As Al-Li based alloys are to find widespread use in aerospace and other structural applications in which their low-density high specific stiffness properties be exploited, their mechanical properties must adequately match those of the which they intended to replace. In order to develop these purposed, the precipitation behaviors of the rapidly solidified Al-Li-Ti alloys aged at various temperature were investigated. δ' phase precipitated homogeneously in the matrix during not only melt quenching but also aging at the aging temperature of 160℃ and 210℃. The addition of the Ti in Al-Li alloy promoted the formation of δ' phase. The addition of Ti on the δ' solvus line had a little effect over the thermodynamics δ' solvus line. The reason for these behavior was that the δ' phase was suppressed to precipitate as much as supercooling by melt quenching. The discontinuous precipitation reaction occurred by the preferential growth of δ' phase due to the migration of grain boundary provided the driving force dependent of solute concentration fluctuations.