With the recent increased awareness of underground water as a resource and detection of radioactive material called radon in underground, underground waterproofing system is newly regard as not only ensuring stability and durability of the structure but also preserving underground water, safety of employee working underground structure, protecting of facilities and comfortable use. For these reasons, constructing industry have highly demanded feasible underground waterproofing system that responding long-life and high-performance new material and developing waterproof performance evaluation techniques. Therefore, this study attempts to build environmental responding waterproof system with high adhesive sealant material and setting a manual of field application in waterproofing construction technique.