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pp.29-34
The sulfuric acid sulfonation of 2-aminonaphthalene was preformed at 30℃~200℃ for 1~15 hours, using 4~10 parts of 90% sulfuric acid~20% oleum. This reaction was influenced by many factory such as reaction temperature, reaction time, strength of sulfuric acid and amount of sulfuric acid and among these factors, the effect of the reaction temperature was considerable. The main products of this reaction were Dahl's acid (2-aminonaphthalene-5-sulfonic acid, Broenner's-acid (2-aminonaphthalene-6-sulfonic acid), amnio-F-acid(2-aminonapthalene-7-sulfonic acid), and Baden acid (2-aminonaphthalene-7-sulfonic acid) and another isomers such as Tobia's acid (2-aminonaphthalene-1-sulfonic acid) and 2-aminonaphthalene-4-sulfonic acid were not formed. Of these isomeric acids, those containing the sulfonic acid group in an α-position, namely, Dahl's acid and Baden acid, are simultaneously formed by sulfonation at low-temperature (30~100℃), whilst those containing the sulfonic acid group in a β-position, namely, Broenner's acid and amino-F-acid, are formed simultaneously by sulfonation at high temperatures(150˚~200˚).
