for the deep geological repository facility is expected to be very large. Therefore, it is essential to conduct various studies to optimize the area required for the disposal of spent nuclear fuel in cases where the nationally available land is extremely limited, such as in Korea. In this study, as part of such research, the strategies and the requirements for the preliminary design of a high efficiency repository concept of spent nuclear fuel were established. For PWR spent nuclear fuel, seven assemblies of spent nuclear fuel can be accommodated in a disposal canister, and high burnup of spent nuclear fuel was taken into consideration, and the source terms such as the amount and time of discharge and disposal were based on the 2nd national basic plan. By evaluating the characteristics, the amount of decay heat that can be accommodated in the disposal canister was optimized through the combination of seven assemblies of spent nuclear fuel. The cooling period of the radiation source for the safety assessment of the repository system was set at 55 years, and the operation of the repository would start from 2070 and then the disposal schedule would be conducted according to the disposal scenario based on the national basic plan. With these disposal strategies described above, the main requirements for setting up the conceptual design of the high efficiency repository system to be carried out in this study were described below. • A combination of seven spent nuclear fuels with high heat and spent nuclear fuels with low heat was loaded into a disposal canister, and the thermal limit per disposal canister was 1,600 W. • In order to maintain the long-term performance of the repository, the maximum temperature design limit in the buffer material was set to 130°C. • In the deep disposal environment, the safety factor [yield strength/maximum stress] required to maintain the structural stability of the disposal canister should be maintained at 2.0 or higher so that integrity of the canister can be maintained even under long-term hydrostatic pressure and buffer swelling pressure in the deep disposal environment. • The repository should have a maximum exposure dose of 10 mSv/yr or less, which is the legal limit in case of a single event such as an earthquake, and the risk level considering natural phenomena and human intrusion, which is less than the legal limit of 10-6/yr. These strategies and requirements can be used to develop the high-efficiency geological disposal concept for spent nuclear fuels as an alternative disposal concept.

It is expected that around 576,000 bundles of CANDU spent nuclear fuels (SNF) will be generated from the four CANDU reactors located at the Wolsong site. The authors designed and proposed a reference disposal concept based on the KBS-3 type and KURT geological data in 2022. In addition, we have reviewed the literatures and selected four alternative disposal methods to develop the higherefficiency disposal concept than the reference concept since 2021. As known well, the most important safety functions of the geological disposal are containment and isolation, and the secondary function is retardation. A disposal canister covers the former, and buffer may do the latter. In this study, we design the engineered barrier systems for the four alternative concepts: (1) mined deep borehole matrix, (2) sub-seabed disposal, (3) deep borehole disposal, and (4) multi-level dispoal. Assuming total 10,000 tU of CANDU SNF, four different kinds of unit disposal module consisting of disposal canisters and compacted bentonite buffers are designed based on the technique currently available. Two alternative concepts, sub-seabed disposal and multi-level disposal, share the same unit module design with the reference concept in 2022. For all the alternative concepts, we assume that the density of the compacted buffer is 1.6 g/cm3. For the mined deep borehole matrix disposal, we introduce a disposal canister slightly modified from the Canadian NWMO canister with a capacity of 48 bundles. The thickness of a copper layer is changed to be 10 mm considering the long-term corrosion resistance. The buffer thickness around a disposal canister is 20 cm, and the diameter of a borehole is 100 cm. Two different kinds of buffer blocks are proposed for the easy handling of them. For the deep borehole disposal, a SiC-stainless steel canister is designed, and 63 bundles of CANDU SNF is emplaced in the canister. We expect that the SiC ceramic canister shows very excellent corrosion resistance and has a high thermal conductivity under the geological conditions. The deep borehole will be plugged with four layered sealing materials consisting of granite blocks, compacted bentonite, SiC ceramic, and concrete plugs.

