In Korea, two types of spent nuclear fuels (SNFs) are generated, pressurized light water reactor type (PWR) and pressurized heavy water reactor type (PHWR; CANDU), that differ greatly in size, decay heat, and radioactive characteristics. Technology development for the disposal of SNFs has mainly focused on PWR SNFs that are large in size and have extremely high decay heat and radioactivity. However, CANDU SNFs should be considered differently from PWR SNFs in deep geological disposal systems because their characteristics significantly differ from those of PWR SNFs in terms of their dimensions, number of SNF bundles, and handling systems in nuclear power plant sites. In this paper, after reviewing the status of the CANDU SNF disposal concept by Canada and Korea, concepts related to the direct geological disposal of CANDU SNFs were described, and two concepts were proposed based on the results of the development. The engineered barrier systems developed using these two concepts were comparatively analyzed in terms of disposal safety, disposal efficiency, and technical maturity. Based on the results of the comparative analyses, a vertical-type emplacement disposal concept was determined as a reference concept for the deep geological disposal of CANDU SNFs.

Even though a huge amount of spent nuclear fuels are accumulated at each nuclear power plant site in Korea, our government has not yet started to select a final disposal site, which might require more than several km2 surface area. According to the second national plan for the management of high-level radioactive waste, the reference geological disposal concept followed the Finnish concept based on KBS-3 type. However, the second national plan also mentioned that it was necessary to develop the technical alternatives. Considering the limited area of the Korean peninsula, the authors had developed an alternative disposal concepts for spent nuclear fuels in order to enhance the disposal density since 2021. Among ten disposal concepts shown in the literature published in 2000’s, we narrowed them to four concepts by international experiences and expert judgements. Assuming 10,000 t of CANDU spent nuclear fuels (SNF), we designed the engineered barriers for each alternative disposal concept. That is, using a KURT geological conditions, the engineered barrier systems (EBS) for the following four alternative concepts were proposed: ① mined deep borehole matrix, ② sub-seabed disposal, ③ deep borehole disposal, and ④ multi-level dispoal. The quantitative data of each design such as foot prints, safety factors, economical factors are produced from the conceptual designs of the engineered barriers. Five evaluation criteria (public acceptance, safety, cost, technology readiness level, environmental friendliness) were chosen for the comparison of alternatives, and supporting indicators that can be evaluated quantitatively were derived. The AHP with domestic experts was applied to the comparison of alternatives. The twolevel disposal was proposed as the most appropriate alternative for the enhancement of disposal efficiency by the experts. If perspectives changes, the other alternatives would be preferred. Three kinds of the two-level disposal of CANDU SNF were compared. It was decided to dispose of all the CANDU spent nuclear fuels into the disposal holes in the lower-level disposal tunnels because total footprint of the disposal system for CANDU SNF was much smaller than that for PWR SNF. Currently, we reviewed the performance criteria related to the disposal canister and the buffer and designed the EBS for CANDU SNF. With the design, safety assessment and cost estimates for the alternative disposal system will be carried out next year.

Various disposal methods for spent nuclear fuels (SNFs) are being researched, and one of these methods involves separating high heat-generating nuclear isotopes such as Strontium-90 (90Sr) and Cesium-137 (137Cs) for deep disposal. These isotopes has relatively short half-lives and substantial decay energies. Especially, 90Sr undergoes decay through Yttrium-90 to Zirconium-90, emitting intense heat with beta radiation. Therefore, the removal of these high heat-generating isotopes will significantly contribute to reducing disposal site area. To remove 90Sr from SNFs, molten salt was utilized in KAERI. During this process, it was discovered that 90Sr dissolves in the molten salt in the form of SrCl2 and/or Sr4OCl6. Afterwards, it is crucial to recover 90Sr in the form of oxide from the salt to create immobilized forms for disposal. This can be achieved by reactive distillation with K2CO3. However, the amount of 90Sr within the SNFs is only 0.121wt%, and even if all the 90Sr in the SNFs were to leach into the molten salt, the quantity of 90Sr in the molten slat would still be very small. Therefore, adding K2CO3 to the molten salt for reactive distillation could result in significant possibilities of side reactions occurring. In this study, a two-step process was employed to mitigate the side reactions: the 1st step involves evaporating the all molten salts and the 2nd step includes adding K2CO3 to make oxides through solid-solid reaction. Eutectic LiCl-KCl, which is the most commonly used salt, was employed. The eutectic LiCl-KCl with SrCl2 was heated at 850°C for 2 h to evaporate the salts under a vacuum (> 0.02 torr). However, after examining the distillation product before the solid-solid reaction, it was observed that SrCl2 reacted with KCl in the salt, resulting in the formation of KSr2Cl5. It means that salts containing KCl are not suitable candidates for reactive distillation aimed at producing immobilized forms. As an alternative, MgCl2 could be a highly promising candidate because it is inert to SrCl2 and according to a recent study in KAERI, MgCl2 exhibited the most efficient separation of Sr among various salts. Therefore, we plan to proceed with the two-step reactive distillation using MgCl2 for the future work.

