This study investigates the melting point and brazing properties of the aluminum (Al)-copper (Cu)-silicon (Si)-tin (Sn) alloy fabricated for low-temperature brazing based on the alloy design. Specifically, the Al-20Cu-10Si-Sn alloy is examined and confirmed to possess a melting point of approximately 520oC. Analysis of the melting point of the alloy based on composition reveals that the melting temperature tends to decrease with increasing Cu and Si content, along with a corresponding decrease as the Sn content rises. This study verifies that the Al-20Cu-10Si-5Sn alloy exhibits high liquidity and favorable mechanical properties for brazing through the joint gap filling test and Vickers hardness measurements. Additionally, a powder fabricated using the Al-20Cu-10Si-5Sn alloy demonstrates a melting point of around 515oC following melting point analysis. Consequently, it is deemed highly suitable for use as a low-temperature Al brazing material.

PURPOSES : The numeric-based Highway Pavement Management System (HPMS), along with an advanced three-dimensional pavement condition monitoring profiler vehicle (3DPM), in South Korea has presented remarkable advancements in pavement management since the early 2000. Based on these results, visual distress on pavement surfaces can be easily detected and analyzed. Additionally, the entire expressway pavement surface conditions in South Korea can be easily monitored using the current graphical user interface-based advanced information graphic (AIG) approach. Therefore, a critically negative pavement section can be detected and managed more easily and efficiently. However, the actual mechanical performance of the selected pavement layer still needs to be investigated in a more thorough manner not only to provide more accurate pavement performance results but also to verify the feasibility of the current 3DPM and AIG approaches. In this study, the low-temperature performance of the selected asphalt pavement layer section was evaluated to further verify and strengthen the feasibility of the current 3DPM and AIG approaches developed by the Korea Expressway Corporation. METHODS : Based on 3DPM and AIG approach, the positive and negative-riding-quality road sections were selected, respectively. The asphalt material cores were extracted from each section then bending beam rheometer mixture creep test was performed to measure their low-temperature properties. Based on the experimental results, thermal stress results were computed and visually compared. RESULTS : As expected, the asphalt material from the negative driving performance section presented a poorer low-temperature cracking resistance than that from the positive driving performance section. CONCLUSIONS : Current 3DPM equipment can successfully evaluate expressway surface conditions and the corresponding material performance quality. However, more extensive experimental studies are recommended to verify and strengthen the findings of this study

PURPOSES : Due to the frequent occurrence of accidents on icy roads during nighttime, it would be advantageous to notify road managers and drivers about the most perilous areas. This would allow road managers to treat the icy roads with de-icing chemicals and enable drivers to be better prepared for potential hazards. Essential information about pavement temperature is required to identify icy spots on the road. METHODS : With the goal of estimating nighttime pavement temperature on the National Highways in Korea using atmospheric data, the current study investigated a widely recognized forecasting method known as deep neural network (DNN). To achieve this objective, the input data for the models were gathered from the weather agency's website. The dataset comprised of relative humidity, air temperature, dew point temperature, as well as the differences in air temperature and humidity between two consecutive days. RESULTS : In order to assess the effectiveness of the built DNN model, a comparison was made using baseline pavement temperature data gathered through an infrared-based pavement temperature sensor installed in a highway patrol car. The results indicated that the DNN model achieved a mean absolute error (MAE) of 0.42 and a root mean square error (RMSE) of 0.62. In comparison, a conventional regression model yielded an MAE of 2.07 and an RMSE of 2.64. Thus, the DNN model demonstrated superior performance in comparison to the conventional regression model. CONCLUSIONS : Considering the increasing focus on preventive maintenance, these newly developed prediction models can be implemented proactively as a preventive measure against icing. This proactive approach has the potential to significantly improve traffic safety on winter roads.

