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Study on Characteristics of Hot Gas Cleanup for Synthesis Gas from Waste Feedstocks
- 언어ENG
- URLhttps://db.koreascholar.com/Article/Detail/341500
Waste gasification can generate hydrocarbon gases that may be utilized for the synthesis of chemicals or liquid fuels, or for fuel cell power generation, if extensive, deep syngas cleaning is initially conducted. Conventional gas cleaning technology for such applications is expensive and may limit the feasibility of wet technology. Conventional cold gas cleanup (scrubbing by solvents) technique needs the temperature of raw waste gasification gas ranging from 900 to 1600℃ reduced to room temperature. Then, the cleaned - up syngas needs to be reheated. Obviously, the process is energetically inefficient. It is the objective of this study to economically meet the most stringent cleanup requirements without reheating syngas for these applications. We investigated the temperature and pressure effect in breakthrough performance of various sorbents for desulfurization and de-chlorination. Based on the results obtained during the desulfurization (Fe₂O₃, Fe₃O₄, ZnO) and the dechlorination (Na₂CO₃, NaHCO₃, Na₂O) screening tests, ZnO and Na₂O were selected as preferred optimum sorbents. H₂S breakthrough time corresponds to an effective capacity of approximately 11 g Cl/100 g of material. Also, HCl, breakthrough time corresponds to an effective capacity of approximately 5 g Cl/100 g of material. ZnO and Na₂O at high temperature of around 550℃ display high sorption performance and removal efficiency for waste syngas along with H₂S and HCl. Although there is an issue of CO₂ recovery in warm gas clean-up technology for desulfurization, we have obtained an interesting new alternative warm gas clean-up system with heat budget merit.