In order to use nuclear energy stably, high level radioactive waste including spent nuclear fuel that is inevitably discharged from nuclear power plants after electricity generation must be managed safely and isolated from the human living area for a long period of time. In consideration of the accumulated amount of spent nuclear fuel anticipated according to the national policy for HLW management, the area required for the deep geological repository facility is expected to be very large. Therefore, it is essential to conduct various studies to optimize the area required for the disposal of spent nuclear fuel in cases where the nationally available land is extremely limited, such as in Korea. In this study, as part of such research, the strategies and the requirements for the preliminary design of a high efficiency repository concept of spent nuclear fuel were established. For PWR spent nuclear fuel, seven assemblies of spent nuclear fuel can be accommodated in a disposal canister, and high burnup of spent nuclear fuel was taken into consideration, and the source terms such as the amount and time of discharge and disposal were based on the 2nd national basic plan. By evaluating the characteristics, the amount of decay heat that can be accommodated in the disposal canister was optimized through the combination of seven assemblies of spent nuclear fuel. The cooling period of the radiation source for the safety assessment of the repository system was set at 55 years, and the operation of the repository would start from 2070 and then the disposal schedule would be conducted according to the disposal scenario based on the national basic plan. With these disposal strategies described above, the main requirements for setting up the conceptual design of the high efficiency repository system to be carried out in this study were described below. • A combination of seven spent nuclear fuels with high heat and spent nuclear fuels with low heat was loaded into a disposal canister, and the thermal limit per disposal canister was 1,600 W. • In order to maintain the long-term performance of the repository, the maximum temperature design limit in the buffer material was set to 130°C. • In the deep disposal environment, the safety factor [yield strength/maximum stress] required to maintain the structural stability of the disposal canister should be maintained at 2.0 or higher so that integrity of the canister can be maintained even under long-term hydrostatic pressure and buffer swelling pressure in the deep disposal environment. • The repository should have a maximum exposure dose of 10 mSv/yr or less, which is the legal limit in case of a single event such as an earthquake, and the risk level considering natural phenomena and human intrusion, which is less than the legal limit of 10-6/yr. These strategies and requirements can be used to develop the high-efficiency geological disposal concept for spent nuclear fuels as an alternative disposal concept.

It is expected that around 576,000 bundles of CANDU spent nuclear fuels (SNF) will be generated from the four CANDU reactors located at the Wolsong site. The authors designed and proposed a reference disposal concept based on the KBS-3 type and KURT geological data in 2022. In addition, we have reviewed the literatures and selected four alternative disposal methods to develop the higherefficiency disposal concept than the reference concept since 2021. As known well, the most important safety functions of the geological disposal are containment and isolation, and the secondary function is retardation. A disposal canister covers the former, and buffer may do the latter. In this study, we design the engineered barrier systems for the four alternative concepts: (1) mined deep borehole matrix, (2) sub-seabed disposal, (3) deep borehole disposal, and (4) multi-level dispoal. Assuming total 10,000 tU of CANDU SNF, four different kinds of unit disposal module consisting of disposal canisters and compacted bentonite buffers are designed based on the technique currently available. Two alternative concepts, sub-seabed disposal and multi-level disposal, share the same unit module design with the reference concept in 2022. For all the alternative concepts, we assume that the density of the compacted buffer is 1.6 g/cm3. For the mined deep borehole matrix disposal, we introduce a disposal canister slightly modified from the Canadian NWMO canister with a capacity of 48 bundles. The thickness of a copper layer is changed to be 10 mm considering the long-term corrosion resistance. The buffer thickness around a disposal canister is 20 cm, and the diameter of a borehole is 100 cm. Two different kinds of buffer blocks are proposed for the easy handling of them. For the deep borehole disposal, a SiC-stainless steel canister is designed, and 63 bundles of CANDU SNF is emplaced in the canister. We expect that the SiC ceramic canister shows very excellent corrosion resistance and has a high thermal conductivity under the geological conditions. The deep borehole will be plugged with four layered sealing materials consisting of granite blocks, compacted bentonite, SiC ceramic, and concrete plugs.

