This study is based on developing a free-cement. The Setting time of 100% GGBS(Ground Granulated Blast furnace Slag) admixed alkali-activators is measured, the influence of cation of alkali-activators on setting time is assessed. As a result, in case of mixing KOH or NaOH, setting time is getting shorter, although, GGBS admixed Ca(OH)2 has similar setting times regardless of concentration of alkali-activators.