본 연구는 도로 노면의 결빙을 방지하기 위해 열적 특성을 갖는 콘크리트를 개발했습니다. 팽창 점 토에 상변화 물질(PCM)을 함침 시키고, 고열 전도성 에폭시와 실리카 흄으로 이중코팅을 하여 PCM 물질의 유출 방지, 골재의 부착성 개선, 열적 성능 개선을 하였으며 이를 DSC를 통해 열적 성능 평가 를 진행하여 확인했습니다. 또한 상변화 물질과 경량골재의 사용으로 인한 강도 감소 개선을 위한 CNT 혼합으로 강도 감소를 25% 개선하였습니다.

상변화 물질(PCM)은 상전이 동안 에너지를 흡수하거나 방출할 수 있는 잠열 저장 물질로 활용된다. 최근 수십 년 동 안, 연구자들은 다양한 온도 적용을 위한 건설 물질로의 다양한 PCM의 통합을 탐구해 왔다. 그러나, PCM을 통합하는 콘크리트 의 기계적 및 열적 반응은 통합 방법에 의해 영향을 받는다. PCM을 콘크리트에 추가하기 위한 여러 기술이 제안되었다. 그럼 에도 불구하고, 콘크리트에 마이크로 캡슐화 PCM(m-PCM)의 통합은 종종 기계적 강도의 상당한 감소를 초래한다. 기존 콘크리 트에 m-PCM의 추가와 관련된 한계를 극복하기 위해, 예외적인 강도 및 내구성 특성으로 인해 초고성능 시멘트 복합체(UHPCC) 가 선호된다. 따라서, 본 연구에서는 기존 기술의 단점을 해결하기 위해 PCM을 통합한 신규 나노 엔지니어링 UHPCC를 개발하 였다. 또한, 시멘트 복합체의 기계적 및 열적 성능을 향상시키기 위해 다중 벽 탄소 나노튜브(MWCNT)를 추가하였다. 결과는 MWCNT의 포함이 기계적 성능을 향상시켰을 뿐만 아니라 시멘트 복합체의 열적 성능을 향상시켰다는 것을 보여 주었다.

SnxSe100-X (15|X|30) alloys have been studied to explore their suitability as phase change materials for nonvolatile memory applications. The phase change characteristics of thin films prepared by a Radio Frequency (RF) magnetron co-sputtering system were analyzed by an X-ray diffractometer and 4-point probe measurement. A phase change static tester was also used to determine their crystallization under the pulsed laser irradiation. X-ray diffraction measurements show that the transition in sheet resistance is accompanied by crystallization. The amorphous state showed sheet resistances five orders of magnitude higher than that of the crystalline state in SnxSe100-X (x = 15, 20, 25, 30) films. In the optimum composition, the minimum time of SnxSe100-X alloys for crystallization was 160, 140, 150, and 30ns at 15mW, respectively. The crystallization temperature and the minimum time for crystallization of thin films were increased by increasing the amount of Sn, which is correlated with the activation energy for crystallization.

Electrical optical switching and structural transformation of Ge15Sb85, Sb65Se35 and N2.0 sccm doped Sb83Si17 were studied to investigate the phase change characteristics for PRAM application. Sb-based materials were deposited by a RF magnetron co-sputtering system and the phase change characteristics were analyzed using an X-ray diffractometer (XRD), a static tester and a four-point probe. Doping Ge, Se or Si atoms reinforced the amorphous stability of the Sb-based materials, which affected the switching characteristics. The crystallization temperature of the Sb-based materials increased as the concentration of the Ge, Se or Si increased. The minimum time of Ge15Sb85, Sb65Se35 and N2.0 sccm doped Sb83Si17 for crystallization was 120, 50 and 90 ns at 12 mW, respectively. Sb65Se35 was crystallized at 170˚C. In addition, the difference in the sheet resistances between amorphous and crystalline states was higher than 104Ω/γ.