It is expected that around 576,000 bundles of CANDU spent nuclear fuels (SNF) will be generated from the four CANDU reactors located at the Wolsong site, according to the 2nd National Plan for the management of High-Level radioactive Waste (HLW). The CANDU SNFs are currently stored at the dry storage facilities at the Wolsong site. The authors proposed KRS+ geological disposal system consisting of two different concepts, Swedish KBS-3V type and Canadian NWMO type, for the final management of CANDU SNF. Both the concepts were designed based on the geological data obtained from the KURT (KAERI Underground Research Tunnel). The NWMO type is an in-room horizontal placement method. In this study, we try to determine the reference concept among the two proposed concepts at 500 meters below the ground surface. Assuming 10,000 tU of CANDU SNF and the KURT site, we design two engineered barrier systems, that is disposal canisters and buffers. The copper disposal canister is designed with a copper thickness of 10 mm based on a cold spray coating technique for both the disposal concepts. The domestic Ca-bentonite is used for the compact bentonite buffer with dry density of 1.6 g/cm3. Two concepts are compared in terms of safety, economics of the engineered barriers, and environment-friendliness. Because the same amounts of CANDU SNF are disposed of at the same depth, the differences in the disposal area are neglected. For the comparison in terms of safety, the corrosion lifetimes of the disposal canisters of two disposal systems are quantitatively calculated, and the capacities for retarding radionuclide releases of the compacted bentonite buffers are assessed. A computer tool developed by the authors is used in order to assess the lifetime of a disposal canister. In this study, the case that corrosion of a copper canister by sulfide from groundwater through intact buffer is analyzed. The sulfide concentration in groundwater is assumed to be 3 ppm. The most important safety function of buffer is to retard the radionuclide release. Twelve long-lived radionuclides are selected to compare the capacities for retarding the radionuclide transport through the buffer using an analytical solution. The retention time by an engineered barrier consisting of a disposal canister and a buffer is compared with twenty times the half-life of each radionuclide for both the disposal systems. The selected reference concept will be compared with the alternative geological concepts through a further study.

Several countries, including Korea, are considering the direct disposal of spent nuclear fuels. The radiological safety assessment results published after a geological repository closure indicate that the instant release is the main radiation source rather than the congruent release. Three Safety Case reports recently published were reviewed and the IRF values of seven long-lived radionuclides, including relevant experimental results, were compared. According to the literature review, the IRF values of both the CANDU and low burnup PWR spent fuel have been experimentally measured and used reasonably. In particular, the IRF values of volatile long-lived nuclides, such as 129I and 135Cs, were estimated from the FGR value. Because experimental leaching data regarding high burnup spent nuclear fuels are extremely scarce, a mathematical modelling approach proposed by Johnson and McGinnes was successfully applied to the domestic high burnup PWR spent nuclear fuel to derive the IRF values of iodine and cesium. The best estimate of the IRF was 5.5% at a discharge burnup of 55 GWd tHM−1.