PURPOSES : In this study, we aimed to evaluate the transition temperature (Tt) of asphalt binders using molecular dynamics simulations, which can provide a more accurate assessment of the mechanical properties of a material at the molecular level and can be applied to material development and design. METHODS : Unlike conventional macro- or meso-level simulations, we utilized MD simulations to evaluate the Tg of asphalt binders based on material composition and aging degree as input variables. In this analysis, 11 temperatures ranging from 434 K to 233 K at 20 K intervals were utilized, and the bulk volume and density were calculated through MD simulations. RESULTS : The MD simulation successfully predicted the Tg of the asphalt binder, and the molecular-level properties and interactions determined in this study can be applied not only to material development but also to the determination of constitutive equations or contact models used in continuum mechanics or discrete element methods. The calculated Tg was slightly different depending on the aging of the asphalt binder; however, it was found to accurately reflect the transitional characteristics. CONCLUSIONS : This study demonstrated the potential of MD simulations as valuable tools for material development and design in the construction industry. The results indicate that the use of MD simulations can lead to more accurate and efficient material development and design by providing a more detailed understanding of material properties and interactions at the molecular level.

본 연구에서는 육계사에 차열 페인트와 히트펌프의 적용에 따른 내부 온도 변화를 분석 하였다. 이를 위하여 환기율, 환기 방법, 시간별 환기 변화에 따른 실험 조건을 설정하였으며 육 계사 외부 및 내부 기온을 측정하였다. 그 결과, 차열 페인트를 도포한 육계사에서는 최대 1－2°C 실내 기온 상승을 억제하 는 효과가 나타났으며 히트펌프를 가동한 육계사에서는 외기 온도의 영향을 제일 적게 받는 환기율 0%일 때 내부 기온 감소 가 제일 크게 나타났다. 계사 내부의 온도가 외기 온도보다 높 을 경우에는 환기율을 높게 설정하여 환기팬을 이용한 냉방이 더욱 효과적이나 계사 내부 온도가 외기 온도와 유사하거나 낮을 경우에는 히트펌프를 이용하는 것이 가장 효과적일 것으 로 판단된다. 히트펌프 가동 시 외기 온도의 영향이 적은 환기 율을 0%로 설정하였을 때 내부 기온이 가장 큰 폭으로 감소하 였으나 실제 육계사에서는 분진, 이물질, 암모니아 등을 고려 하여 최소환기율 정도로 환기율을 설정한 후 히트펌프를 가동 하는 것이 가장 효율적일 것으로 판단된다. 본 연구는 실험 기 간이 짧아 데이터가 많지 않으며 실제 육계가 사육되고 있는 환경에서 실험을 진행한 것이 아니라는 한계가 있다. 향후 후 속 연구로 실제 닭이 사육되고 있는 환경에서의 히트펌프 효 과 분석과 히트펌프의 전력사용량, 냉방부하, 환기팬 가동시 간 등 다양한 환경인자를 포함한 연구가 진행되어야 할 것으 로 판단된다.

For the commercialization of hydrogen energy, a technology enabling safe storage and the transport of large amounts of hydrogen is needed. Porous materials are attracting attention as hydrogen storage material; however, their gravimetric hydrogen storage capacity (GHSC) at room temperature (RT) is insufficient for actual use. In an effort to overcome this limitation, we present a N-doped microporous carbon that contains large proportion of micropores with diameters below 1 nm and small amounts of N elements imparted by the nitrogen plasma treatment. The N-doped microporous carbon exhibits the highest total GHSC (1.59 wt%) at RT, and we compare the hydrogen storage capacities of our sample with those of metal alloys, showing their advantages and disadvantages as hydrogen storage materials.

