The decomposition of NF3 using only an electron beam, and an electron beam in the presence of hydrogen are assessedin terms of the destruction and removal efficiency (DRE, %). Experiments were conducted at a flow rate of 500LPM.The inlet concentration of NF3 in nitrogen gas was about 1,000ppm, and the concentration of hydrogen ranged from 1,500to 8,000ppm, respectively. Absorbed dose (kGy) and electric current ranged from 33.87 (5mA) to 203.21kGy (30mA).The results in this study indicate that the DRE increased about 35% with hydrogen addition at electric current 30mA.Additionally hydrogen gas played a significant role in the constituents of byproducts.