The research for the safe management of high-level waste in Korea has been conducted by the Korea Atomic Energy Research Institute since 1997, and the results have formed the basis of the national basic plan for the high-level waste management and the revised national basic plan. In the future, it is evolving and developing R&D focusing on securing technologies for demonstration of the disposal technologies and R&D to develop disposal concepts that increase safety and improve efficiency. Efficient management of heat generated from high-level radioactive waste, including spent nuclear fuel, is an important factor in establishing the disposal concepts because it must be in harmony with key factors such as repository layout, waste disposal container specifications, and design and operation for the barriers of the disposal system. For safe and complete isolation of highlevel radioactive waste in the deep geology, the disposal systems that meet the thermal requirements for the disposal system design have been developed by harmonizing the thermal characteristics of engineered and natural barriers in Korea. These disposal systems were based on low burn-up spent nuclear fuel characteristics generated in the early stages of nuclear power generation, and next, based on the high-level wastes from recycling process of the high burn-up spent nuclear fuels, and were the direct disposal systems for the high burn-up spent nuclear fuels. So, it is necessary to track and analyze the change process in the decay heat characteristics of the high-level waste to be disposed of in order to improve the disposal concept, which enhances the safety of disposal and the utilization of the national land. Therefore, in this paper, the process of change in decay heat of reference spent nuclear fuels for disposal applied to the disposal concepts from the initial stage of development of high-level waste disposal technology to the present in Korea is analyzed.

Around 40 years ago, in the mid-1980s, Swedish government approved the KBS-3 method for the direct disposal of spent nuclear fuels (SNF) in Sweden. Since then, this method has become a reference for many countries including Korea, Republic of. The main ideas of the KBS-3 method are to locate SNF at 500 m below the ground surface using a copper disposal canister and a bentonite buffer. In 2016, our government announced the National Plan (NP 2016) regarding the final management of high-level waste (HLW) in Korea. In 2019, new committee were organized to review the NP 2016, and they submitted the final recommendations to the government in 2021. Finally, the government announced the 2nd National Plan in December, 2021. So far, KAERI has developed the technologies related to the final management of SNF in two directions. One follows ‘direct disposal’ based on the KBS-3 concept, and the other ‘recycling’ based on ‘pyroprocessing-and-SFR’ (PYRO-SFR). Even though Posiva and SKB obtained the construction permits with the KBS-3 method in Finland and Sweden, respectively, there are still several technical obstacles to applying directly to our situations. Some examples are as follows: high burnup, huge amounts of SNF, and high geothermal gradient in Korean peninsula. In this work, we try to illustrate some limits of the KBS-3 method. Within our country, currently, the most probable disposal option is the KBS-3 type geological disposal, but no one knows what the best option will be in 20 or 30 years if those kinds of drawbacks are considered. That is, we compare the effects of the drawbacks using our geological data and characteristics of spent fuels. Last year, we reviewed alternative disposal concepts focusing on the direct disposal of SNF and compared the pros and cons of them in order to enhance the disposal efficiency. We selected four candidate concepts. They were multi-level disposal, deep borehole disposal, sub-seabed disposal and mined deep borehole matrix. As mentioned before, KAERI has developed a pyroprocessing technology based on the SFR to reuse fissile radionuclides in SNF. Even though we can consume some fissile nuclides such as 239Pu and 241Pu using PYRO-SFR cycle, there still remain many long-lived radionuclides such as 129I and 135Cs waiting for the final disposal. The authors review and propose several concepts for the future final management of the long-lived radionuclides.

With respect to spent nuclear fuels, disposal containers and bentonite buffer blocks in deep geological disposal systems are the primary engineered barrier elements that are required to isolate radioactive toxicity for a long period of time and delay the leakage of radio nuclides such that they do not affect human and natural environments. Therefore, the thermal stability of the bentonite buffer and structural integrity of the disposal container are essential factors for maintaining the safety of a deep geological disposal system. The most important requirement in the design of such a system involves ensuring that the temperature of the buffer does not exceed 100℃ because of the decay heat emitted from high-level wastes loaded in the disposal container. In addition, the disposal containers should maintain structural integrity under loads, such as hydraulic pressure, at an underground depth of 500 m and swelling pressure of the bentonite buffer. In this study, we analyzed the thermal stability and structural integrity in a deep geological disposal environment of the improved deep geological disposal systems for domestic light-water and heavy-water reactor types of spent nuclear fuels, which were considered to be subject to direct disposal. The results of the thermal stability and structural integrity assessments indicated that the improved disposal systems for each type of spent nuclear fuel satisfied the temperature limit requirement (< 100℃) of the disposal system, and the disposal containers were observed to maintain their integrity with a safety ratio of 2.0 or higher in the environment of deep disposal.

