간행물

한국분말야금학회지 KCI 등재 Journal of Korean Powder Metallurgy Institute

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Vol. 6 No. 3 (1999년 9월) 8

2.
1999.09 구독 인증기관 무료, 개인회원 유료
The oxidation behavior of the simulated spent fuel of burn up 33 MWD/kgU was investigated to predict that of the spent fuel in the temperature ranges of 400 to and was compared with those of . The forms of uranium oxides after the oxidation were conformed by XRD analyses. The oxidation rate at each the temperature and the activation energy were obtained. After complete oxidation, the simulated spent fuel was converted to and pulverized to powder due to the density difference between the simulated spent fuel and uranium oxides. The activation energies were 85.35 and 30.77kJ/mol in the temperature ranges of 400T()500 and 500T()700, respectively.
4,000원
3.
1999.09 구독 인증기관 무료, 개인회원 유료
The synthesis of and NiSi has been investigated by mechanical alloying (MA) of Ni-27.9at%Si, Ni-33.3at%Si and Ni-50.0at%Si powder mixtures. As-received and premilled elemental powders were subjected to MA. The as-received Ni powder was spherical and the mean particle size 48.8m, whereas the premilled Ni powder was flaky and the mean particle diameter and thickness were found to be 125 and 5m, respectively. The mean surface area of the premilled Mi powder particle was 3.5 times as large as that of the as-received Ni powder particle. The as-received Si powder was was 10.0m. Self-propagating high-temperature synthesis (SHS) reaction, followed by a slow reaction (a solid state diffusion), was observed to produce each Ni silicide during MA of the as-received elemental powders. In other word , the reactants and product coexisted for a long period of MA of time. Only SHS reaction was, however, observed to produce each Ni silicide during MA of the premilled elemental powders, indicating that each Ni sillicide formed rather abruptly at a short period of MA time. The mechanisms and reaction rates for the formation of the Ni silicides appeared to be influenced by the elemental powder particle size and shape as well as the heat of formation of the products longrightarrow-43.1kJ/mol.at., -47.6kJ/mol.at.).
4,000원
4.
1999.09 구독 인증기관 무료, 개인회원 유료
Oxide powders of were prepared by spray drying, plasma densification and fused+crushed processes. The oxide coating layers were made by plasma spray and characterized by microstructure, hardness, adhesion strength and relative density. The optimum spray distance for the high quality coatings by spraying dried powders was found to be 9cm. A small amount addition of powder significantly improved coating characteristics by lowering the melting point of powders. The hardness and relative density of coating layers of the plasma densified powders were comparable to fused and crushed powders, however, the adhesion strength was much higher in the former case.
4,000원
5.
1999.09 구독 인증기관 무료, 개인회원 유료
In this study, the characteristics of gas atomized Mg-3wt%Al-1wt%Zn-1wt%MM alloy powders under vacuum condition were investigated. In spite of the low fluidity and easy oxidation of the molten magnesium, the spherical powders could be successfully produced by using a modified three pieces nozzle attached to the gas atomization unit. It was found that most of the solidified powders less than 50m in diameter were single crystal and the solidified structure showed a typical dendritic morphology due to supercooling prior to nucleation. The secondary dendrite arm spacing decreased as the size of powders decreased. The Mg-Al-Ce intermetallic compounds with chemically stable phase were found in the interdendritic regions of -Mg. It is considered that formation of the chemically stable phase may possibly affect to improve the corrosion resistance. Therefore, it is expected that the materials formed of these Mg-Al-Zn-MM alloy powders shows better mechanical properties and corrosion resistance due to the structural refinement.
4,000원
6.
1999.09 구독 인증기관 무료, 개인회원 유료
The preparation of powder by the Chemical Vapor Synthesis process (CVS) was studied using the liquid metal organic precursor (TTIP). The residence time and the collection methods were considered as main processing variables through the experiments. The CVS equipment consisted of a micropump and a flashvaporizer, a tube furnace and a tubular collection device. The synthesis was performed at with various sets of collection zone. The residence time and the total system pressure were controlled in the range of 3~20 ms and 10 mbar, respectively. Nitrogen adsorption, X-ray diffraction and electron microscopy were used to determine particle size, specific surface area and crystallographic structure. The grain size of the as-prepared powder was in the range of 2~8 nm for all synthesis parameters and the powder exhibited only little agglomeration. The relationship between particle characteristics and the processing variables is reviewed based on simple growth model.
4,000원
7.
1999.09 구독 인증기관 무료, 개인회원 유료
The effects of the starting particle size and / phase transformation during sintering process on the microstructure evolution of Yttrium -Sialon ceramics were investigated. As-received powder (mean particle size: 0.54m) and classified powder(mean particle size: ) were used as starting powders. With decreasing the starting particle size, the growth of elongated grains was enhanced, which resulted in the whisker -like microstructure with elongated grains. These results were discussed in relation to the two-dimensional nucleation and growth theory. In the specimen heat treated at for 10h before sintering at for 1h under 40atm(2-step sintering), the grain size was smaller than of the 1-step sintering at 195 for 1h. However, bimodal microstructure evolution were not not remarkable in both sample, which is ascribed to the -phase contents existing in starting powder.
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