백은무(Kalanchoe pumila)는 돌나물과(Crassulaceae)에 속 한 다육식물의 일종이다. 이 종은 학술적으로는 알려진 바가 거의 없는 미지의 식물이나 군생하여 자라며 분홍색 꽃을 개화 하기 때문에 관상가치가 높다. 이에 따라 본 연구에서는 온도 처리에 따른 백은무의 생육과 개화특성에 대해서 조사하였다. 온도는 주간/야간의 온도를 20/15, 24/19, 28/23, 32/27℃ 의 네 가지 단계로 설계하였다. 결과에서 백은무는 20/15℃ 처리구에서 초폭, 줄기의 지름, 피복면적, 엽수, 엽장, 엽폭, 지상부와 지하부의 생체중과 건물중, 꽃대의 길이, 꽃수, 화 장, 화폭이 가장 높은 것으로 나타났다. 따라서 백은무는 상대 적으로 저온의 환경에서 더 많은 탄소동화작용을 수행하는 것 으로 보인다. 한편, 24/19℃ 처리구에서는 초장과 정규식생지 수를 나타내는 normalized difference vegetation index (NDVI)가 가장 높은 것으로 나타났으며, 28/23℃ 처리구에서 는 근장과 안토시아닌 반사 지수 2를 나타내는 anthocyanin reflectance index 2(ARI2)가 가장 높은 것으로 나타났다. 32/27℃ 처리구에서는 대부분의 매개변수가 가장 낮은 것으 로 나타났으며, 생육이 거의 정지된 것으로 판단된다. 특히 과 거 연구에서 스트레스 지수로 활용된 매개변수인 CIELAB L* 과 b*는 32/27℃ 처리구에서 가장 높게 나타났다. 상관관계 분석에서는 L*은 지상부와 지하부의 생체중 및 건물중과 음의 상관관계를 가지는 것으로 나타나 잎의 명도(lightness)가 높 을수록 식물의 생육에 부정적인 것으로 평가되었다. 추가적으 로 b*도 이와 유사한 결과를 나타내었다. 결과적으로 백은무 의 식물체 크기를 유의미하게 증대시키고 개화 품질을 촉진시 켜 관상가치를 극대화하기 위해서는 20/15℃ 수준에서 재배 할 것을 권고한다.

In this study, numerical modeling on the gas flow and off-gases in the low temperature carbonization furnace for carbon fiber was analyzed. The furnace was designed for testing carbonization process of carbon fibers made from various precursors. Nitrogen gas was used as a working gas and it was treated as an incompressible ideal gas. Three-dimensional computational fluid dynamics for steady state turbulent flow was used to analyze flow pattern and temperature field in the furnace. The off-gas mass fraction and cumulative emission gas of species were incorporated into the CFD analyses by using the user defined function(UDF). As a results, during the carbonization process, the emission of CO2 was the dominant among the off-gases, and tow moving made the flow in the furnace be uniform.

In order to respond to environmental pollution, developed countries, including Korea, have begun to conduct research to utilize hydrogen energy. For mass transfer of hydrogen energy, storage as liquid hydrogen is advantageous, and in this case, the volume can be reduced to 1/800. As such, the transportation technology of liquefied hydrogen for ships is expected to be needed in the near future, but there is no commercialized method yet. This study is a study on the technology to test the performance of the components constituting the membrane type storage container in a cryogenic environment as a preparation for the above. It is a study to find a way to respond by analyzing in advance the problems that may occur during the shear test of adhesives. Through this study, the limitations of ISO4587 were analyzed, and in order to cope with this, the specimen was supplemented so that fracture occurred in the adhesive, not the adhesive gripper, by using stainless steel, a low-temperature steel, to reinforce the thickness. Based on this, shear evaluation was performed under conditions lowered to minus 243℃, and it was confirmed that the breaking strength was higher at cryogenic temperatures.

The influence of MgO addition on the densification and microstructure of alumina (Al2O3) was studied. Compacted alumina specimens were manufactured using ball-milling and one-directional pressing followed by sintering at temperatures below 1700oC. Relative density, shrinkage, hardness, and microstructure were investigated using analytical tools such as FE-SEM, EDS, and XRD. When the MgO was added up to 5.0 wt% and sintered at 1500oC and 1600oC, the relative density exhibited an average value of 97% or more at both temperatures. The maximum density of 99.2% was with the addition of 0.5 wt% MgO at 1500oC. Meanwhile, the specimens showed significantly lower density values when sintered at 1400oC than at 1500oC and 1600oC owing to the relatively low sintering temperature. The hardness and shrinkage data also showed a similar trend in the change in density, implying that the addition of approximately 0.5 wt% MgO can promote the densification of Al2O3. Studying the microstructure confirmed the uniformity of the sintered alumina. These results can be used as basic compositional data for the development of MgOcontaining alumina as high-dielectric insulators.