국내 원자력발전소에서 발생하는 사용후핵연료의 제원 및 방출시점 등 특성과 현재의 고준위 방사성폐기물 기본계획에 근거한 처분시나리오를 도출하여 기존 심층 처분시스템을 바탕으로 처분효율과 경제성을 향상시킨 개선된 처분시스템을 제안 하였다. 이를 위하여 국내 원자력발전소에서 발생하는 사용후핵연료의 길이에 따라 2종류의 처분용기 개념을 도출하고, 사용후핵연료 발생 년도와 현재의 기본계획에 근거한 처분 시나리오 설정에 따른 처분시점에서의 냉각기간을 고려하여 처분 용기내 수용 가능한 붕괴열량을 결정하였다. 그리고 2종류의 처분용기에 대한 처분시스템과 결정된 붕괴열을 바탕으로 열 적 안정성 분석을 통하여 제안된 처분시스템의 설계요건에 대한 적합성 여부를 확인하고, 처분효율을 평가하였다. 개선된 처분시스템은 기존 처분시스템에 비하여 처분면적은 약 20% 감소되고 처분밀도는 약 20% 향상됨을 확인하였고, 처분용기와 완충재 재료도 상당량 절감됨을 확인하였다. 본 연구의 결과는 향후 사용후핵연료 관리정책 수립 및 실제 사업을 위한 처분시스템 설계를 위한 자료로 활용될 수 있다.

본 논문에서는 가압경수로(PWR) 고준위폐기물을 깊은 지하 500 m에 처분 시 사용되는 처분용기의 기본 구조설계에 필요한 처분용기 구조물에 대한 열응력 해석을 수행하였다. 일반적으로 고준위폐기물 처분용기는 지하 수백 미터에 위치하는 화강암 등의 암반 내에 설치하게 되는데, 이 때 처분용기는 내부 바스켓에 채워진 사용 후 핵연료다발의 높은 온도에 따른 열발생에 의하여 내부 주철삽입물 및 외곽쉘에 발생하는 열응력에 견디어야 한다. 따라서 본 논문에서는 처분용기 내부의 핵연료 다발의 열발생을 고려한 열응력 해석을 수행하였다 해석 방법은 유한요소법을 사용하였다. 직접 유한요소해석코드를 작성하는 대신에 구조물의 복잡성 및 유한요소개수의 많음을 고려하여, 상용 유한요소해석 코드인 NISA프로그램을 이용하여 열응력 해석을 수행하였다 해석 결과 처분용기에 가해지는 심지층 지하수압 및 벤토 나이트 버퍼의 팽윤압에 추가하여, 고온의 내부 핵연료다발에 의한 열하중이 작용하더라도 처분용기의 내부 주철삽입물에 발생하는 응력은 주철의 항복응력 보다 여전히 작아 처분용기는 구조적으로 안전함이 확인되었다

본 논문에서는 고준위 핵폐기물의 지하 처분 시 사용되는 핵폐기물 처분장치의 기본 구조설계에 필요한 처분장치내의 핵 폐기물다발들을 지지하는 내부 삽입물의 구조형상과 재원 또 처분장치의 화학적 부식을 방지하기 위해 외곽에 설치하는 외곽쉘과 위아래 덮개의 두께를 결정하기 위하여 처분장치 구조물에 대한 선형정적 구조해석을 수행하였다. 해석 대상 처분장치는 가압경수로와 중수로의 핵폐기물 처분장치를 사용하였다. 일반적으로 핵폐기물 처분장치는 지하수백 미터에 위치하는 화강암 등의 암반 내에 설치하게 되는데 이 때 지하수의 침수에 의한 지하수압 및 처분장치 외곽에 완충장치로 설치하는 벤토나이트 버퍼의 팽윤압을 견디어 내야 한다. 따라서 이와 같은 압력의 변화에 따른 처분장치 구조물에 발생하는 응력 및 변형 등을 알기 위해서는 처분장치 구조물에 대한 구조해석을 수행해야 된다. 이를 위하여 본 논문에서는 처분장치에 대하여 선형정적 구조해석을 수행하였다.