It is expected that around 576,000 bundles of CANDU spent nuclear fuels (SNF) will be generated from the four CANDU reactors located at the Wolsong site, according to the 2nd National Plan for the management of High-Level radioactive Waste (HLW). The CANDU SNFs are currently stored at the dry storage facilities at the Wolsong site. The authors proposed KRS+ geological disposal system consisting of two different concepts, Swedish KBS-3V type and Canadian NWMO type, for the final management of CANDU SNF. Both the concepts were designed based on the geological data obtained from the KURT (KAERI Underground Research Tunnel). The NWMO type is an in-room horizontal placement method. In this study, we try to determine the reference concept among the two proposed concepts at 500 meters below the ground surface. Assuming 10,000 tU of CANDU SNF and the KURT site, we design two engineered barrier systems, that is disposal canisters and buffers. The copper disposal canister is designed with a copper thickness of 10 mm based on a cold spray coating technique for both the disposal concepts. The domestic Ca-bentonite is used for the compact bentonite buffer with dry density of 1.6 g/cm3. Two concepts are compared in terms of safety, economics of the engineered barriers, and environment-friendliness. Because the same amounts of CANDU SNF are disposed of at the same depth, the differences in the disposal area are neglected. For the comparison in terms of safety, the corrosion lifetimes of the disposal canisters of two disposal systems are quantitatively calculated, and the capacities for retarding radionuclide releases of the compacted bentonite buffers are assessed. A computer tool developed by the authors is used in order to assess the lifetime of a disposal canister. In this study, the case that corrosion of a copper canister by sulfide from groundwater through intact buffer is analyzed. The sulfide concentration in groundwater is assumed to be 3 ppm. The most important safety function of buffer is to retard the radionuclide release. Twelve long-lived radionuclides are selected to compare the capacities for retarding the radionuclide transport through the buffer using an analytical solution. The retention time by an engineered barrier consisting of a disposal canister and a buffer is compared with twenty times the half-life of each radionuclide for both the disposal systems. The selected reference concept will be compared with the alternative geological concepts through a further study.

The management before disposal of spent nuclear fuel is an essential process for safe management. It is important to determine the amount of nuclide inventory in order to ensure the integrity of spent nuclear fuel, as radiation generated from the nuclides is generated along with residual heat in the spent nuclear fuel. Based on the data on the characteristics of spent nuclear fuel generated in Korea, the correlation equation between burnup and enrichment was derived by referring to overseas cases (Sweden). Source term analysis was performed using the SCALE ORIGEN ARP code by securing the burnup history of nuclear fuel. Calculation was performed by inputting the combustion history of the fuel WH14×14 and WH17×17 as a reference for CE16×16 spent fuel. Through this study, the relationship was identified using the burnup, enrichment, and cooling time factors that influence the characteristics of spent nuclear fuel. In addition, the total source and spectrum data from neutrons and gamma sources were used to find out the characteristics of fuel.

There are highly toxic radio-isotopes and high heat emitting isotopes in spent nuclear fuels which could be a burden in a deep geological repository. Some preliminary study in order to see if there are some advantages in terms of waste burden, in case that the spent fuel is appropriately processed and then disposed of in a final repository, has been carried out at KAERI. This study is focused on the proliferation resistance for various processing alternatives for them. The evaluation criteria and their indicators for proliferation resistance analysis are selected and then evaluated quantitatively or quantitatively for the alternatives. The processing alternatives are grouped into three categories according to the level of decrease of burden for final disposal and named them as Level I, Level II and Level III technolgy alternatives. Level I alternative is to maximize the long-term safety in the final repository from the removal of I- 129, semi-volatile radioisotope, which is the greatest impact on the long-term safety of the repository. Level II alternative is to remove the strontium-90, high heat emitter, in addition to the removal in Level I. The Level III is to additionally remove uranium from main stream of the level II to reduce the volume of the high level wastes to be disposed. The intrinsic radiation and chemical barriers against the nuclear proliferation are selected and analyised for the alternatives. It is resulted from the proliferation resistance analysis that all three options showed excellent resistance to nuclear proliferation for the two barriers. However, Level III technology including electrochemical refining process is relatively a little weaker than others. Overall, it could be an effective means to reduce the burden of disposal if the spent fuels are appropriately conditioned for final disposal. Further detailed studies are, however, needed to finalize its feasibility.

Several countries, including Korea, are considering the direct disposal of spent nuclear fuels. The radiological safety assessment results published after a geological repository closure indicate that the instant release is the main radiation source rather than the congruent release. Three Safety Case reports recently published were reviewed and the IRF values of seven long-lived radionuclides, including relevant experimental results, were compared. According to the literature review, the IRF values of both the CANDU and low burnup PWR spent fuel have been experimentally measured and used reasonably. In particular, the IRF values of volatile long-lived nuclides, such as 129I and 135Cs, were estimated from the FGR value. Because experimental leaching data regarding high burnup spent nuclear fuels are extremely scarce, a mathematical modelling approach proposed by Johnson and McGinnes was successfully applied to the domestic high burnup PWR spent nuclear fuel to derive the IRF values of iodine and cesium. The best estimate of the IRF was 5.5% at a discharge burnup of 55 GWd tHM−1.

