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Cyclotetramethylene-tetranitramine의 미세 입자 제조를 위한 결정화 연구 KCI 등재

The study on crystallization for fine particles of Cyclotetramethylene-tetranitramine

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  • URLhttps://db.koreascholar.com/Article/Detail/257605
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한국응용과학기술학회지 (The Korean Society of Applied Science and Technology)
한국응용과학기술학회(구 한국유화학회) (The Korean Society of Applied Science and Technology (KSAST))
초록

In T-mixer crystallization, supersaturation is generated by mixing of another solvent or non-solvent in order to reduce the solubility of the compound. Also, T-mixer is a type of continuous crystallization. In order to induce micro-mixing, two solutions were mixed rapidly by T-mixer, which formed high supersaturation. As the results, mean size of HMX crystals decreased with increasing de-supersaturation rate (Rs). Eventually, HMX particles ranging from 0.5 to 5μm can be obtained by T-mixer crystallization. Mixing efficiency in T-mixer increased with increasing Rs values. In T-mixer crystallization without surfactants, homogeneous nucleation was formed when S and Rs was over 54 and 1.6×103/sec. In T-mixer crystallization with surfactants, homogeneous nucleation was formed when S and Rs was over 26 and 7.4/sec.

저자
  • 김성일 | Kim, Sung-Il
  • 전석근 | Chun, Suk-Keun
  • 박두곤 | Park, Du-Goan
  • 박근호 | Park, Keun-Ho
  • 박소진 | Park, So-Jin