In order to reuse the photocatalyst and enhance the photolysis efficiency, we have used atmospheric pressure dielectric barrier discharge (APDBD) to clean and activate TiO2 powder. The photocatalytic activity of the TiO2 powder before and after APDBD treatment was evaluated by the degradation of methylene blue (MB) in aqueous solution. The apparent reaction rate constant of photolysis of the first sample of reused TiO2 cleaned by APDBD improved to a level up to 0.32h- 1 higher than the 30 % value of the initial TiO2 powder. As the number of photolysis reactions and APDBD cleanings increased, the apparent rate constants gradually decreased; however, the fourth photolysis reaction still showed a value that was greater than 10% of the initial value. In addition, APDBD treatment enhanced the process by which TiO2 effectively adsorbed MB at every photolysis stage.