This study is carried out to obtain basic data regarding oxidation and reduction reactions, originated on the recycling of waste tungsten hard scraps by oxidation and reduction processes. First, it is estimated that the theoretical Gibbs free energy for the formation reaction of WO2 and WO3 are calculated as ΔG1,000K= -407.335 kJ/mol and ΔG1,000K = -585.679 kJ/mol, from the thermodynamics data reported by Ihsan Barin. In the experiments, the oxidation of pure tungsten rod by oxygen is carried out over a temperature range of 700-1,000oC for 1 h, and it is possible to conclude that the oxidation reaction can be represented by a relatively linear relationship. Second, the reduction of WO2 and WO3 powder by hydrogen is also calculated from the same thermodynamics data, and it can be found that it was difficult for the reduction reaction to occur at 1,027oC, in the case of WO2, but it can happen for temperatures higher than 1127oC. On the other hand, WO3 reduction reaction occurs at the relatively low temperature of 827oC. Based on these results, the reduction experiments are carried out at a temperature range of 500-1,000oC for 15 min to 4 h, in the case of WO3 powder, and it is possible to conclude that the reduction at 900oC for 2h is needed for a perfect reduction reaction.

This study was conducted to provide strategies for the reduction of plate waste and prevention of plate waste reuse in foodservice operations. To achieve these goals, we surveyed the entrepreneurs of foodservice operations, professionals in the field of foodservice management and food safety, and public officials working for food safety enforcement about their perceptions and strategies on plate waste management. The professionals’ survey indicated that definition of plate waste needed to be clear for understanding. Also Korean food culture insisting on abundance and variety table settings, foodservice owners' demands for cost reduction, and foodservice workers' insufficient safety perceptions were indicated to bring forth the practice to reuse plate waste. The effective ways to control plate waste management were systematic educational supports for Korean food culture upgrade among consumers and improvements of safety perceptions among owners, as well as workers. Also small portion size was needed to reduce plate waste.

경막결정화를 이용한 산화물 사용후연료의 전해환원 공정에서 발생하는 LiCl 염폐기물 내 포함되어 있는 Cs 및 Sr을 분리(농축)에 대한 실험을 수행하였다. 결정화 공정에서 Cs 및 Sr과 같은 불순물들은 불순물들의 용융염 상 및 결정상에 대한 용해도이 차리로 분리되어 최종적으로 작은 양의 LiCl 용융염내에 농축된다. 본 연구에서는 LiCl-CsCl-SrCl2 계에대한 고체-액체 상평형도를 통해 결정화를 통한 분리가능성을 파악하였으며 열전달방정식 의 계산을 통해 경막결정화 운전중 LiCl 용융염상의 온도분포를 예측할 수 있었다. 경막결정화 공정에서 결정성 장 속도는 분리효율에 큰 영향을 미쳤으며 90%의 LiCl 재생율을 가정할 경우 20-25 l/min의 냉각속도 그리고 0.2 g/min·cm2보다 작은 결정성장 속도조건에서 각각의 Cs 및 Sr에 대하여 90% 정도의 분리효율을 나타내었다.

In the present study, the focus is on the analysis of carbothermal reduction of oxide powder prepared from waste WC/Co hardmetal by solid carbon under a stream of argon for the recycling of the WC/Co hard-metal. The oxide powder was prepared by the combination of the oxidation and crushing processes using the waste hardmetal as the raw material. This oxide powder was mixed with carbon black, and then this mixture was carbothermally reduced under a flowing argon atmosphere. The changes in the phase structure and gases discharge of the mixture during carbothermal reduction was analysed using XRD and gas analyzer. The oxide powder prepared from waste hardmetal has a mixture of . This oxide powder reduced at about , formed tungsten carbides at about , and then fully transformed to a mixed state of tungsten carbide (WC) and cobalt at about by solid carbon under a stream of argon. The WC/Co composite powder synthesized at for 6 hours from oxide powder of waste hardmetal has an average particle size of .

