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재활용용도 확대를 위한 인산석고의 용출특성 연구 KCI 등재

Leaching Characteristics of Phospho-gypsum for the Expansion of Recycling

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한국폐기물자원순환학회지 (Journal of Korea Society of Waste Management)
한국폐기물자원순환학회 (Korea Society Of Waste Management)
초록

Phospho-gypsum (PG) is a by-product generated from wet process of phosphoric acid production. The recycling rateof PG is only fifteen percents for the recycling uses, such as cement retardant, gypsum board, plaster, functional fertilizer.In the result of pH analysis, PG, neutralizing gypsum, soil, and dredged soil were 3.5, 7.4, 8 to 8.8, and 7.8, respectively.In case of the electric conductivity (EC), PG, neutralizing gypsum, and soil were 2,990µS/cm, 2,230µS/cm, and84~99µS/cm, respectively. In heavy metal contents of PG, As and Cd could be measured under environmentalstandards in Korean Soil Environment Conservation Act. In inorganic elements of leaching PG, Ca and Na were 629mg/L and 13 mg/L, respectively, but As, Cd, and other elements were detected under the regulated levels in Korean WasteManagement Act. Also, among inorganic elements in PG, the leaching ratio of Mg and Cd were 7.3%, 1.3% respectively.In neutralized PG, leaching ratio of Mg and Cu were 1.9%, 1.4% respectively compared with other elements. Insequential batch leaching test, the leaching concentrations of As and Cd were rapidly decreased after 2 days. F− andCa were steadily decreased until 2 days and 8 days, respectively, and no more change since then. In case of SO42−, itfell at constant rate to 1,600~1,800mg/L. As seen in Ca leaching curve relating to pH value, the leaching decreasedwith increasing pH.

목차
I. 서 론
 II. 연구내용 및 방법
  1. 연구내용
  2. 시료채취방법
  3. 분석 및 용출시험방법
 III. 결과 및 고찰
  1. 인산석고의 배출특성 및 재활용성
  2. 인산석고의 함량 및 용출농도 특성
  3. 연속회분식 용출시험에서 용출액의 농도 특성
 IV. 결 론
 감사의 글
 References
저자
  • 김우일(국립환경과학원 자원순환연구과) | Woo-Il Kim Corresponding author
  • 윤철우(국립환경과학원 자원순환연구과) | Cheol-Woo Yoon
  • 엄남일(국립환경과학원 자원순환연구과) | Nam-Il Um
  • 최효현(국립환경과학원 자원순환연구과) | Hyo-Hyun Choi
  • 강영렬(국립환경과학원 자원순환연구과) | Young-Yeul Kang
  • 전태완(국립환경과학원 자원순환연구과) | Tae-Wan Jeon
  • 신선경(국립환경과학원 자원순환연구과) | Sun-Kyoung Shin