세라믹 분리막은 높은 열적, 화학적 안정성을 갖기 때문에 극한의 조건에서 운전되는 다양한 산업 공정에 적용할 수 있다. 그러나 투과도와 기계적 강도의 trade-off 현상에 의한 세라믹 분리막 활용에 제약이 있어, 고투과성-고강도 분리막 의 개발이 필요하다. 본 연구에서는 상전이-압출법으로 알루미나 중공사 분리막을 제조하고, 고분자 바인더의 종류와 그 혼합 비에 따른 분리막의 특성 변화를 관찰하였다. 용매인 DMAc (Dimethylacetamide)와 고분자 바인더의 한센 용해도 인자를 비 교하면, PSf (polysulfone)가 DMAc와 높은 용해도 특성을 갖기 때문에 도프 용액의 점도와 토출압력이 높게 나타나 분리막 내부가 치밀한 구조로 형성되기 때문에 높은 기계적 강도를 갖으나 수투과도가 감소하는 것으로 확인되었다. 그에 반해, PES (polyethersulfone)를 이용하여 분리막을 제조하면 기계적 강도가 다소 감소하고 수투과도가 증가하는 것으로 나타났다. 따라 서 분리막 성능과 물성을 최적화하기 위해 PSf와 PES를 혼합하여 분리막을 제조하였으며, 9:1로 혼합하여 제조된 분리막에 서 최적화된 수투과도와 기계적 강도를 얻을 수 있었다.

본 논문은 인간의 양면성에 대한 탐구를 바탕으로 예술적 언 어의 표현에 대한 연구이다. 철학에서 언급되는 논조의 이해를 바탕으로 회화, 도자 등 다양한 작품을 조사하였다. 이를 통해 각각의 예술가들이 시대별 환경 속에서 양면성에 대해 어떤 차 별적 관점으로 작업을 진행했는지 고찰하였다. 첫째, 동서양의 철학과 심리학의 기본이론과 함께 양면성에 대한 다양한 이해를 문헌 자료를 통해 고찰했다. 모든 사람이 내적, 외적 또는 이성과 감성의 양면성을 가지고 있음을 확인 하고, 인간의 내적 갈등과 복잡성을 탐구했다. 둘째, 미술작품 실례를 조사하고 형태와 특징을 분석했다. 예 술가는 개인의 내면적 감정이나 사회현상에 따른 사람들의 심 리상태를 작품형태로 표현한다. 인간의 양면성을 주제로 한 작 품들은 내면을 표현하고 주목하는 데에 중점을 두었다. 철학 적 이론과 작품 실례를 결합 연구한 후 연구자의 해석을 추가 했다. 셋째, 상이 연구를 바탕으로 철학 이론과 미학적 관점을 결합 하여 추상적인 개념을 도자공예매체로 구상화 및 시각화하였다. 이러한 표현방식을 매개체로 삼아 본인의 창작의도를 분석했 다. 다양한 시각화 과정과 일정한 철학을 가지고 진행하였고, 작품의 미학적 분석을 바탕으로 하여 도자조형을 통한 양면성 에 대한 표현기법 및 내포된 의미를 탐구했다. 사람에 대한 내적 사고와 관심을 불러일으키고, 작업을 통한 감성의 발전을 진전시켰다. 철학과 예술 분야의 논의를 통해 예술을 보다 심미적이고 철학적으로 만들고 현대예술에 새로운 영혼을 불어넣으려 한다.

Copper hexacyanoferrate (Cu-HCF), which is a type of Prussian Blue analogue (PBA), possesses a specific lattice structure that allows it to selectively and effectively adsorb cesium with a high capacity. However, its powdery form presents difficulties in terms of recovery when introduced into aqueous environments, and its dispersion in water has the potential to impede sunlight penetration, possibly affecting aquatic ecosystems. To address this, sponge-type aluminum oxide, referred to as alumina foam (AF), was employed as a supporting material. The synthesis was achieved through a dip-coating method, involving the coating of aluminum oxide foam with copper oxide, followed by a reaction with potassium hexacyanoferrate (KHCF), resulting in the in-situ formation of Cu-HCF. Notably, Copper oxide remained chemically stable, which led to the application of 1, 3, 5-benzenetricarboxylic acid (H3BTC) to facilitate its conversion into Cu-HCF. This was necessary to ensure the proper transformation of copper oxide into Cu-HCF on the AF in the presence of KHCF. The synthesis of Cu-HCF from copper oxide using H3BTC was verified through X-ray diffraction (XRD) analysis. The manufactured adsorbent material, referred to as AF@CuHCF, was characterized using Fourier-transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). These analyses revealed the presence of the characteristic C≡N bond at 2,100 cm-1, confirming the existence of Cu-HCF within the AF@CuHCF, accounting for approximately 3.24% of its composition. AF@CuHCF exhibited a maximum adsorption capacity of 34.74 mg/g and demonstrated selective cesium adsorption even in the presence of competing ions such as Na+, K+, Mg2+, and Ca2+. Consequently, AF@CuHCF effectively validated its capabilities to selectively and efficiently adsorb cesium from Cs-contaminating wastewater.