In this study, we evaluated the effects of acid leaching on the properties of Cr powder synthesized using self-propagating high-temperature synthesis (SHS). Cr powder was synthesized from a mixture of Cr2O3 and magnesium (Mg) powders using the SHS Process, and the byproducts after the reaction were removed using acid leaching. The properties of the recovered Cr powder were analyzed via X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), particle size analysis (PSA), and oxygen content analysis. The results show that perfect selective leaching of Cr is challenging because of various factors such as incomplete reaction, reaction kinetics, the presence of impurities, and incompatibility between the acid and metal mixture. Therefore, this study provides essential information on the properties under acidic conditions during the production of high-quality Cr powder using a self-propagating high-temperature synthesis method.

홍삼의 일반적인 가공법인 물과 주정 혼합용매로 추출여과하여 농축액으로 제조 시 증숙 등의 가열처리에 의해 가수분해되거나 중합반응이 일어나게 되어 현재 기능성이 밝혀진 30여 가지 주요 진세노사이드 외 극미량인 200여 종의 진세노사이드가 검출되고 있어서, 오히려 홍삼 본래 의 기능성 규명과 효능 구현을 복잡하게 만들고, 추출 횟 수를 거듭할수록 떫은맛이 강해지는 등 건강기능식품으로 서 부정적인 영향을 배제하기 위하여 저온(40oC 미만)에 서 1차만 추출한 홍삼농축액을 제조한 결과 수율은 고형 분 66-77% 정도에서 26-30%를 나타내어 기존의 연구 결 과인 40.47±0.47% 보다 현저히 적은 수율을 나타내었고, 동결건조 분말의 진세노사이드 함량분석시험을 진행한 결 과 시료 18종 전체에서 진세노사이드 34종이 검출되었고, 특히 홍삼 지표성분 3종인 Rb1, Rg1, Rg3 합계는 42.48 mg/ g으로 시판 홍삼제품의 환산량 9.0 mg/g과 8.7 mg/g 보다 4-5배 많았다. 본 시료는 진한 홍삼의 향취와 함께 면역력 증진 등 6가지 기능발현에 9-25%의 소량 복용으로 1일 복 용량이 유의성 있게 작아서 복용의 편의성과 함께 제품의 보관, 유통에 장점이 있는 것으로 판단된다.

Cyanobacteria Pseudanabaena strains are known to produce 2-MIB (odorous material) in freshwater systems, thereby causing problems in water use. However, their physiological responses to environmental factors in relation with 2-MIB production is not well explored. This study was conducted to evaluate the effect of temperature on the growth and 2-MIB production of Pseudanabaena redekei. The experimental cyanobacteria strains were separated from the Uiam Reservoir (North Han River) and cultured in the BG-11 medium. Temperature was set to 10, 15, 20, 25, and 30℃ for the experiment, in the reflection of the seasonal water temperature variation in situ. For each temperature treatment, cyanobacterial biomass (Chl-a) and 2-MIB concentration (intra-cellular and extra-cellular fractions) were measured every 2 days for 18 days. Both maximal growth and total 2-MIB production of P. redekei appeared at 30℃. While intra-cellular 2-MIB contents were similar (26~29 ng L-1) regardless of treated temperatures, extra-cellular 2-MIB concentration was higher only in high temperature conditions (25~30℃), indicating that the extents of 2-MIB biosynthesis and release by P. redekei vary with temperature. The 2-MIB productivity of P. redekei was much higher in low-temperature conditions (10~15℃) than high temperature conditions (25~30℃). This study demonstrated that temperature was a critical factor contributing to 2-MIB biosynthesis and its release in cell growth (r=0.605, p<0.01). These results are important to understand the dynamics of 2-MIB in the field and thereby provide basic information for managing odorous material in drinking water resources.

이 논문에서는 내구성이 우수한 것으로 알려져 있는 펄트루젼 FRP의 습도 노출 및 동결 융해 영향을 검토하고, 이에 따른 국부좌굴강도 영향을 검토하기 위한 해석적 연구를 수행하였다. FRP는 일반적으로 내구성이 우수하다고 알려져 있기 때문 에, 해양 구조물 등 습윤환경에서 적용하기 위한 다양한 연구가 진행되고 있으며, 특히 구조용 부재로 제작되는 펄트루젼 FRP 부재는 하절기와 동절기의 온도변화에 노출되기 때문에 이에 대한 검토가 필요하다. 펄트루젼 FRP의 습도 노출 및 동결 융해 영향은 기존 연구의 실험 결과를 참고하였으며, 국부좌굴강도는 정밀해법을 통해 영향을 검토하였다. 검토 결과 펄트루젼 FRP 는 습도노출 및 동결융해의 영향으로 인해 최대 약 20%의 인장강도 및 탄성계수 변화를 나타내었으나, 국부좌굴강도는 약 3% 로 그 영향이 상대적으로 작은 것으로 나타났다. 따라서, 온도이력 및 습윤환경에서도 펄트루젼 FRP는 국부좌굴강도의 큰 변화 를 나타내지 않고 높은 내구성을 나타낼 수 있을 것으로 판단된다.