대표적인 산업부산물인 폐주물사와 플라이애쉬의 재활용은 매우 시급한 현안중의 하나이다. 이러한 산업부산물의 재활용을 위해 저강도 콘크리트 개념을 적용한 유동성채움재(CLSM)로의 재활용을 위한 기본 연구가 지난 3년간 수행되었다. 본 연구에서는 폐주물사중 환경오염문제의 발생 가능성이 적은 것을 선별하여 CLSM용 잔골재로 이용하였다. 특히, 폐주물사에 화학약품처리를 하여 재활용 잔골재로 이용하는 방식사 역시 실험 재료로 이용하였다. 실험은 기존에 보편적으로 이용되는 뒤채움재 시공시 발생하는 사일로 토압에 대한 검증과 토압 경감효과에 대한 연구를 수행하였다. 실험결과 CLSM은 기존의 뒤채움재와는 그 성질이 매우 달라서, 옹벽배면과 절개면사이의 거리가 짧아서 발생하는 사일로 토압효과는 나타나지 않았다. 이는 기존의 뒤채움재와는 상당히 다른 재료이고, 또한, 기존에 이용되는 각종 토압론의 공식적용에 다소 신중해야 할 것으로 판단된다. 사용된 잔골재용 시료중에서는 방식사가 가장 큰 토압경감 효과를 나타냈고, 사용된 CLSM의 잔골재 특성에 따라 토압경감 효과에 다소 시간적인 차이는 있으나, 그 절대값은 어느 정도 일정한 값으로 수렴하는 것으로 나타났다.

대표적인 산업부산물인 폐주물사와 플라이애쉬의 재활용은 매우 시급한 현안중의 하나이다. 이러한 산업부산물의 재활용을 위해 저강도 콘크리트 개념을 적용한 유동성채움재(CLSM)로의 재활용을 위한 기본 연구가 지난 3년간 수행되었다. 본 연구에서는 폐주물사중 환경오염문제의 발생 가능성이 적은 것을 선별하여 CLSM용 잔골재로 이용하였다. 특히, 폐주물사에 화학약품처리를 하여 재활용 잔골재로 이용하는 방식사 역시 실험 재료로 이용하였다. 실험은 기존에 보편적으로 이용되는 뒤채움재 시공시 발생하는 사일로 토압에 대한 검증과 토압 경감효과에 대한 연구를 수행하였다. 실험결과 CLSM은 기존의 뒤채움재와는 그 성질이 매우 달라서, 옹벽배면과 절개면사이의 거리가 짧아서 발생하는 사일로 토압효과는 나타나지 않았다. 이는 기존의 뒤채움재와는 상당히 다른 재료이고, 또한, 기존에 이용되는 각종 토압론의 공식적용에 다소 신중해야 할 것으로 판단된다. 사용된 잔골재용 시료중에서는 방식사가 가장 큰 토압경감 효과를 나타냈고, 사용된 CLSM의 잔골재 특성에 따라 토압경감 효과에 다소 시간적인 차이는 있으나, 그 절대값은 어느 정도 일정한 값으로 수렴하는 것으로 나타났다.

Food waste is both an industrial and residential source of pollution, and there has been a great need for food waste reduction. As a preliminary step in this study, waste reduction is quantitatively modeled. This study presents two models based on kinetics: a simple kinetic model and a mass transport-shrinking model. In the simple kinetic model, the smaller is the reaction rate constant ratio k1 , the lower the rate of conversion from the raw material to intermediate products. Accordingly, the total elapsed reaction time becomes shorter. In the mass transport-shrinking model, the smaller is the microbial decomposition resistance versus the liquid mass transfer resistance, the greater is the reduction rate of the radius of spherical waste particles. Results showed that the computed reduction of waste mass in the second model agreed reasonably with that obtained from a few experimantal trials of biodegradation, in which the microbial effect appeared to dominate. All calculations were performed using MATLAB 2020 on PC.

