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물리화학적 처리를 통한 극성 용매 내 나노다이아몬드의 탈응집 및 분산성 향상 연구 KCI 등재

Deaggregation and Ultradispersion of Detonation Nanodiamonds in Polar Solvent Using Physicochemical Treatments

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한국분말야금학회지 (Journal of Korean Powder Metallurgy Institute)
한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

In the present work, physicochemical treatments were introduced for de-aggregation and stable dispersion of detonation nanodiamonds (DND) in polar solvents. The DNDs in water exhibited a particle size of 138 nm and high dispersion stability without particular treatment. However, the DNDs in ethanol were severely aggregated to several micrometers in size and showed poor dispersion stability with time. To break down aggregates of DNDs and enhance the dispersion stability of them in ethanol, mechanical force and chemical surfactant were introduced as functions of zirconia ball size, kind of surfactant and amount of surfactant added. From the analyses of average particle size and Turbiscan results, it was suggested that the size of DNDs in ethanol can be reduced by only mechanical force; however, the DNDs were re-aggregated due to high surface activity. The long-term dispersion stability can be achieved by applying mechanical force to break down the aggregates of DNDs and by preventing re-aggregation of them using proper surfactant.

저자
  • 김창규(한국원자력연구원 원자력재료개발부, 과학기술연합대학원대학교 양자에너지화학공학) | Changkyu Kim
  • 이경자(한국원자력연구원 원자력재료개발부) | Gyoung-Ja Lee Corresponding Author
  • 이창규(한국원자력연구원 원자력재료개발부) | Changkyu Rhee