본 연구에서는 공정 간소화, 균일한 나노 입자 형성, 백금 저감 및 활용도를 높이기 위하여 원자층 증착법 (Atomic Layer Deposition, ALD)을 통하여 양이온 교환막 연료전지용 촉매를 제조하고 증착 온도에 따른 백금 입자 형성 거동 을 확인하였다. 증착 온도는 250 °C, 300 °C, 350 °C로 조절하여 백금 촉매를 형성하였으며 각 각의 촉매의 증착 양 상을 확인하기 위하여 Thermogravimetric analysis, X-ray diffraction 및 Transmission electron microscopy를 도입하여 담지량, 백금 입자 분포, 크기 및 결정구조 등을 확인하였다. 합성된 백금 촉매를 연료전지에 적용하기 위해서 Cyclic Voltammetry 기법을 통해서 전기화학적 활성 표면적를 구하고, Membrane Electrode Assembly 셀을 제작하여 전지 특성을 확보하였다. 최종적으로, 백금 촉매 제조 시 ALD 증착 온도는 300 °C 이하에서 합성해야 됨을 밝혀냈으며, ALD으로 제작된 백금 촉매가 기존 습식 촉매보다 더 우수한 특성을 보임을 확인하였다. 해당 연구는 ALD을 통하여 다양한 접근법으로 촉매를 제조할 시, 기본적인 ALD 공정 정보 및 ALD 촉매 합성 방향성을 제공할 수 있다.

본 연구는 국내 산림생명자원 중 광나무의 대량생산을 위한 기초연구로, Priming 처리에 따른 발아 효율성 및 유묘 생육특성에 미치는 영향을 구명하고자 수행하였다. 종자 Priming처리는 대조구, GA3 (10, 100, 200 ㎎·L-1), Ca (NO3)2 (50, 100, 200 mM), KNO3 (50, 100, 200 mM)를 24시간 처리하여 발아특성을 분석하였고, 순화재배에 따른 생육특성 및 활착률을 조사하여 수확량을 비교·분석하였다. 발아특성은 25℃·KNO3 100 mM에서 발아율이 유의적으로(p<0.001) 높았으며, 평균발아일수는 10.3~18.1일로 15℃에서 대체적으로 빠른 발아일수를 나타냈다(p<0.001). 발아속도 및 발아균일지수 또한 25℃·KNO3 100 mM에서 유의적으로 높은 값을 보였다(p<0.001). 생육특성의 경우 2 5℃·KNO3 100 mM 처리에서 유근 길이(5.1±2.4 ㎝), 초장(5.7±0.7 ㎝), 근장(16.6±2.0 ㎝), 건중량(0.079 g)이 유의적으로 가장 높게 나타났다 (p<0.001). 유묘활력지수 또한 25℃·KNO3 100 mM 처리에서 1418.3으로 높았으며, 가장 높은 수확량(16.8 g/㎡)을 나타냈다. 결과적으로 25℃, KNO3 100 mM 처리 시 실내발아에서 발아효율성을 높일 수 있었으며, 순화재배 시 우수한 유묘 생육을 보여 수확량을 증진시킬 수 있었다.

Crystallographic properties of Ni-based alloys such as alloys 600, 617, and Hastelloy N, which are a candidate to be used as structural materials in Molten Salt Reactor (MSR), were studied in the temperature range of 25-1,000°C using high-temperature X-ray diffraction (HT-XRD) under an Ar atmosphere. We found that face-centered cubic Ni crystal structure at room temperature was started to be changed over 600°C in all Ni-based samples. However, the appearance of changing diffraction patterns over 600°C was different for all samples. In addition, we observed the increase in the lattice constant along the a-axis upon heating in all specimens, determined by Pawley refinement of HTXRD data.

