논문 상세보기

기계적 합금화에 의한 Ni Silicide 분말의 합성에 미치는 원소 분말의 입도 및 형상의 영향 KCI 등재

Effects of Elemental Powder Particle Size and Shape on the Synthesis of Ni Silicides by Mechanical Alloying

  • 언어KOR
  • URLhttps://db.koreascholar.com/Article/Detail/2123
구독 기관 인증 시 무료 이용이 가능합니다. 4,000원
한국분말야금학회지 (Journal of Korean Powder Metallurgy Institute)
한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

The synthesis of and NiSi has been investigated by mechanical alloying (MA) of Ni-27.9at%Si, Ni-33.3at%Si and Ni-50.0at%Si powder mixtures. As-received and premilled elemental powders were subjected to MA. The as-received Ni powder was spherical and the mean particle size 48.8m, whereas the premilled Ni powder was flaky and the mean particle diameter and thickness were found to be 125 and 5m, respectively. The mean surface area of the premilled Mi powder particle was 3.5 times as large as that of the as-received Ni powder particle. The as-received Si powder was was 10.0m. Self-propagating high-temperature synthesis (SHS) reaction, followed by a slow reaction (a solid state diffusion), was observed to produce each Ni silicide during MA of the as-received elemental powders. In other word , the reactants and product coexisted for a long period of MA of time. Only SHS reaction was, however, observed to produce each Ni silicide during MA of the premilled elemental powders, indicating that each Ni sillicide formed rather abruptly at a short period of MA time. The mechanisms and reaction rates for the formation of the Ni silicides appeared to be influenced by the elemental powder particle size and shape as well as the heat of formation of the products longrightarrow-43.1kJ/mol.at., -47.6kJ/mol.at.).

저자
  • 변창선