Over the past two decades, the options for solid waste management have been changing from land disposal to recycling, waste-to-energy, and incineration due to growing attention for resource and energy recovery. In addition, the reduction of greenhouse gas (GHG) emission has become an issue of concern in the waste sector because such gases often released into the atmosphere during the waste management processes (e.g., biodegradation in landfills and combustion by incineration) can contribute to climate change. In this study, the emission and reduction rates of GHGs by the municipal solid waste (MSW) management options in D city have been studied for the years 1996-2016. The emissions and reduction rates were calculated according to the Intergovernmental Panel on Climate Change guidelines and the EU Prognos method, respectively. A dramatic decrease in the waste landfilled was observed between 1996 and 2004, after which its amount has been relatively constant. Waste recycling and incineration have been increased over the decades, leading to a peak in the GHG emissions from landfills of approximately 63,323 tCO2 eq/yr in 2005, while the lowest value of 35,962 tCO2 eq/ yr was observed in 2016. In 2016, the estimated emission rate of GHGs from incineration was 59,199 tCO2 eq/yr. The reduction rate by material recycling was the highest (-164,487 tCO2 eq/yr) in 2016, followed by the rates by heat recovery with incineration (-59,242 tCO2 eq/yr) and landfill gas recovery (-23,922 tCO2 eq/yr). Moreover, the cumulative GHG reduction rate between 1996 and 2016 was -3.46 MtCO2 eq, implying a very positive impact on future CO2 reduction achieved by waste recycling as well as heat recovery of incineration and landfill gas recovery. This study clearly demonstrates that improved MSW management systems are positive for GHGs reduction and energy savings. These results could help the waste management decision-makers supporting the MSW recycling and energy recovery policies as well as the climate change mitigation efforts at local government level.

This study examined the potentials for greenhouse gas reduction by material recovery and energy recovery from municipal solid waste between 2017 and 2026 in Daejeon Metropolitan City (DMC), which is trying to establish a material-cycle society by constructing a waste-to-energy town by 2018. The town consists of energy recovery facilities such as a mechanical treatment facility for fluff-type solid refuse fuel (SRF) with a power generation plant and anaerobic digestion of food waste for biogas recovery. Such recycling and waste-to-energy facilities will not only reduce GHGs, but will also substitute raw materials for energy consumption. The emissions and reduction rate of GHGs from MSW management options were calculated by the IPCC guideline and EU Prognos method. This study found that in DMC, the decrease of the amount of MSW landfilled and the increase of recycling and waste-to-energy flow reduced GHGs emissions from 167,332 tonCO2 eq/yr in 2017 to 123,123 tonCO2 eq/yr in 2026. Material recycling had the highest rate of GHG reduction (-228,561 tonCO2 eq/yr in 2026), followed by the solid refuse fuels (-29,146 tonCO2 eq/yr in 2026) and biogas treatment of food waste (-3,421 tonCO2 eq/yr in 2026). This study also shows that net GHG emission was found to be -30,505 tonCO2 eq in 2017 and -105,428 tonCO2 eq, indicating a great and positive impact on future CO2 emission. Improved MSW management with increased recycling and energy recovery of material waste streams can positively contribute to GHGs reduction and energy savings. The results of this study would help waste management decision-makers clarify the effectiveness of recycling MSW, and their corresponding energy recovery potentials, as well as to understand GHG reduction by the conversion.

온실가스인 이산화탄소는 다른 온실가스에 비해 Global Warming Potential(GWP)가 가장 낮지만 배출량이 전체 온실가스 중 88 %의 비중을 차지하고 있다. 많은 국가에서 기후변화에 관심을 가지고 이산화탄소 저감에 대한 연구개발이 활발히 일어나고 있다. 본 연구에서는 암모늄 화합물을 이용하여 이산화탄소를 포집하고 산업폐기물의 금속이온을 이용하여 무기재료인 탄산칼슘을 생성하는 다양한 방법을 소개한다. 탄산칼슘 생성을 위해 칼슘이온이 포함된 탈황석고, 폐시멘트를 이용하였다. 결과에서 이산화탄소 포집 성능 및 최종생성물의 결정구조를 확인하였으며, 이산화탄소 loading 값  는 약 2.0의 값을 가진다. X-Ray Diffraction, Scanning Electron Microscope의 분석을 통하여 탄산칼슘이 생성되었음을 확인하였으며, 결정구조는 Vaterite가 생성됨을 확인할 수 있다. 효과적인 공정을 위하여, 생성물을 생성한 후 용액을 회수하여 재이용할 수 있어 연속적인 공정이 가능하다. 회수된 용액의 재이용의 가능성을 보기위하여 이산화탄소를 재흡수 시키면서 같은 공정을 2cycle씩 진행하여, 연속적인 공정의 잠재성을 확인하였다.