LiCl-KCl eutectic possesses unique properties such as a low melting point, high thermal conductivity, and good electrical conductivity. These properties make it suitable for various applications, including nuclear power generation, pyroprocessing in nuclear waste management, and thermal energy storage systems. In most experiments using LiCl-KCl, the molten salt composition is an important factor; therefore, periodic analysis through sampling is necessary for monitoring compositional changes. Although manual sampling is typically used, it is time-consuming and can introduce errors due to low reproducibility. To address this issue, we have developed an automatic molten salt sampling device using the cold-finger method. This method involves immersing the tip of a tungsten rod in hightemperature LiCl-KCl, removing it after a few seconds, and allowing the adhered molten salt to solidify instantly. A collector then scratches and drops the solidified sample. These processes are carried out automatically using servo motors, enabling the sampling device to move around the molten salt system. We have optimized the sampling conditions, such as insertion and withdrawal rate, immersion time, and the interval between continuous sampling, based on the molten salt temperature. The temperature was set between 500°C and 850°C, considering the operating temperatures of the applications. In addition to sampling speed, the sampling depth is a key condition for determining the sampling mass. Therefore, we examined the amount of sample depending on the sampling depth and, particularly, considered the change in salt height when sampling is performed continuously. As a result, we determined the number of sampling iterations required to reach the target sample mass. Furthermore, to minimize the initial salt loss, we noted that sampling from the salt surface resulted in less representative samples. To determine the reliability, we compared the results of surface sampling with those obtained when sampling at the middle of the salt. This study will enable highly reproducible and reliable sampling by providing a prototype for an automatic sampling device for molten salt along with guidelines.

Change in chemical constitution of a zirconium sample treated at the simulated condition of a pressurized water reactor (water at 315°C and 15.5 MPa) was investigated using X-ray diffraction (XRD) and Raman spectroscopy. We observed swelling of the zirconium sample as well as the change in its color from silver to gray treated after the pressurized water at high temperature. On the basis of XRD and Raman data, we confirmed that the variation in composition of zirconium specimen from hexagonal Zr to monoclinic ZrO2 occurred at the simulated PWR condition. Therefore, we suggested that the oxidation of zirconium appeared due to the reaction with water at high temperature and pressure, as shown in the following reaction: Zr + 2H2O → ZrO2 + 2H2.

It is reported that 48 pressurized heavy water reactors (PHWRs) are in operation, and 10 PHWRs including Wolsong-1 NPP have been permanently shut down in the world. In the case of PHWRs, which have been permanently ceased, they are managed through the delayed decommissioning method, but there are no cases of dismantling. Therefore, technology development is urgent for the effective decommissioning of PHWRs. Unlike PWRs, PHWRs are separated into coolant system and moderator system. Most of pipes and systems of coolant system are mainly composed of carbon steel, expect of the steam generator tubes which are composed of nickel alloy. On the other hand, the moderator system is composed of stainless steel. In the case of stainless steel, the inner layer of the oxide film is composed of chromium oxide, and the outer layer is composed of iron and nickel oxide in enriched. To remove two oxide layers, it is needs to different decontamination method, the coolant system can perform the system decontamination process through a reduction process, but in the case of the moderator system, the oxidation/reduction process is required because it has a material and oxide film similar to PWRs. In this study, this is evaluated the oxide film removal rate according to the type of stainless steel and temperature in order to remove the oxide film deposited in the moderator system. The experiments were carried out at temperatures of 60, 70, 80 and 90°C, with a concentration of 200 ppm of permanganic acid and nitric acid, and 2,000 ppm of oxalic acid, respectively. The results of the oxide film removal rate test for SUS304 showed 29% at 60°C, 38% at 70 and 80°C, and 41% at 90°C. For SUS403, the oxide film removal rate experiment results showed 62% at 60°C, 85% at 70°C, 94% at 80°C, over 99% at 90°C. The results showed that the removal efficiency of the oxide film increased as the temperature increased. Following the results of experimental, the optimum temperature of oxide removal in composed of the stainless steel material is to be 90°C for decontamination of PHWR.