The p-type semiconductor thermoelectric materials were fabricated by melting, milling and sintering process and their thermoelectric properties were characterized. The compound materials were ball-milled with milling time and the powders were sintered by spark plasma sintering process. The ball milled powders had equiaxial shape and approedmately in size. The figure of meritz of sintered thermoelectric materials decreased with milling time because of lowered electrical resistivity. The thermoelectric properties of materials have been discussed in terms of electrical property with ball mill process.
In-situ processing route was adopted to disperse carbon nanotubes (CNTs) into powders homogeneously. The composite powders with homogeneous dispersion of CNTs could be synthesized by a catalytic route for in-situ formation of CNTs on nano-sized Fe dispersed powders. CNTs/Fe/ nanopowders were densified by spark plasma sintering (SPS). The hardness and bending strength as well as electrical conductivity increased with increasing sintering temperature. However, the electrical conductivity of the composites sintered at above showed decreased value with increasing sintering temperature due to the oxidation of CNTs
Nanopowders of titanium dioxide incorporating the transition metal element(s) were synthesized by flame synthesis method. Single element among Fe(III), Cr(III), and Zn(II) was doped into the interior of crystal; bimetal doping of Fe and Zn was also made. The characteristics of transition-metal-doped nanopowders in the particle feature, crystallography and electronic structures were determined with various analytical tools. The chemical bond of Fe-O-Zn was confirmed to exist in the bimetal-doped nanopowders incorporating Fe-Zn. The transition element incorporated in the was attributed to affect both Ti 3d orbital and O 2p orbital by NEXAFS measurement. The bimetal-doped nanopowder showed light absorption over more wide wavelength range than the single-doped nanopowders
This work is to present a new synthesis of metallic glass (MG)/metallic glass (MG) composites using gas atomization and spark plasma sintering (SPS) processes. The MG powders of (CuA) and (NiA) as atomized consist of fully amorphous phases and present a different thermal behavior; (glass transition temperature) and (crystallization temperature) are 716K and 765K for the Cu base powder, but 836K and 890K for the Ni base ones, respectively. SPS process was used to consolidate the mixture of each amorphous powder, being in weight. The resultant phases were Cu crystalline dispersed NiA matrix composites as well as NiA phase dispersed CuA matrix composites, depending on the SPS temperatures. Effect of the second phases embedded in the MG matrix was discussed on the micro-structure and mechanical properties.
Copper is able to work as a current collector under wide range of hydrocarbon fuels without coking in Solid oxide fuel cells (SOFCs). The application of copper in SOFC is limited due to its low melting point, which result in coarsening the copper particle. This work focuses on the sintering of copper powder with ceria coating layer. Ceria-coated powder was prepared by thermal decomposition of urea in solution, which containing CuO core particles. The ceria-coated powder was characterized by XRD, ICP, and SEM. The thermal stability of the ceria-coated copper in fuel atmosphere was observed by SEM. It was found that the ceria coating layer could effectively hinder the grain growth of the copper particles
The with various phases were prepared by simple ex-situ hydrolysis and spark plasma sintering (SPS) process of Al powder. The nano bayerite phase was derived by hydrolysis of commercial powder of Al with micrometer size, whereas the bohemite (AlO(OH)) phase was obtained by hydrolysis of nano Al powder synthesized by pulsed wire evaporation (PWE) method. Compaction as well as dehydration of both nano bayerite and bohemite was carried out simultaneously by SPS method, which is used to fabricate dense powder compacts with a rapid heating rate of per min. under the pressure of 50MPa. After compaction treatment in the temperature ranges from , the bayerite and bohemite phases change into various alumina phases depending on the compaction temperatures. The bayerite shows phase transition of sequences. On the other hand, the bohemite experiences the phase transition from AlO(OH) to It shows AlO(OH) sequences. The compacted at shows a high surface area .
In the present study, silver-doped antibacterial hydroxyapatites were successfully prepared by the sol-gel method. For the starting solution, the molar ratio of was set to 0.075:0.045:20:0.135; was added to a ratio of Ag to total cation concentration of . The prepared sol was dried at for 48h and heat-treated at for 2h to obtain particles in the 200-500nm size range. The product from the synthesis of silver-doped hydroxyapatite was investigated through X-ray diffraction experiments and scanning electron microscopy. The product showed high antibacterial properties, with a disinfection ratio of Staphylococcus aureus (ATCC 6538) and Escherichia coli (ATCC 25922) over as calculated from an antimicrobial effects evaluation by the shake flask method.
The hydrogen sorption speed of nanocrystalline and amorphous alloys was evaluated at room temperature. Nanocrystalline alloys of were prepared by planetary ball milling. The hydrogen sorption speed of nanocrystalline alloys was higher than that of the amorphous alloy. The enhanced sorption speed of nanocrystalline alloys was explained in terms of surface oxygen stability which has been known to retard the activation of amorphous alloys. The retardation can be reduced by formation of nanocrystals, which results in the observed increase in sorption properties
The copper oxide nano powders were synthesized by levitational gas condensation (LGC) method, and were applied to catalyst to fabricate 3,4-dihydropyrimidin-2-(1H)-one. Processes of adsorption of Biginelli reaction reagents on the copper nanooxide surface were studied by IR-spectroscopy. It was shown that benzaldehyde coordination, acetoacetic ether on the oxide surface is carried out with participation of carbonyl fragments, urea by N-H bonds which affects positively on the reagents reactivity.
The synthesis and consolidation of titanium silicide by electro-discharge-sintering has been investigated. As-received Ti powder was in flaky shape and the mean particle size was , whereas the mean particle size of the pre-milled Si powder with angular shape was . Single pulse of 2.5 to 5.0 kJ/0.34g-elemental Ti and pre-milled Si powder mixture with the composition of Si was applied using capacitor. The solid with phase has been successfully fabricated by the discharge with the input energy more than 2.5kJ in less than Hv values were found to be higher than . The formation of occurred through a fast solid state diffusion reaction.