In recent years, waste-to-energy conversion using municipal solid waste (MSW) has been gaining attention in municipalities. Such conversion can reduce the dependency of non-renewable energy such as fossil fuels by generating solid refuse fuel (SRF) and diverting landfilling of the waste, although there is debate over the efficiency and economic aspect of the practice. With a growing interest in the conversion, D city is trying to adopt all possible measures towards achieving a material-cycle society by constructing a waste-to-energy town by 2018. The waste-to-energy town will be comprised of energy recovery facilities such as a mechanical treatment facility for fluff-type SRF with a power generation plant, and anaerobic digestion of food waste for biogas recovery. In this paper, we focus on estimating the energy recovery potentials and greenhouse gas (GHG) reduction of MSW by waste-to-energy conversion under three different scenarios. The data required for this study were obtained from available national statistics and reports, a literature review, and interviews with local authorities and industry experts. The lower heating value was calculated using the modified Dulong equation. Based on the results of this study, the energy recovery potential of MSW was calculated to be approximately 14,201-51,122 TOE/y, 12,426-44,732 TOE/y, and 8,520-30,673 TOE/y for Scenarios 1, 2, and 3, respectively. The reduction of GHG by such conversion was estimated to range from 10,074-36,938 tonCO2eq/y, depending on scenario. This study would help determine the production rate of fluff-type SRF to be converted into a form of energy. In addition, this study would aid waste management decision-makers to clarify the effectiveness of recycling of MSW and their corresponding energy recovery potentials, as well as to understand GHG reduction by the conversion.

With a growing concern of greenhouse gas (GHG) emissions due to climate change, many activities and efforts onthe greenhouse gas reduction have been implemented in solid waste sectors. Since recycling is the major managementoption for solid waste in Korea, it is important to estimate the reduction of the greenhouse gas emission during recyclingprocesses. In this study, two common methodologies, Prognos method of EU and waste reduction model (WARM) methodof USA, have been critically reviewed and compared to estimate the reduction for recycling of waste paper in terms ofsystem boundary, recycling processes, and emission factors. As a common point of two methodologies, the reductionfactors for the paper recycling have been developed by subtracting the recycled product emissions from the virgin productemissions to get the greenhouse gas savings. While the recycling losses and transportation are considered in twomethodology development, there are a number of differences between the methodologies in system boundary,transportation distance and forest carbon sequestration. As a result, it caused the difference in final greenhouse gasreduction factor of paper recycling. The reduction factor was −820kgCO2eq/ton in Prognos method, while −3,891kgCO2eq/ton was found in the WARM method. When both methods were applied to recycling of waste paper in Korea,the greenhouse gas reductions by the Prognos method and the WARM method were found to be 3,485.2tCO2eq/day and2,248.8tCO2eq/day, respectively. When the carbon sequestration by forest is considered in the WARM method, thereduction rate was estimated to be 16,538.3tCO2eq/day. The main reasons for such difference can be attributed to systemboundary and forest carbon sequestration. Especially, forest carbon sequestration can be an important factor in Korea thatusually manufactures papers from imported pulp from abroad. This study implies that the applications and results of bothmethods to estimate greenhouse gas reduction by waste recycling should carefully reviewed and acknowledged beforeuse due to the different assumptions and results that are anticipated.

