논문 상세보기
Poly(Styrene-co-2-Hydroxypropylacrylate)의 라디칼 공중합 및 열분해 속도론 KCI 등재
The Kinetics of Radical Copolymerization and Thremal Decoposition of Poly(Styrene-co-2- Hydroxypropylacrylate)
한국응용과학기술학회지
(The Korean Society of Applied Science and Technology)
Vol.26 No.2 (2009.06)
pp.205-212
pp.205-212
한국응용과학기술학회(구 한국유화학회)
(The Korean Society of Applied Science and Technology (KSAST))
초록
Solution copolymerization of Styrene(St.) with 2-Hydroxypropylacrylate(2-HPA) was carried out with Benzoylperoxide(BPO) as an initiator in toluene at 80℃ in a batch reactor. Reaction volume and reaction time were 0.3 liters, 8 hours respectively. The time to reach steady state was about the six time. The monomer reactivity ratios, r1(St.) and r2(2-HPA) were determined by both the Kelen-Tudos method and the Fineman-Ross method ; r1(St.)=0.376(0.330), r2(2-HPA)=0.408(0.778). The activation energy of thermal decomposition was in the range of 33~55kcal/mol.
저자
같은 권호 다른 논문