Various dry active wastes (DAWs) have been accumulated in nuclear power plants since the DAWs are mostly combustible. KAERI has developed a thermochemical treatment process for the used decontamination paper as an operational waste to substitute for incineration process and to decontaminate radionuclides from the DAWs. The thermochemical process is composed of thermal decomposition in a closed vessel, chlorination of carbonated DAWs, separation of soluble chlorides captured in water by hydroxide precipitation, and immobilization of the precipitate. This study examined the third and fourth steps in the process to immobilize Co-60 by fabricating a stable wasteform. Precipitation behaviors were investigated in the chloride solution by adding 10 M KOH. It was shown that the precipitates were composed of Mg(OH)2 and Al(OH)3. Then, the glass-ceramic wasteform for the precipitates were produced by adding additive mixtures in which silica and boron oxide were blended with various ratios. The wasteform was evaluated in terms of volume reduction ratio, bulk density, compressive strength, and leachability.

One of released radioactive gases from a spent fuel is cesium (137Cs) as semi-volatile fission products and reticulated ceramic foam could be used for capturing the gaseous cesium. It has threedimensional open-pore structures and consumes cesium above 600°C to form cesium species including Cs-nepheline (CsAlSiO4) and pollucite (CsAlSi2O6) phases. Kaolinite-based foam filter is a favorable ceramic filter because they exhibit superior capture characteristics compared to other aluminosilicate minerals and other shape filters. However, for usage in special conditions, structural limitations such broken struts must be improved. Here, recoating by using centrifugation, followed by a pre-sintering cycle was conducted for covering the cracks and voids, resulting from the burnout of the polyurethane sponge as a sacricial template. The slurry including additives was chosen by considering viscous behavior of slurries for the centrifugation. The microstructure and strength was improved by the recoating.

A solution combustion process for the synthesis of hollandite (BaAl2Ti6O16) powders is described. SYNROC (synthetic rock) consists of four main titanate phases: perovskite, zirconolite, hollandite and rutile. Hollandite is one of the crystalline host matrices used for the disposal of high-level radioactive wastes because it immobilizes Sr and Lns elements by forming solid solutions. The solution combustion synthesis, which is a self-sustaining oxi-reduction reaction between a nitrate and organic fuel, generates an exothermic reaction and that heat converts the precursors into their corresponding oxide products in air. The process has high energy efficiency, fast heating rates, short reaction times, and high compositional homogeneity. To confirm the combustion synthesis reaction, FT-IR analysis was conducted using glycine with a carboxyl group and an amine as fuel to observe its bonding with metal element in the nitrate. TG-DTA, X-ray diffraction analysis, SEM and EDS were performed to confirm the formed phases and morphology. Powders with an uncontrolled shape were obtained through a general oxide-route process, confirming hollandite powders with micro-sized soft agglomerates consisting of nano-sized primary particles can be prepared using these methods.

Fouling is an inevitable problem in membrane water treatment plant. It can be measured by trans-membrane pressure (TMP) in the constant flux operation, and chemical cleaning is carried out when TMP reaches a critical value. An early fouilng alarm is defined as warning the critical TMP value appearance in advance. The alarming method was developed using one of machine learning algorithms, decision tree, and applied to a ceramic microfiltration (MF) pilot plant. First, the decision tree model that classifies the normal/abnormal state of the filtration cycle of the ceramic MF pilot plant was developed and it was then used to make the early fouling alarm method. The accuracy of the classification model was up to 96.2% and the time for the early warning was when abnormal cycles occurred three times in a row. The early fouling alram can expect reaching a limit TMP in advance (e.g., 15-174 hours). By adopting TMP increasing rate and backwash efficiency as machine learning variables, the model accuracy and the reliability of the early fouling alarm method were increased, respectively.

BNKT Ceramics, one of the representative Pb free based piezoelectric ceramics, constitutes a perovskite(ABO3) structure. At this time, the perovskite structure (ABO3) is in the form where the corners of the octahedrons are connected, and in the unit cell, two ions, A and B, are cations, A ion is located at the body center, B ion is located at each corner, and an anion O is located at the center of each side. Since Bi, Na, and K sources constituting the A site are highly volatile at a sintering temperature of 1100℃ or higher, it is difficult to maintain uniformity of the composition. In order to solve this problem, there should be suppression of volatilization of the A site material or additional compensation of the volatilized. In this study, the basic composition of BNKT Ceramics was set to Bi0.5(Na0.78K0.22)0.5TiO3 (= BNKT), and volatile site (Bi, Na, and K sources) were coated in the form of a shell to compensate additionally for the A site ions. In addition, the physical and electrical properties of BNKT and its coated with shell additives(= @BNK) were compared and analyzed, respectively. As a result of analyzing the crystal structure through XRD, both BNKT(Core) and @BNK(Shell) had perovskite phases, and the crystallinity was almost similar. Although the Curie temperature of the two sintered bodies was almost the same (TC = 290 ~ 300 ℃), it was confirmed that the d33 (piezoelectric coefficient) and Pr (residual polarization) values were different. The experimental results indicated that the additional compensation for a shell additive causes the coarsening, resulting in a decrease in sintering density and Pr(remanent polarization). However, coating shell additives to compensate for A site ion is an effective way to suppress volatilization. Based on these experimental results, it would be the biggest advantage to develop an eco-friendly material (Lead-free) that replaced lead (Pb), which is harmful to the human body. This lead-free piezoelectric material can be applied to a biomedical device or products(ex. earphones (hearing aids), heart rate monitors, ultrasonic vibrators, etc.) and skin beauty improvement products (mask packs for whitening and wrinkle improvement).