According to the quality standards of the BIO-SRF(Bio-Solid Fuel Products) in Act on the Promotion of Saving and Recycling of Resources enforcement regulations, chloride is regulated to less than 0.5wt.%. The reason why chloride was regulated may generate HCl and dioxin when bio-solid fuel was burnt. Chloride and chloride compounds can be presented the characteristic of corrosiveness. These materials is reacted with iron to produce ferric chloride. Ferric chloride is oxidized to ferric oxide and ferric oxide can cause a pipe corrosion to short boiler life in combustion facility. There are several reactions to reduce Cl concentration in organic wastes and some wastes can be used in nucleophile reaction as reductive agents. Nucleophile(Nu) material can be represented by phosphate, nitrate, sulfate etc. Nu materials can substitute them for chlorine-based compounds(X-: Cl-, Br-, I-). Nu materials can reduce the harmfulness and chlorine concentration by substituting them for chlorine-based compounds of the solid fuel product produced by carbonization. In order to produce solid fuel product from organic wastes, carbonization among pyrolysis processes is suitable because nucleophile reaction should be an endothermic reaction, which heat must be entered to solid fuel product from outside. In this study, sewage sludge is used as a reductive agent to evaluate the characteristics of the reduction reaction in carbonization process because a large amount of Nu material is contained in sewage sludge. In order to evaluate the effect of Nu materials to control chloride in the residue of carbonization, waste wood mixed with sewage sludge was used in carbonization process.

This study was to select five places among apartment houses (apartment), detached houses (including houses, villas), downtown area (markets, shops, restaurants) being operated in Korea and use the analysis of physical and chemical characteristics for treatment residues of weight reduction equipment as basic data. Also, we were to evaluate the recyclability by determining whether discharged treatment residues are available in the thermochemical process such as cement sintering facilities and power plants in which energy can be recovered based on the quality standards of Bio- SRF and SRF. Three components for food waste were analyzed and as a result, moisture average, combustibles average and ash average were found to be 11.9% (2.0 ~ 24.8%), 78.9% (63.3 ~ 93.0%) and 9.2% (5.0 ~ 11.9%) respectively and all of them were found to satisfy less than 25%, the moisture content standard of Solid Refuse Fuel (SRF) products. The results of the elemental analysis were analyzed to be carbon average 49.71% (48.41 ~ 52.14%), hydrogen average 6.62% (31.32 ~ 40.63%), oxygen average 37.92% (31.32 ~ 40.63%), nitrogen average 3.82% (2.79 ~ 5.81%), sulfur average 0.26% (0.19 ~ 0.46%), chlorine average 1.67% (1.10 ~ 3.16%). In addition, the low-heating value measurement result is average 4,016.6 kcal/kg (3,255.9 ~ 4,657.9 kcal/kg) and turned out to satisfy most general Solid Refuse Fuel (SRF) product standards but that of Facility E is 3,255.9 kcal/kg and was analyzed not to meet the quality standard 3,500 kcal/kg. However, if maintaining the moisture content of treatment residues to 20% or less, it is determined to satisfy the caloric value standards of general Solid Refuse Fuel products.

In spite of the government's various efforts to reduce food waste, the food waste in Korea has increased about 3%every year, mainly due to the growing population, number of households, and income. Food waste occurs in the processesof production, transportation, distribution, storage and cooking of food ingredients. However, there has been little reliabledata about how households - a major food waste source - store and treat their food and how much food waste they produce.In this regard, we thought it was important to understand the exact amount and characteristics of food waste fromhouseholds in order to reduce the country's food waste, which is why we monitored kinds, storage periods, treatment,and waste of food consumed in 100 households in the Seoul metropolitan area. Households normally store their foodingredients in refrigerators - on average 33 kinds and 35kg of food are stored - and some of them stayed there for upto 3 years. Moreover, not a small portion of the food is thrown away nearly untouched, mostly because people tend topurchase too much food at one time or they don't know or miss their expiration dates. The amounts of food waste bytype were in the order of vegetable>side dish>frozen food>fruit>seasoning. Also, we suggest effective and realisticmeasures to reduce food waste and promote a more desirable food consumption culture.