냉축열 잠열재로 Na2SO4.10H2O를 선정하여 냉축열을 위한 잠열축열 온도 수준을 NH4Cl과 KCI을 잠열온도 조절제로 활용하여 16℃에서 -0.3℃까지 조절하였으며, 상변화 사이클에 의한 열특성 변화 추이와 물성의 안정성을 실험 분석하여 다음과 같은 결과를 얻을 수 있었다. 1. 냉축열재로 선택한 Na2SO4.10H2O는 물성이 불안정한 상변화 잠열 재였으나, 조핵제로 BRX를, 증점제로 CBP를 첨가하여 물성을 안정시켰으며, NH4Cl과 KCl을 상변화 온도조절제로 선택하여 상변화 온도를 조절할 수 있다. 2. SSD＋NH4Cl서 NH4Cl을 g~21wt%로 증가시킴에 따라 상변화 온도는 16~-0.3℃로 조절할 수 있었으며, 잠열축열량은 30kca1/kg에서 23.4kca1/kg으로 감소하였고, 상변화 온도조절제, KCl을 l7wt%에서 25wt%로 증가시킴에 따라 상변화 온도를 14℃에서 4℃까지 조절할 수 있었다.

This paper investigates the effect of amount of Paraffin-encapsulated phase change material (PCM) on the thermal energy storage of cement mortar for developing energy saving concrete. The PCM with melting point of 44℃ was used in this study. The added amounts of PCM in the cement mortar were 0, 10, 20 and 30% of cement weight. The results indicated that the heat storage properties of cement mortar was improved with increasing contents of PCM.

This paper investigates the effect of amount of Paraffin-encapsulated phase change material (PCM) on the thermal energy storage of cement mortar for developing energy saving concrete. The PCM with melting point of 44℃ was used in this study. The added amounts of PCM in the cement mortar were 0, 10, 20 and 30% of cement weight. The results indicated that the heat storage properties of cement mortar was improved with increasing contents of PCM.

For the distribution of fresh produce, the thermoelectric cooling system combined with thermo electric materials (TEM) and phase change material (PCM) was studied. The PCM used this study was produced by in-situ polymerization technology which referred microencapsulation of hydrocarbon (n-tetradecane and n-hexadecane). In this study, quality characteristics of bell peppers in thermoelectric cooling system combined with TEM and PCM were analyzed and control was placed in an EPS (expanded polystyrene) box. As a result of quality characteristics analysis, weight of bell peppers decreased and moisture content of bell peppers was 90.96~94.43% during storage. Vitamin C content of bell pepper decreased during storage and reduction ratio of control was higher than that of BPT-5 treatment(bell pepper in thermoelectric cooling system with PCM which is kept the temperature at 5℃). The result of color value, on 21 day, ΔE value of BPT-5 treatment was 5.05 while that of control was 41.8. On 21 day, total bacteria count of BPT-5 treated bell pepper shown less than that of control. In conclusion, it suggested that the thermoelectric cooling system combined with PCM improved quality of fresh produce during transportation and storage.

a initial setting of mortar containing 0.2% xylitol and 2% sodium phosphate dibasic dodecahydrate was found to become fast. And a initial setting of mortar containing 0.3% xylitol was found to become slow. Also, mortar containing xylitol and PCM can reduce of maximum temperature and increase compressive and tensile strength compared to the plain mortar and mortar containing blast-furnace slag.

본 연구는 저온 유통 시스템을 구축하기 위해 이동식 저온 컨테이너에서 잠열재, 내부온도의 유지특성과 운영조건별 사과의 내부 품온을 살펴보았으며, 그 결과를 요약하면 축냉식 저온유통 체계에서 다목적용 농산물 유통에 적합하도록 , , 3가지 온도대역별 잠열재를 개발하였다. 잠열재는 과 Sodium polyacrylate, 잠열재는 , , Sodium polyacrylate, 잠열재는 , , Sodium polyacrylate를 혼합하여