The research for the safe management of high-level waste in Korea has been conducted by the Korea Atomic Energy Research Institute since 1997, and the results have formed the basis of the national basic plan for the high-level waste management and the revised national basic plan. In the future, it is evolving and developing R&D focusing on securing technologies for demonstration of the disposal technologies and R&D to develop disposal concepts that increase safety and improve efficiency. Efficient management of heat generated from high-level radioactive waste, including spent nuclear fuel, is an important factor in establishing the disposal concepts because it must be in harmony with key factors such as repository layout, waste disposal container specifications, and design and operation for the barriers of the disposal system. For safe and complete isolation of highlevel radioactive waste in the deep geology, the disposal systems that meet the thermal requirements for the disposal system design have been developed by harmonizing the thermal characteristics of engineered and natural barriers in Korea. These disposal systems were based on low burn-up spent nuclear fuel characteristics generated in the early stages of nuclear power generation, and next, based on the high-level wastes from recycling process of the high burn-up spent nuclear fuels, and were the direct disposal systems for the high burn-up spent nuclear fuels. So, it is necessary to track and analyze the change process in the decay heat characteristics of the high-level waste to be disposed of in order to improve the disposal concept, which enhances the safety of disposal and the utilization of the national land. Therefore, in this paper, the process of change in decay heat of reference spent nuclear fuels for disposal applied to the disposal concepts from the initial stage of development of high-level waste disposal technology to the present in Korea is analyzed.

Around 40 years ago, in the mid-1980s, Swedish government approved the KBS-3 method for the direct disposal of spent nuclear fuels (SNF) in Sweden. Since then, this method has become a reference for many countries including Korea, Republic of. The main ideas of the KBS-3 method are to locate SNF at 500 m below the ground surface using a copper disposal canister and a bentonite buffer. In 2016, our government announced the National Plan (NP 2016) regarding the final management of high-level waste (HLW) in Korea. In 2019, new committee were organized to review the NP 2016, and they submitted the final recommendations to the government in 2021. Finally, the government announced the 2nd National Plan in December, 2021. So far, KAERI has developed the technologies related to the final management of SNF in two directions. One follows ‘direct disposal’ based on the KBS-3 concept, and the other ‘recycling’ based on ‘pyroprocessing-and-SFR’ (PYRO-SFR). Even though Posiva and SKB obtained the construction permits with the KBS-3 method in Finland and Sweden, respectively, there are still several technical obstacles to applying directly to our situations. Some examples are as follows: high burnup, huge amounts of SNF, and high geothermal gradient in Korean peninsula. In this work, we try to illustrate some limits of the KBS-3 method. Within our country, currently, the most probable disposal option is the KBS-3 type geological disposal, but no one knows what the best option will be in 20 or 30 years if those kinds of drawbacks are considered. That is, we compare the effects of the drawbacks using our geological data and characteristics of spent fuels. Last year, we reviewed alternative disposal concepts focusing on the direct disposal of SNF and compared the pros and cons of them in order to enhance the disposal efficiency. We selected four candidate concepts. They were multi-level disposal, deep borehole disposal, sub-seabed disposal and mined deep borehole matrix. As mentioned before, KAERI has developed a pyroprocessing technology based on the SFR to reuse fissile radionuclides in SNF. Even though we can consume some fissile nuclides such as 239Pu and 241Pu using PYRO-SFR cycle, there still remain many long-lived radionuclides such as 129I and 135Cs waiting for the final disposal. The authors review and propose several concepts for the future final management of the long-lived radionuclides.

Solid-state mechanochemical reduction combined with subsequent melting consolidation was suggested as a technical option for the oxide reduction in pyroprocessing. Ni ingot was produced from NiO as a starting material through this technique while Li metal was used as a reducing agent. To determine the technical feasibility of this approach for pyroprocessing, which handles spent nuclear fuels, thermodynamic calculations of the phase stabilities of various metal oxides of U and other fission elements were made when several alkaline and alkali-earth metals were used as reducing agents. This technique is expected to be beneficial, not only for oxide reduction but also for other unit processes involved in pyroprocessing.

Currently, the interim storage pools of spent fuels in South Korea are expected to become saturated from 2024. It is required to prepare an operation plan of a domestic dry storage facility during a long-term period, with the researches on safety evaluation methods. This study modified the FRAPCON code to predict the spent fuel integrity evaluation such as the axial cladding temperature, the hoop stress and hydrogen distribution in dry storage. The cladding temperature in dry storage was calculated using the COBRA-SFS code with the burnup information which was calculated using the FRAPCON code. The hoop stress was calculated using the ideal gas equation with spent fuel information such as rod internal pressure. Numerical analysis method was used to calculate the degree of hydrogen diffusion according to the hydrogen concentration and temperature distribution during a dry storage period. Before 50 years of dry storage, the cladding temperature and hoop stress decreased rapidly. However, after 50 years, they decreased gradually and the cladding temperature was below 400 K. The initial temperature distribution and hydrogen concentration showed a parabolic line, but hydrogen was transferred by the hydrogen concentration and temperature gradient over time.